CAS: 12023-53-9; Iron Phosphide

该化合物是一种无机化合物,其特点是金属特性,以及铁和磷的独特的异异异体,其结构可能不同,各种异体具有不同特性,各种异体具有不同特性.铁磷在磁材料研究中也很感兴趣,并且能够影响铁基合金的机械特性.在处理该化合物时,由于在水或酸反应中可能释放危险气体,安全防范至关重要.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

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    专利信息


    专利号:US-2024097109-A1
    优先权日:2021-02-11
    标 题:Bottom-Up, Scalable Synthesis Of Oxide-Based Sub-Nano And Nanofilaments And Nanofilament-Based Two-Dimensional Flakes And Mesoporous Powders
    发明人:BARSOUM MICHEL W; BADR HUSSEIN OSAMA
    权利人:UNIV DREXEL
    摘要:Provided are methods to convert—through a bottom-up approach—binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into lepidocrocitic nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can comprise nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances.

    专利号:US-11400438-B2
    优先权日:2018-12-05
    标 题 :Synthesis and immobilization of a ferrous sulfite catalyst and method of degrading fluorinated organic chemicals in aqueous media
    发明人:DIONYSIOU DIONYSIOS D; ABDELRAHEEM WAEL H M; NADAGOUDA MALLIKARJUNA N
    权利人:UNIV CINCINNATI; THE US ADMINISTRATOR OF THE U S ENVIRONMENTAL PROTECTION AGENCY
    摘要:A composition includes an aqueous solution including at least one fluorinated organic compound; and a reaction product of a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. A method of making a catalyst includes reacting a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. The water may include less than or equal to 1 weight percent dissolved molecular oxygen. The catalyst may be used for degrading fluorinated organic chemicals in aqueous media.

    专利号:WO-2022174264-A1
    优先权日:2021-02-11
    标题:Bottom-up, scalable synthesis of oxide-based sub-nano and nanofilaments and nanofilament-based two-dimensional flakes and mesoporous powders
    发明人:BADR HUSSEIN O; BARSOUM MICHEL W
    权利人:UNIV DREXEL
    摘要:Provided are methods to convert - through a bottom-up approach – binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can be C-containing anatase-based layers that are in turn comprised of nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances. Electrodes made from these materials performed well in energy systems. The materials also reduce the viability of some cancer cells. Also provided are mesoporous materials, devices, and related methods.

    专利号:US-2012168686-A1
    优先权日:2009-09-03
    标 题:Continuous Synthesis of Carbon-Coated Lithium-Iron-Phosphate
    发明人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E
    权利人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E; CLARIANT FINANCE BVI LTD
    摘要:The invention relates to a continuous process for preparing carbon-coated lithium-iron-phosphate particles, wherein the carbon-coated lithium-iron-phosphate particles have a mean (d 50 ) particle size of 10 to 150 nm, and wherein the carbon-coating is an acetylene-black coating, comprising performing in a reactor a flame-spray pyrolysis step (i) in a particle formation zone of the reactor, and a carbon-coating step (ii) in a carbon-coating zone of the reactor, wherein inn (i) a combustible organic solution containing a mixture of lithium or a lithium compound; iron or an iron compound; and phosphorus or a phosphorous compound in an organic solvent, is fed through at least one nozzle where said organic solution is dispersed, ignited and combusted, to give a flame spray thereby forming an aerosol of lithium iron phosphate particles; (ii) acetylene gas is injected into said aerosol thereby forming an acetylene-black coating on the lithium iron phosphate particles; (iii) the coated particles are cooled by an inert quench gas and collected on a filter.

    专利号:EP-4291240-A1
    优先权日:2021-02-11
    标题 :Bottom-up, scalable synthesis of oxide-based sub-nano and nanofilaments and nanofilament-based two-dimensional flakes and mesoporous powders

    专利号:US-10755939-B2
    优先权日:2018-09-11
    标 题 :Multilayer graphene using chemical vapor deposition and method of manufacturing same
    发明人:CHO KILWON; YOO MIN SEOK; LEE HYO CHAN
    权利人:CT ADVANCED SOFT ELECTRONICS; POSTECH ACADEMY-INDUSTRY FOUND
    摘要:Disclosed is a method of manufacturing multilayer graphene, including (a) contacting of a metal substrate with a nonmetal element, (b) reduction through heat treatment, and (c) chemical vapor deposition of a graphene precursor on the metal substrate containing the nonmetal element dissolved therein, thereby manufacturing multilayer graphene that is doped with the nonmetal element on the metal substrate. In the multilayer graphene thus manufactured, the number of graphene layers and the work function are simultaneously adjusted by controlling the concentration of doped nonmetal element in a thickness direction of graphene through interactions related to the reduction of the nonmetal element dissolved in a copper catalyst and the growth of graphene, and moreover, the stacking structure of graphene is maintained and the optoelectronic properties of multilayer graphene can be controlled by simultaneously regulating graphene growth and doping during the synthesis procedure without additional processing.

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    合成参考文献


    摘要:L982: International Programme on Chemical Safety (IPCS) INCHEM (1996). Poison Information Monograph for Phosphine.
    摘要:L987: Wikipedia. Iron phosphide. Last Updated 10 May 2009.
    摘要:A291: Singh S, Bhalla A, Verma SK, Kaur A, Gill K: Cytochrome-c oxidase inhibition in 26 aluminum phosphide poisoned patients. Clin Toxicol (Phila). 2006;44(2):155-8.
    摘要:L980: ATSDR - Agency for Toxic Substances and Disease Registry (2002). ToxFAQ for phosphine. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA).
    摘要:A292: Proudfoot AT: Aluminium and zinc phosphide poisoning. Clin Toxicol (Phila). 2009 Feb;47(2):89-100. doi: 10.1080/15563650802520675.
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