CAS: 781-43-1; 9,10-Dimethylanthracene

该化合物是炭疽家族的有机化合物,其特点是多环芳烃结构,其特点是9和10个位置的炭疽脊柱上有两个附属于其物理和化学特性的甲基组,该化合物一般是晶状固体,熔点高,具有很强的荧光性,因此对各种应用,包括有机电子和光子具有兴趣. 9,10-二甲基安非他勒苯在水中相对不溶,但在苯和甲苯等有机溶剂中可溶解,其化学稳定性使其得以进行各种反应,包括替代电毒剂,这对芳香化合物很常见.此外,该化合物在开发有机半导体和在生物化学应用中作为荧光探针方面的潜在作用也得到了研究.然而,与许多多环芳烃一样,它可能对环境和健康造成危害,需要小心处理和处置.

结构式图片

相似化合物

779-02-2 7072-00-6 18512-55-5

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

methyl magnesium iodide diethyl ether acetic acid 10-oxo-9,10-dihydro-anthracen-9-yl ester 9,10-dibromomethylanthracene anthracene-9,10-diylbis(methyl) diacetate 9,9,10,10-tetramethyl-9,10-dihydroanthracene 9,10-dimethyl-9,10-ditrityl-9,10-dihydro-anthracene

合成工艺路线路线简述

  • 合成目标产物 9,10-Dimethylanthracene 主要起始原料 9,10-Bis(Chloromethyl)Anthracene
  • (文献来源)合成步骤主要原料 9,10-Bis(Chloromethyl)Anthracene
蒽醌置于盐酸,Magnesium,Tin(Ll) Chloride体系中,用 乙醚,溶剂黄146 作为反应溶剂,化学反应 20.5H,反应生成 9,10-二甲基蒽
参考文献:Complementarity In Bimolecular Photochromism
标题:Complementarity In Bimolecular Photochromism
摘要:在 9,10-二甲基蒽存在的情况下,辐照 2,3,6,7-四苯基蒽会完全形成交叉二聚体.在没有另一种发色团的情况下,辐照这两种发色团中的任何一种,都不会发生光化学反应.
DOI:10.1039/b502183A

海关参考信息

专利信息


专利号:US-2003162992-A1
优先权日:2001-12-14
标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
发明人:WATANABE KYOICHI A; DU JINFA
摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

专利号:US-2005245752-A1
优先权日:2004-04-29
标 题 :Synthesis of unsymmetric anthracene compounds
发明人:CONLEY SCOTT R; COSIMBESCU LELIA; VREELAND WILLIAM B
权利人:EASTMAN KODAK CO
摘要:A process for forming an unsymmetric anthracene compound comprises a first step of forming a 9-perfluoroalkylsulfonate derivative of anthrone by reacting the anthrone with a perfluoroalkyl sulfonating agent, followed by a second step of contacting the reaction product with an aryl or heteroaryl boronic acid, ester or anhydride, and a palladium catalyst for a period of time sufficient to form an unsymmetric anthracene compound having at least one 9-position aromatic substituent.

专利号:US-3919155-A
优先权日:1970-12-18
标题:Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
发明人:SQUIRE EDWARD NOONAN
权利人:DU PONT
摘要:An improved process for producing an aromatic amine is provided in which an aromatic compound is reacted with ammonia in the presence of a conditioned nickel/nickel oxide cataloreactant at a temperature of from about 150*C. to about 500*C. and at a pressure of from about 10 to about 1000 atmospheres and in the presence of from 1 mole percent to 250 mole percent of water based on the molar amount of the aromatic compound.

专利号:US-7144700-B1
优先权日:1999-07-23
标 题 :Photolithographic solid-phase polymer synthesis
发明人:MCGALL GLENN; FALVEY DANIEL E; FIDANZA JACQUELINE A; FELDMAN BRIAN M
权利人:AFFYMETRIX INC
摘要:Methods, employing a polycyclic hydrocarbon or a polycyclic heteroaromatic compound as sensitizers, are provided to increase the efficiency of removing, by irradiation, photolabile protecting groups that mask reactive sites on synthesis intermediaries. Preferred groups of photolabile protecting moieties include: ((α-methyl-2-nitropiperonyl)-oxy)carbonyl (MeNPOC), ((Phenacyl)-oxy)carbonyl (PAOC), O-(9-phenylxanthen-9-yl) (PIXYL), and ((2-methylene-9,10-anthraquinone)-oxy)carbonyl (MAQOC). In conjunction with using the sensitizers and protecting groups described above, a method of forming, from component molecules, a plurality of compounds on a support, each compound occupying a separate predefined region of the support is provided. These resulting solid-phase arrays are useful, for example, to assay for the presence of biochemical products in biological samples.

专利号:US-7973109-B2
优先权日:2007-03-29
标 题 :Crosslinked type layered metal phosphonate compound, production process therefor, non-crosslinked type layered metal phosphonate compound, production process therefor, as well as stock solution
发明人:OGATA SHIN-ICHI; FUKUSHIMA YOSHIAKI; KAWASUMI MASAYA
权利人:TOYOTA CHUO KENKYUSHO KK
摘要:A process for producing a crosslinked type or non-crosslinked type layered metal phosphonate compound including a reaction step of reacting two or more members selected from organic diphosphonic acids or monophosphonic acids, or derivatives thereof having predetermined conditions and a metal source capable of forming an ion of a hexacoordinate metal atom as a central atom (M) of a metal oxide octahedron upon reaction under the presence of a sulfuric acid catalyst, a crosslinked or non-crosslinked metal phosphonate compound obtained by the process, as well as a stock solution used for the synthesis of the crosslinked or non-crosslinked type layered metal phosphonate compound described above.

专利号:CA-2470202-A1
优先权日:2001-12-14
标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
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主要参考文献

[参考文献]: A A Toropov, Et Al. Qspr Modeling Of Octanol/water Partition Coefficient For Vitamins By Optimal Descriptors Calculated With Smiles. Eur J Med Chem. 2008 Apr;43(4):714-40.
[参考文献]: C E Cerniglia, Et Al. Stereoselective Fungal Metabolism Of Methylated Anthracenes. Appl Environ Microbiol. 1990 Mar;56(3):661-8.
[参考文献]: David Plouffe, Et Al. In Silico Activity Profiling Reveals The Mechanism Of Action Of Antimalarials Discovered In A High-Throughput Screen. Proc Natl Acad Sci U S A. 2008 Jul 1;105(26):9059-64.
[参考文献]: E Gross, Et Al. Singlet Oxygen Generation By Porphyrins And The Kinetics Of 9,10-Dimethylanthracene Photosensitization In Liposomes. Photochem Photobiol. 1993 May;57(5):808-13.
[参考文献]: Helen Connelly, Et Al. Immunomodulatory Effects Of Dietary Exposure To Selected Polycyclic Aromatic Hydrocarbons In The Bluegill (Lepomis Macrochirus). Int J Toxicol. 2010 Sep-Oct;29(5):532-45.

合成参考文献


摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 797.
摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 790.
摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 814.
摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 802.
摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 808.
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