CAS: 1067-43-2; Tetraallyloxysilane

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CAS号10026-04-7 四氯化硅 | CAS号107-18-6 烯丙醇 | CAS号78-10-4 正硅酸乙酯 | CAS号10025-78-2 三氯氢硅 | CAS号2290-36-0 3-(Triethylsily...

📜烯丙醇置于四氯化硅体系中,化学反应生成硅酸四烯丙酯
参考文献:Helferich; Hausen,Chemische Berichte,1924,Vol. 57,P. 797
标题:Helferich; Hausen,Chemische Berichte,1924,Vol. 57,P. 797

专利信息

专利号:US-9714174-B2
优先权日:2012-07-19
标题:Methods of controlling polymorphism in organic-free synthesis of Na-zeolites and zeolite crystals formed therefrom
发明人：RIMER JEFFREY D; MALDONADO MIGUEL; OLEKSIAK MATTHEW D
权利人:RIMER JEFFREY D; MALDONADO MIGUEL; OLEKSIAK MATTHEW D; UNIV HOUSTON SYSTEM
摘要:Methods of controlling crystal polymorphism in organic-free synthesis of Na-Zeolites and the zeolite crystals formed using those methods are provided. The methods disclosed herein create certain types of zeolite crystals more efficiently than other previously known methods. The methods also create certain types of zeolite crystals in a form and concentration not previously disclosed. The methods disclosed herein generally comprise using solutions with varying ratios of silicon (Si), aluminum (Al), hydroxide (OH), and water. Some implementations of the invention disclosed include efficient methods of producing nearly pure cancrinite (CAN), methods of obtaining sodalite in solutions with a high Si/Al ratio, and a method of forming thin, platelet-like ANA crystals with a width of less than about 1 μm and a length of at least about 3 μm.

专利号:US-4476327-A
优先权日:1982-07-28
标题 :Process for the synthesis of glycol monomethylethers
发明人：NERI CARLO; BUONOMO FRANCO; ANFOSSI BARTOLOMEO
权利人:ANIC SPA
摘要:A process for the synthesis of glycol monomethylethers consisting of reacting an olefin compound, methanol and hydrogen peroxide in aqueous solution in the presence of synthetic zeolites containing titanium atoms, of general formula: n n xTiO.sub.2.(1-x)SiO.sub.2, n n where x lies between 0.0001 and 0.04.

专利号:WO-2010011420-A1
优先权日:2008-07-25
标题:Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
发明人：MERTENS MACHTELD M; VAUGHN STEPHEN N; CAO GUANG; MARTENS LUC R M; AFEWORKI MOBAE
权利人:EXXONMOBIL CHEM PATENTS INC; MERTENS MACHTELD M; VAUGHN STEPHEN N; CAO GUANG; MARTENS LUC R M; AFEWORKI MOBAE
摘要:In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+ CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.

专利号:WO-2010011419-A1
优先权日:2008-07-25
标 题 :Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
发明人：MERTENS MACHTELD M
权利人:EXXONMOBIL CHEM PATENTS INC; MERTENS MACHTELD M
摘要:In a method of synthesizing a mostly CHA-type silicoaluminophosphate sieve, a reaction mixture comprises sources of water, silicon, aluminum, phosphorus, and a template. In one aspect, the inorganic phosphorus and silicon sources are first combined to form a primary mixture that is aged. Then, the aluminum source is added, followed optionally by any organic phosphorus source, and then the template, to form the synthesis mixture. After heating at <10°C/hr to induce crystallization, in this aspect, both the crystallized sieve has an average crystal size ≤1.5μm and/or is recovered in a yield of ≥10.0wt%. In another aspect, when the synthesis mixture Si/Al2 ratio is <0.33, crystallization is induced. Advantageously, the sieve so crystallized has a template efficiency of ≥0.5 and/or is recovered in a yield of ≥10.0wt%. The molecular sieve from both aspects can be used in a hydrocarbon (oxygenates-to-olefins) conversion process.

专利号:US-6495208-B1
优先权日:1999-09-09
标 题 :Near-room temperature CVD synthesis of organic polymer/oxide dielectric nanocomposites
发明人：DESU SESHU B; SENKEVICH JOHN J
权利人:VIRGINIA TECH INTELL PROP
摘要:Nanocomposite thin films with low dielectric constants are made by the simultaneous deposition of an oxide dielectric and an organic polymer at near room temperatures. Suitable oxides include SiO 2 , and suitable organic polymers include poly(chloro-para-xylylene). The two dielectric materials, when deposited, form nanocomposites characterized by nanometer-sized domains of dielectric material. The nanocomposite thin films of this invention are useful as dielectric layers for interlevel dielectric (ILD) and intermetal dielectric (IMD) dielectrics in the manufacture of semiconductor devices as well as for thin films for flat panel displays, food wraps, hybrid ceramics, glass, hard disk drives, and optical disk drives. Additionally, the invention comprises semiconductor devices and semiconductor chips made incorporating nanocomposites deposited by chemical vapor deposition.

专利号:US-8399578-B2
优先权日:2008-07-25
标题 :Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
发明人：MERTENS MACHTELD M; VAUGHN STEPHEN N
权利人:MERTENS MACHTELD M; VAUGHN STEPHEN N; EXXONMOBIL CHEM PATENTS INC
摘要:In a method of synthesizing a silicoaluminophosphate molecular sieve having 90+% CHA framework-type character, a reaction mixture is prepared comprising sources of water, silicon, aluminum, and phosphorus, as well as an organic template. In one aspect, the reaction mixture is heated at more than 10° C./hour to a crystallization temperature and is retained at the crystallization temperature or within the crystallization temperature range for a crystallization time from 16 hours to 350 hours to produce the silicoaluminophosphate molecular sieve. In another aspect, the reaction mixture is heated at less than 10° C./hour to a crystallization temperature from about 150° C. to about 225° C. and is then retained there for less than 10 hours to produce the silicoaluminophosphate molecular sieve. The molecular sieve can then be recovered from the reaction mixture and, preferably, used in a hydrocarbon conversion process, such as oxygenates to olefins.