CAS: 52093-27-3; Praseodymium(Iii) Trifluoromethanesulfonate

该化合物是一种稀土金属三叶酸盐,在有机合成中广泛用作刘易斯酸催化剂,具有很强的电益特性和高热稳定性,能够有效促进Friedel-Crafts 烷基菌,环状体和二尔斯-阿尔德环状添加物等反应;三氟甲烷硫酸酯(OTf) 氮能增加极地有机溶剂的溶解性,有利于同质反应条件;三氟化物(III) 丙烯酸盐与其他酸三增压剂相比,具有抗湿性,可提供更好的处理和储存稳定性;其选择性催化活动和可耐用性使其在精细的化学和制药应用中具有价值;该化合物通常作为白色的离白晶粉粉的粉末供应.

结构式图片

相似化合物

139177-64-3 141478-68-4 139177-62-1

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    专利信息


    专利号:US-11926589-B2
    优先权日:2019-07-09
    标 题 :Process for the synthesis of non-racemic cyclohexenes
    发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
    权利人:BASF CORP; CALIFORNIA INST OF TECHN
    摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

    专利号:US-8119794-B2
    优先权日:2009-03-31
    标 题:Process for the synthesis of ivabradine and addition salts thereof with a pharmaceutically acceptable acid
    发明人:PEGLION JEAN-LOUIS; DESSINGES AIMEE; SERKIZ BERNARD
    权利人:PEGLION JEAN-LOUIS; DESSINGES AIMEE; SERKIZ BERNARD; SERVIER LAB
    摘要:Process for the synthesis of ivabradine of formula (I): n nand addition salts thereof with a pharmaceutically acceptable acid.

    专利号:US-8101747-B2
    优先权日:2009-03-31
    标 题:Process for the synthesis of ivabradine and addition salts thereof with a pharmaceutically acceptable acid
    发明人:PEGLION JEAN-LOUIS; DESSINGES AIMEE; SERKIZ BERNARD
    权利人:PEGLION JEAN-LOUIS; DESSINGES AIMEE; SERKIZ BERNARD; SERVIER LAB
    摘要:Process for the synthesis of ivabradine of formula (I): n nand addition salts thereof with a pharmaceutically acceptable acid.

    专利号:US-10294336-B2
    优先权日:2014-11-27
    标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use
    发明人:KOENIG CHRISTIAN; EMGE ANDREAS; OTERO MARTINEZ IRAN
    权利人:BASF SE
    摘要:The present invention relates to the synthesis of polymer polyols in unsaturated polyols as liquid phase, polymer polyols and their use.

    专利号:WO-2017030685-A1
    优先权日:2015-08-14
    标题 :One-pot synthesis of anhydropentitol mono- and diethers
    发明人:STENSRUD KENNETH
    权利人:ARCHER DANIELS MIDLAND CO
    摘要:A process for preparing anhydropentitol mono- and diethers from C 5 sugar alcohols is described. The process involves performing in a single reaction vessel consolidated reactions that a) cyclize dehydratively a linear C 5 sugar alcohol and b) etherify a resulting anhydropentitol. Each of the reactions is catalyzed by a very low amount of a water-tolerant Lewis acid catalyst relative to the starting sugar-alcohol. Depending on the reaction conditions, the synthesis method is efficient, selective and affords good yields of mono- and diethers. The anhydropentiol ethers can serve as renewable substitute precursors of petroleum incumbents for use in the making of surfactants and plasticizers.

    专利号:WO-2017100402-A1
    优先权日:2015-12-11
    标 题 :One-pot synthesis of anhydropentitol esters from pentitols, catalyzed by water-tolerant lewis acids
    发明人:STENSRUD KENNETH
    权利人:ARCHER DANIELS MIDLAND CO
    摘要:A procedure for preparing anhydropentitol mono, di, and tri esters is described. The process is performed in a single vessel and involves sequential dehydrative cyclization and carboxylic acid acylation steps. Each step is catalyzed by low loadings of a water-tolerant Lewis acid catalyst. The method of synthesis is efficacious and depending on the reaction condition, generates modest to high yields of the target mono-, di-, and triesters. The esters can be practical surrogates of incumbent petroleum materials of similar structure used for surfactants and plasticizers.

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    合成参考文献


    摘要:Dissanayake, P.; Averill, D. J.; Allen, M. J., Science of Synthesis Knowledge Updates, (2011) 4, 7.
    摘要:Spitzner, D., Science of Synthesis Knowledge Updates, (2016) 1, 293.
    摘要:Witt, D., Science of Synthesis Knowledge Updates, (2011) 3, 269.
    摘要:Kobayashi, S., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 1.
    摘要:Ayaz, M.; De Moliner, F.; Morales, G. A.; Hulme, C., Science of Synthesis: Multicomponent Reactions, (2013) 1, 103.
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