专利号:US-7763230-B2 优先权日:2005-11-10 标题:Process and apparatus utilizing mixed ligand organometallic catalysts for in situ growth of high purity, low defect density carbon nanotubes 发明人:HEPP ALOYSIUS F; HARRIS JERRY D 权利人:NANOTECH INNOVATIONS LLC 摘要:The present invention relates to a simple method for the synthesis of fullerenes using a mixture of liquid metallorganic precursors and liquid organic hydrocarbon solvents wherein the mixture is injected in the form of droplets into a multiple heated zone reactor tube in which the droplets are thermally decomposed and fullerenes are formed. The process is useful for the formation of all types of fullerenes, and in particular yields multi-walled carbon nanotubes (MWNTs) with low defect density and controllable wt % of metal impurity atoms. In particular, a method is disclosed that produces as-grown MWNTs with less than 5 wt % metal impurity atoms. Large classes of metallorganic precursors suitable for use in the process are also identified.
专利号:WO-2007007735-A1 优先权日:2005-07-12 标 题 :Synthesis of organic conductive polymerizable material onto metal oxide surface through light irradiation 发明人:TACHIBANA YASUHIRO 权利人:UNIV OSAKA; KANSAI TECH LICENSING ORG CO; TACHIBANA YASUHIRO 摘要:Disclosed is a composite material having a nanostructure containing metal oxide fine particles and an organic conductive polymerizable material. In this composite material, the metal oxide fine particles are joined with one another and the organic conductive polymerizable material is contained in the spaces between the fine particles. In this connection, the organic conductive polymerizable material is a copolymer which is composed of a polythiophene derivative, a thiophene or a derivative thereof and pyrrole, aniline, fluorene, furan or a derivative thereof. Also disclosed is a method for producing such a composite material. This composite material is useful for display elements such as electronic paper.
专利号:US-2009117020-A1 优先权日:2007-11-05 标题 :Rapid microwave-solvothermal synthesis and surface modification of nanostructured phospho-olivine cathodes for lithium ion batteries 发明人:MANTHIRAM ARUMUGAM; MURUGAN ARUMUGAM VADIVEL; THEIVANAYAGAM MURALIGANTH 权利人:UNIV TEXAS 摘要:The present invention includes methods, coatings, and a nanostructured phospho-olivine composition Li x M y PO 4 , capable of being formed hydrothermally or solvothermally in aqueous solutions and non-aqueous solutions M is one or more elements selected from the group consisting of Fe, Mn, Co, Ti, Ni, Cu, V, Mo, Zn, Mg, Cr, Al, Ga, B, Zr, Nb or combination thereof and x is between 0 and 1 and y is between 0.8 and 1.2. The phospho-olivine may also have the compositions like Li x Fe 1-y M y PO 4 , wherein x is between 0 and 1, and y is between 0 and 1.
专利号:US-2022325053-A1 优先权日:2019-08-13 标题:Method for the synthesis of a two-dimensional or quasi-two-dimensional polymer film, the two-dimensional or quasi-two-dimensional polymer film and the use
专利号:US-8530594-B2 优先权日:2006-03-16 标 题 :Copolymers of alkoxythiophene 发明人:PEI QIBING; YANG YANG; SHI CHENJUN 权利人:PEI QIBING; YANG YANG; SHI CHENJUN; UNIV CALIFORNIA 摘要:The synthesis, characterization, optical and electrochemical properties of a regioregular copolymer, poly(3-octylthiophene-2,5-diyl-co-3-decyloxythiophene-2,5-diyl) (POT-co-DOT), and an alternating regioregular copolymer poly{(9,9-dioctylfluorene)-2,7-diyl-alt-[4,7-bis(3-decyloxythien-2-yl)-2,1,3-benzothiadiazole]-5′,5″-diyl} (PF-co-DTB) is disclosed. The incorporation of 3-alkoxythiophene units onto the conjugated backbones enhances the electron-donating property of the polymer and lowers its bandgap. The fabrication and performance of photovoltaic cells with bulk heterojunction architecture based on blends of these copolymers with PCBM are also described.
专利号:WO-2021028429-A1 优先权日:2019-08-13 标题:Method for the synthesis of a two-dimensional or quasi-two-dimensional polymer film, the two-dimensional or quasi-two-dimensional polymer film and the use
参考标题:Metal-Free Oxidative Coupling Reactions Via σ-Iodonium Intermediates: The Efficient Synthesis Of Bithiophenes Using Hypervalent Iodine Reagents 作者:Koji Morimoto,Tomofumi Nakae,Nobutaka Yamaoka,Toshifumi Dohi,Yasuyuki Kita |发布日期:2011.11 摘要:The Direct Oxidative Biaryl Coupling Reaction Is An Attractive Tool For Environmentally Benign Green Chemistry. A Novel Direct Method For The Synthesis Of Bithiophene Using A Hypervalent Iodine Reagent Has Been Developed. The Reaction Mechanism Has Also Been Investigated, Casting Light On The Reaction Intermediate And Revealing The Reactivity With Iodonium Salts.
合成参考文献
摘要:Logeswaran, R.; Aravindan, N.; Jeganmohan, M., Science of Synthesis: Cross-Dehydrogenative Coupling, (2023) nan, 30. 参考文献:10.1364/ao.40.003737 摘要:Hwang J, Goldner LS, Karim A, Gettinger C. Imaging phase-separated domains in conducting polymer blend films with near-field scanning optical microscopy. Appl Opt. 2001 Aug 01;40(22):3737–45. doi: 10.1364/ao.40.003737.