CAS: 459-64-3; 4-Methoxybenzenediazonium Tetrafluoroborate

该化合物是一种盐,通常用作有机合成中的一种多用途通合剂,其主要优点包括:在Sandmeyer和Gomber-Bachmann反应中具有高度的再活性,能够将4-甲基苯基组有效引入目标分子中;四氟乙酸对冲可增强稳定性,便于处理和储存,与其他二氮盐相比.在染料,药品和先进材料的合成中,这种化合物特别宝贵,需要对其进行受控的丙烯组转移.其晶晶状固态能够精确地权衡和一致的反应性.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号104-94-9 对甲氧基苯胺 | CAS号51-66-1 4'-甲氧基乙酰苯胺 | CAS号5329-14-6 氨基磺酸 | CAS号74317-32-1 18-crown-6/p-me... | CAS号3762-33-2 (4-甲氧基苯基)膦酸二乙酯 | CAS号1754-49-0 苯基膦酸二乙酯 | CAS号696-62-8 4-碘苯甲醚 | CAS号5335-87-5 4,4'-二甲氧基二苯二硫醚 | CAS号4406-41-1 2-甲基-N-苯基丙酰胺 | CAS号120346-03-4 4-methoxyphenyl... | CAS号620-71-3 N-苯基丙酰胺 | CAS号120346-05-6 S-(4-methoxyphe... | CAS号120346-00-1 4-methoxyphenyl...

合成工艺路线路线简述

    📜甲氧苯胺 反应生成 四氟硼酸-4-甲氧基重氮苯正酯
    参考文献:Yuan,Mu;Zhong,Yuguo;Pang,Qijie;Li,Zhenghua,Xuasi Ikeh Dasyueh Syuehbao,21,(1990) N,S. 310-314
    标题:Yuan,Mu;Zhong,Yuguo;Pang,Qijie;Li,Zhenghua,Xuasi Ikeh Dasyueh Syuehbao,21,(1990) N,S. 310-314

    海关参考信息

    专利信息


    专利号:CN-117623998-A
    优先权日:2023-12-05
    标 题:Application of perfluorocarbon sulfur-based silver reagent in synthesis of aryl perfluoroethyl sulfide

    专利号:US-5300675-A
    优先权日:1993-06-29
    标 题 :Process for synthesizing substituted cinnamic acid derivatives
    发明人：ELANGO VARADARAJ
    权利人:HOECHST CELANESE CORP
    摘要:This invention discloses a novel process for preparing cinnamic acid derivatives. The inventive process is illustrated by the synthesis of 2-ethylhexyl p-methoxycinnamate by coupling p-methoxybenzenediazonium tetrafluoroborate with 2-ethylhexyl acrylate in an alcohol solution, wherein a buffer compound such as sodium acetate is present, the coupling reaction being catalyzed by a mixture comprising a copper salt, such as cuprous chloride, and a palladium salt, such as Li 2 PdCl 4 .

    专利号:US-7122694-B2
    优先权日:1998-11-06
    标 题 :Hydroboronation process
    发明人：MARCUCCIO SEBASTIAN MARIO; RODOPOULOS MARY; WEIGOLD HELMUT
    权利人:BORON MOLECULAR PTY LTD
    摘要:The invention relates to processes for the synthesis of aryl or alkene borates which comprises reacting: (i) an olefinic compound having a halogen or halogen-like substituent in a vinylic substitution position, or (ii) an aromatic ring having a halogen or halogen-like substituent in a ring substitution position, with a disubstituted monohydroborane in the presence of a Group 8-11 metal catalyst. The invention also relates to the use of these borates in coupling reactions. The invention further relates to certain disubstituted monohydroboranes and aryl or alkene borates.

    专利号:CN-110698483-A
    优先权日:2019-10-29
    标 题:Synthesis of a 2-sulfonyl-9H-pyrrolo[1,2-a]indole compound

    专利号:CN-116751174-A
    优先权日:2023-06-07
    标题 :Synthesis method of aryl substituted 1,3, 4-oxadiazole derivative

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    主要参考文献

    参考标题:Process For Synthesizing Substituted Cinnamic Acid Derivatives
    摘要:This Invention Discloses A Novel Process For Preparing Cinnamic Acid Derivatives. The Inventive Process Is Illustrated By The Synthesis Of 2-Ethylhexyl P-Methoxycinnamate By Coupling P-Methoxybenzenediazonium Tetrafluoroborate With 2-Ethylhexyl Acrylate In An Alcohol Solution, Wherein A Buffer Compound Such As Sodium Acetate Is Present, The Coupling Reaction Being Catalyzed By A Mixture Comprising A Copper Salt, Such As Cuprous Chloride, And A Palladium Salt, Such As Li.Sub.2 Pdcl.Sub.4.

    合成参考文献


    摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 45, 232.
    摘要:Joule, J. A., Science of Synthesis Knowledge Updates, (2010) 2, 240.
    摘要:Götzinger, A. C.; Müller, T. J. J., Science of Synthesis Knowledge Updates, (2017) 3, 60.
    摘要:Kleoff, M.; Omoregbee, K.; Zimmer, R., Science of Synthesis Knowledge Updates, (2018) 4, 225.
    摘要:Kleoff, M.; Omoregbee, K.; Zimmer, R., Science of Synthesis Knowledge Updates, (2018) 4, 222.
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