专利号:US-2024375965-A1 优先权日:2021-10-04 标 题:MXene compound having novel crystalline morphology, and process for fabricating a compound of MAX phase type for synthesis of said MXene compound 发明人:CHMIELOWSKI RADOSLAW; LARROMONA GERARDO; DELATOUCHE BRUNO; PERE DANIEL 权利人:IMRA EUROPE SAS 摘要:MXene compound having a novel crystalline morphology, and process for fabricating a compound of MAX phase type for synthesis of said MXene compound. The invention firstly relates to a MXene compound advantageously having a crystalline morphology that is mostly in tablet form which may be obtained from a MAX phase precursor obtained by spark plasma sintering process whereby the powders of the mixture are insulated, and to a process for fabricating the MXene compound. The invention also relates to compound of MAX phase type obtained by spark plasma sintering process whereby the powders of the mixture are insulated. The invention also relates to a synthesis process of an MXene compound from said precursor, and to the MXene compound thus obtained advantageously having a crystalline morphology that is mostly in tablet form.
专利号:US-7247287-B2 优先权日:2003-06-11 标 题 :Synthesis of aluminophosphates and silicoaluminophosphates 发明人:CAO GUANG; SHAH MATU J 权利人:EXXONMOBIL CHEM PATENTS INC 摘要:The invention is directed to a method of synthesising silicoaluminophosphate and aluminophosphate molecular sieves using synthesis templates that contain at least one template of general formula R 1 R 2 N—R 3 , wherein R 1 and R 2 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R 3 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms, and 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S. In particular, the present invention relates to the synthesis of silicoaluminophosphate molecular sieves of the CHA framework type having a low silicon to aluminium atomic ratio.
专利号:US-2010016607-A1 优先权日:2006-12-11 标题:Process for the Synthesis of Highly Active Binary Metal Fluoride as a Fluorinating Agent for Aromatics 发明人:DOLBIER JR WILLIAM R; JANMANCHI KRISHNA MURTHY 权利人:UNIV FLORIDA 摘要:The subject invention relates to a process for the synthesis of highly active binary metal fluoride system for the fluorination of aromatic compounds. Fluorinated aromatic compounds are valuable synthons for the chemical synthesis of pharmaceutical drugs and novel polymers. Fluorobenzene is used to control carbon content in steel manufacturing, is an intermediate for pharmaceuticals, pesticides and other organic compounds. Fluorobenzene is typically produced by the reaction of aniline and sodium nitrite in the presence of hydrogen fluoride. The present invention relates to a process for the synthesis of highly active binary metal fluoride system consists of copper (II) fluoride and aluminum (III) fluoride for the fluorination of aromatic compounds in gas phase and recycling of the reagent, in situ, using O 2 and HF.
专利号:US-5096684-A 优先权日:1989-03-31 标题 :Process for the synthesis of precursors of molecular sieves of the silicoaluminophosphate type, precursors obtained and their application to obtaining the said molecular sieves 发明人:GUTH FRANCOISE; KESSLER HENRI; DES COURIERES THIERRY 权利人:ELF FRANCE 摘要:Process for the synthesis of precursors of molecular sieves of the silicoaluminophosphate type by heating to >/=100 DEG C. under autogenous pressure a reaction mixture containing sources of silicon, aluminum and phosphorus in the presence of an organic structuring agent and of hydrofluoric acid. The precursor obtained can be converted into molecular sieve by calcination. Molecular sieves of the silicoaluminophosphate type can be used as adsorbants and catalysts for the conversion of hydrocarbons.
专利号:EP-1308206-A1 优先权日:2001-10-29 标 题:Process for the synthesis of an aluminium modified carbon supported palladium catalyst 发明人:MURTHY JANMANCHI KRISHNA; SHEKAR SRIDARA CHANDRA; RAMARAO KAMARAJU SEETHA; RAJU BURRI DAVID; RAGHAVAN KONDAPURAM VIJAYA 权利人:COUNCIL SCIENT IND RES 摘要:The present invention relates to a process for the synthesis of highly active modifiedncarbon supported palladium catalyst by simultaneously impregnating activated carbon with anpalladium precursor and an aluminium precursor. The carbon supported palladium catalyst isnuseful for the hydrodechlorination of dichlorodifluoromethane to produce difluoromethane.
专利号:US-9714174-B2 优先权日:2012-07-19 标题:Methods of controlling polymorphism in organic-free synthesis of Na-zeolites and zeolite crystals formed therefrom 发明人:RIMER JEFFREY D; MALDONADO MIGUEL; OLEKSIAK MATTHEW D 权利人:RIMER JEFFREY D; MALDONADO MIGUEL; OLEKSIAK MATTHEW D; UNIV HOUSTON SYSTEM 摘要:Methods of controlling crystal polymorphism in organic-free synthesis of Na-Zeolites and the zeolite crystals formed using those methods are provided. The methods disclosed herein create certain types of zeolite crystals more efficiently than other previously known methods. The methods also create certain types of zeolite crystals in a form and concentration not previously disclosed. The methods disclosed herein generally comprise using solutions with varying ratios of silicon (Si), aluminum (Al), hydroxide (OH), and water. Some implementations of the invention disclosed include efficient methods of producing nearly pure cancrinite (CAN), methods of obtaining sodalite in solutions with a high Si/Al ratio, and a method of forming thin, platelet-like ANA crystals with a width of less than about 1 μm and a length of at least about 3 μm.
[参考文献]: C Fritz, Et Al. Preparation And Stabilization Of Aluminium Trifluoroacetate Fluoride Sols For Optical Coatings. Dalton Trans. 2012 Oct 7;41(37):11351-60. [参考文献]: Haroula Koletsi-Kounari, Et Al. An In Vitro Study Of The Effect Of Aluminum And The Combined Effect Of Strontium, Aluminum, And Fluoride Elements On Early Enamel Carious Lesions. Biol Trace Elem Res. 2012 Jun;147(1-3):418-27. [参考文献]: K P Sharma, Et Al. Protective Effect Of Spirulina And Tamarind Fruit Pulp Diet Supplement In Fish (Gambusia Affinis Baird & Girard) Exposed To Sublethal Concentration Of Fluoride, Aluminum And Aluminum Fluoride. Indian J Exp Biol. 2012 Dec;50(12):897-903. [参考文献]: Kan Usuda, Et Al. Comparison Of The Biological Impacts Of The Fluoride Compounds By Graphical Risk Visualization Map Technique. Biol Trace Elem Res. 2015 Sep;167(1):84-90. [参考文献]: Kenji Arita, Et Al. Hydroxyapatite Particle Characteristics Influence The Enhancement Of The Mechanical And Chemical Properties Of Conventional Restorative Glass Ionomer Cement. Dent Mater J. 2011;30(5):672-83.
合成参考文献
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