CAS: 14099-01-5; Rhenium Pentacarbonyl Chloride

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CAS号14285-68-8 十羰基二铼 | CAS号14524-92-6 Methyl rhenium ... | CAS号15684-00-1 methanone,rhenium | CAS号14220-21-4 溴代五羰基铼(I) | CAS号56-23-5 四氯化碳 | CAS号41706-12-1 pentacarbonyl(2... | CAS号71252-85-2 pentacarbonyl(2... | CAS号78670-75-4 pentacarbonyl(t... | CAS号7647-01-0 盐酸 | CAS号1066-45-1 三甲基氯化锡 | CAS号14285-68-8 十羰基二铼 | CAS号14220-21-4 溴代五羰基铼(I)

📜Pentacarbonyl(Tetrafluoroborato)Rhenium置于三氯化磷体系中,用 二氯甲烷 用作溶剂,化学反应生成五羰基氯铼(I)
参考文献:Metallorganischelewis-Säuren :Xxxvii.五溴羰基化ation(kationische Penta羰基(phosphan)rhenium-Komplexe Unde Deren Reaktionen Mit Nucleophilen)
标题:Metallorganischelewis-Säuren :Xxxvii.五溴羰基化ation(kationische Penta羰基(phosphan)rhenium-Komplexe Unde Deren Reaktionen Mit Nucleophilen)
摘要:Pentacarbonyletrafluoroboratorhenium的反应中,(oc)5 Refbf 3,用ph 3,Pph 3 Pph 2 H,和chlorphosphanes导致阳离子络合物[(oc)5 Repr 3 ] + Bf 4-(1).亲核试剂与的chlorphosphane配体反应1,得到离子络合物[(oc)5 Repr 3-ñ R' ñ ] + Bf 4-(r'= Oh,青梅,Oet).[(oc)的reacton 5 Repph 2 Cl] +bf 4-用oh-产生桥接的[(oc)5 Rep(ph)2-O-(ph)2 Pre(co)5 ] 2+ 2Bf 4-,而用[(oc)5 Repet 2 Cl] + Bf 4-和oh-的配合物[(oc)repet 2 Oh] + Bf 4-形成.该叠氮化物离子被添加到顺式-羰基配体的[(oc)5 Repph 2
Doi:10.1016/0022-328X(89)87258-4

专利信息

专利号:WO-2009077719-A1
优先权日:2007-12-17
标 题:Process for the conversion of hydrocarbons to ethanol
发明人：DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
权利人:BP P I C; DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
摘要:The present invention relates to a process for producing ethanol, and optionally methanol, from synthesis gas. In particular the present invention relates to a process for producing ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to methanol which is then converted to dimethyl ether which is then converted to methyl ethanoate, which is then hydrogenated to produce ethanol in the same alcohol synthesis unit used for converting the said synthesis gas to methanol.

专利号:US-5596115-A
优先权日:1994-11-04
标题:Compounds of rhenium and aluminium, preparation thereof and use thereof as catalysts
发明人：COMMEREUC DOMINIQUE
权利人:INST FRANCAIS DU PETROLE
摘要:The present invention concerns new compounds of rhenium and aluminum corresponding to the general formula: O 3 Re--O--[Al(OR)(L) x --O] n --ReO 3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns derived compounds of the formula O 3 Re(L')--O--[Al(OR)(L) x --O] n --ReO 3 (L') in which L' is a stabilising ligand. The invention also concerns the preparation of such compounds and the use thereof in the preparation of catalysts.

专利号:US-5747409-A
优先权日:1994-11-04
标题 :Catalytic compositions based on compounds of rhenium and aluminium, preparation thereof and use thereof for the metathesis of olefins
发明人：COMMEREUC DOMINIQUE
权利人:INST FRANCAIS DU PETROLE
摘要:The present invention concerns new catalytic compositions containing at least one compound of rhenium and aluminium corresponding to the general formula: O 3 Re--O-- Al(OR)(L) x --O! n --ReO 3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns the preparation of such compositions and the use thereof for the metathesis of olefins in a homogeneous phase.

专利号:EP-0021496-A1
优先权日:1979-06-21
标 题:Synthesis of long-chain alkanes having terminal functionality

专利号:WO-0013004-A9
优先权日:1998-08-26
标 题:Combinatorial polymer synthesis of sensors for polymer-based sensor arrays

专利号:US-8907140-B2
优先权日:2007-11-14
标 题 :Process for the production of alcohol from a carbonaceous feedstock
发明人：DANIEL BERIAN JOHN; DEELEY JON MICHAEL STEWART; GRACEY BENJAMIN PATRICK; LI CONG RONG
权利人:BP PLC
摘要:The present invention relates to an improved process for the production of ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to ethanoic acid, which is then esterified and which is then hydrogenated to produce ethanol.