CAS: 50-31-7; 2,3,6-Trichlorobenzoic Acid

该化合物是一种芳烃式的碳酸,其特点是苯环上2,3,3和6个位置上存在三个替代氯原子,与箱状酸组相对,该化合物一般是白色的脱白晶体固体,以其在水中的溶性较低而闻名,同时在有机溶剂中更易溶解;它有一个熔点,一般处于中范围,表明其晶体性质;氯原子的存在增强了其回活动,能够影响其生物活动,使其在各个领域,包括农用化学品和制药业中引起兴趣. 2,3,6-三氯苯甲硫酸可以通过苯酸氯化合成,并经常用作其他化学化合物合成的中间体.此外,它显示出可能是有毒或有害的特性,需要在实验室和工业环境中谨慎处理和处置.

结构式图片

欧盟法规

统一分类与标签ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号124-38-9 二氧化碳 | CAS号120-82-1 1,2,4-三氯苯 | CAS号2077-46-5 2,3,6-三氯甲苯 | CAS号4659-47-6 2,3,6-三氯溴苯酚氧酯 | CAS号95-49-8 邻氯甲苯 | CAS号62077-25-2 3,4-二氯-2-甲基苯胺 | CAS号24653-85-8 1,2,4-trichloro... | CAS号32768-54-0 2,3-二氯甲苯 | CAS号186393-28-2 2-methyl-3,4-di... | CAS号108-88-3 甲苯 | CAS号4093-17-8 2,3,6-trichloro...

合成工艺路线路线简述

    📜4-叔丁基甲苯置于aluminum (Iii) Chloride,Iron(Iii) Chloride,氧气,Magnesium Acetate,Cobalt(II) Diacetate Tetrahydrate,氯,Sodium Bromide体系中,用 丙酸,甲苯 作为反应溶剂,30.0~160.0 °C,1.0 Mpa 条件下,反应 14.0H,反应生成 草芽畏
    参考文献:2-甲氧基-3,6-二氯苯甲酸的制备方法
    标题:2-甲氧基-3,6-二氯苯甲酸的制备方法
    摘要:本发明公开了一种2-甲氧基-3,6-二氯苯甲酸的制备方法.本发明的制备方法包括如下步骤:甲醇中,甲醇钠作用下,将2,3,6-三氯苯甲酸进行醚化反应,制得2-甲氧基-3,6-二氯苯甲酸;所述2,3,6-三氯苯甲酸与甲醇钠的摩尔比为1:1~1:10.本发明的制备方法还可包括如式2所述的化合物经过氯化反应,脱除叔丁基或磺酸基的反应,氧化反应制得所述2,3,6-三氯苯甲酸的步骤.本发明的制备方法操作简单,原料价格低廉,生产成本低,后处理方便,反应条件温和,环境友好,收率较高,反应时间较短,适于工业化生产.

    海关参考信息

    专利信息


    专利号:US-6180830-B1
    优先权日:1995-11-08
    标题 :Method for preparing a bimetallic ruthenium/tin catalyst and a process for the synthesis of aldehydes
    发明人:JACQUOT ROLAND
    权利人:RHODIA CHIMIE SA
    摘要:The present invention relates to a new process for the preparation of a bimetallic ruthenium/tin catalyst. The process for the preparation of a bimetallic ruthenium/tin catalyst according to the invention is characterised by the fact that it consists in carrying out the reduction of a ruthenium complex having an electrovalency of -4 and a coordination number of 6, the ligands being either a halogen atom or an anion or a tin halide. The catalyst is further employed for the preparation of aldehydes by reduction, in the vapor phase, of carboxylic acids, esters and anhydrides.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-8183409-B2
    优先权日:2004-05-06
    标题:High yield and rapid synthesis methods for producing metallo-organic salts
    发明人:CHRISTGAU STEPHAN; ANDERSEN JENS E T
    权利人:CHRISTGAU STEPHAN; ANDERSEN JENS E T; OSTEOLOGIX AS
    摘要:A new method for preparing salts of metal cations and organic acids, especially divalent salts of alkaline earth metal ions from group II of the periodic system and carboxylic acids. The method comprising the use of a high temperature (about 90° or more) and, optionally. high pressure, in order to obtain a higher yield, purity and faster reaction speed than obtained with known synthesis methods. In particular, the present invention relates to the production of strontium salts of carboxylic acids. Novel strontium salts are also provided by the present method.

    专利号:US-9999223-B2
    优先权日:2008-05-21
    标 题 :Herbicidal composition comprising glyphosate, glufosinate or their salts
    发明人:SIEVERNICH BERND; MOBERG WILLIAM KARL; SIMON ANJA; WALTER HELMUT; EVANS RICHARD R
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal composition which comprises:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, and b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone]. nn The present invention relates in particular to a herbicidal composition comprising:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone], and c) at least one further herbicide C, which is selected from the herbicide groups C.1 to C.8:n C.1 herbicides of the group of acetolactate synthase inhibitors (ALS inhibitors), C.2 herbicides of the group of protoporphyrinogen oxidase inhibitors (PPO inhibitors), C.3 herbicides of the group of auxines, C.4 herbicides of the group of 4-hydroxyphenyl-pyruvate-dioxygenase inhibitors (HPPD inhibitors), C.5 herbicides of the group of phytoene desaturase inhibitors (PDS inhibitors), C.6 herbicides of the group of photosystem II inhibitors (PSII inhibitors), C.7 herbicides of the group of microtubulin inhibitors, and C.8 herbicides of the group of inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors).

    专利号:US-7375058-B2
    优先权日:2001-09-14
    标 题:Herbicidal mixtures based on 3-phenyluracils
    发明人:ZAGAR CYRILL; SIEVERNICH BERND; QUAKENBUSH LAURA; EVANS RICHARD R; LANDES MAX; NEWSOM LARRY J; ORTLIP CHARLES L; WITSCHEL MATTHIAS; LANDES ANDREAS
    权利人:BASF AG
    摘要:Herbidically active compositions, comprising: A) at least one phenyluracil compound of the formula (I); in which the variables R 1 -R 7 are as defined in the claims, and/or at least one of its agriculturally acceptable salts; and at least one further active compound, selected from B) herbicides of classes b1) to b15): b1) lipid biosynthesis inhibitors; b2) acetolactate synthase inhibitors (ALS inhibitors); b3) photosynthesis inhibitors; b4) protoporphyrinogen-IX oxidase inhibitors; b5) bleacher herbicides; b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7) glutamine synthetase inhibitors; b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9) mitose inhibitors; b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11) cellulose biosynthesis inhibitors; b12) decoupler herbicides; b13) auxin herbicides; b14) auxin transport inhibitors; b15) other herbicides selected from the group consisting of benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin, methyldymron, etobenzanid, fosamine, metam, pyributicarb, oxaziclomefone, dazomet, triaziflam and methyl bromide; and safeners selected from: benoxacor, cloquintocet, cyometrinil, dichlormid, dicyclonon, dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, mefenpyr, mephenate, naplithalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane and oxabetrinil, the agriculturally acceptable salts of the active compounds B and C and the agriculturally acceptable derivatives of the active compounds B and C, provided they have a carboxyl group

    专利号:US-2009137678-A1
    优先权日:2005-07-06
    标 题:High yield synthesis methods for producing organic salts of strontium
    发明人:CHRISTGAU STEPHAN; ANDERSEN JENS E T
    权利人:CHRISTGAU STEPHAN; ANDERSEN JENS E T
    摘要:New organic salts of strontium and methods of synthesizing such salts with high purity, high yields and with short processing times, at neutral conditions and at low reaction temperature, such as a temperature at or below 50° C.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Zhang, H.; Liu, C.; Lei, A., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 144.
    摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 35(10)(14), 1970
    摘要:Pesticide Manual., 9(782), 1991
    摘要:Guide to the Chemicals Used in Crop Protection., 6(515), 1973
    摘要:Frear DS; Herbicides: Chem, Degr and Mode of Action Vol 2. Kearney PC, Kaufman DD eds. Marcel Dekker: NY,NY: p. 541-607 (1976)
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