1-phenyl-3-thiosemicarbazidewaternitrogen(II) oxideNitrogen dioxide(1-)triiodide(1-)titanium(IV)nitrogenchromate(VI) ion
合成工艺路线路线简述
五氧化二氮 反应生成硝酸钾 参考文献:Haszpra L.; Turanyi T.,Idojaras,90,(1986) N 6,332-338 标题:Haszpra L.; Turanyi T.,Idojaras,90,(1986) N 6,332-338
专利信息
专利号:US-11926589-B2 优先权日:2019-07-09 标 题 :Process for the synthesis of non-racemic cyclohexenes 发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND 权利人:BASF CORP; CALIFORNIA INST OF TECHN 摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.
专利号:US-11866398-B2 优先权日:2018-05-15 标 题:Total synthesis of prostaglandin J natural products by stereoretentive metathesis 发明人:LI JIAMING; CHEN XU; AHMED TONIA S; STOLTZ BRIAN M; GRUBBS ROBERT H 权利人:CALIFORNIA INST OF TECHN 摘要:This invention relates generally to the synthesis of Δ12-Prostaglandin J product using stereoretentive ruthenium olefin metathesis catalysts supported by dithiolate ligands. Δ12-Prostaglandin J products were generated with excellent selectivity (>99% Z) and in moderate to high/good yields (47% to 80% yield; 58% to 80% yield).
专利号:WO-2004087313-A1 优先权日:2003-03-31 标题:Catalyst for synthesis of hydrocarbons from synthesis gas, process of preparation of catalyst 发明人:PANDULA SAMUEL; MAITY SUDIP; DASANDHI YOGESH CHANDRA; MUKHERJEE SOMNATH; MAITRA SANDIP KUMAR 权利人:COUNCIL SCIENT IND RES 摘要:The present invention relates to a catalyst useful in the synthesis of hydrocarbons from synthesis gas. The present invention also relates to a process for the preparation of a catalyst useful for the production of hydrocarbons from synthesis gas. The present invention particularly relates to preparation of a catalyst for production of wax from synthesis gas. The invention finds its usage in synthesising hydrocarbons, specifically wax, using Fisher-Tropsch Synthesis.
专利号:US-10597358-B2 优先权日:2015-01-16 标题:Synthesis of carbamate or urea compounds 发明人:VAN DER HEIJDEN ANTONIUS EDUARD DOMINICUS MARIA; VAN GEEST ERIK; VAN DEN ELSHOUT JOS JOHAN MATTHIJS HUGO 权利人:TNO 摘要:The invention pertains to the synthesis of carbamate and urea compounds. In particular the invention is directed to the synthesis of carbamate and urea compounds which may be used in the production of compounds that are used to stabilize nitrocellulose. The method of the invention comprises preparing a carbamate or urea derivative comprising reacting an amine and a carbonate or carbamate in the presence of an ionic liquid.
专利号:US-2018265547-A1 优先权日:2014-07-18 标 题 :Z-selective olefin metathesis of peptides 发明人:MANGOLD SHANE L; GRUBBS ROBERT H 权利人:CALIFORNIA INST OF TECHN 摘要:The invention relates generally to the synthesis of modified amino acids and modified peptides in the presence of cyclometalated catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.
专利号:US-2018297857-A1 优先权日:2015-06-02 标 题:Aqueous Synthesis of Polyhedral 'Brick-Like' Iron Oxide Nanoparticles for Hyperthermia and T2 MRI Contrast Enhancement, and for Targeting Endothelial Cells for Therapeutic Delivery 发明人:HEGMANN TORSTEN; WORDEN MATTHEW; MILLER DONALD W 权利人:UNIV KENT STATE OHIO 摘要:A low temperature, aqueous synthesis of polyhedral iron oxide nanoparticles (IONPs) is presented. The modification of the co-precipitation hydrolysis method with Triton X surfactants results in the formation of crystalline polyhedral particles. The particles are herein termed iron oxide “nanobricksâ€? (IONBs), as the varieties of particles made are all variations on a simple “brick-likeâ€?, polyhedral shape such as rhombohedral shape or parallelogram as evaluated by TEM. These IONBs can be easily coated with hydrophilic silane ligands, allowing them to be dispersed in aqueous media. The dispersed particles are investigated for potential applications as hyperthermia and T 2 MRI contrast agents. The results demonstrate that the IONBs perform better than comparable spherical IONPs in both applications, and show r 2 values amongst the highest for iron oxide based materials reported in the literature.
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