专利号:US-5194410-A 优先权日:1991-11-15 标题:Crystalline molecular sieve synthesis using quaternary ammonium-functionalized organosiliconate 发明人:CALABRO DAVID C 权利人:MOBIL OIL CORP 摘要:This invention relates to a method for preparing crystalline silicates such as zeolites from a forming mixture containing quaternary ammonium-functionalized organosiliconate as a directing agent. The products prepared depend, inter alia, on reaction conditions such as temperature, crystallization time, and pH. More particularly, this invention relates to the use of a quaternary ammonium-functionalized organosiliconate in the preparation of ZSM-5, ZSM-48, ZSM-51 and the ZSM-48 composition thus prepared.
参考文献:10.1007/s10971-020-05343-7 摘要:Matsumoto T, Kaneko Y. Correlation between molecular structures and reaction conditions (temperature–pressure–time) in the preparation of secondary, tertiary, and quaternary ammonium-functionalized polyhedral oligomeric silsesquioxanes. Journal of Sol-Gel Science and Technology. 2020 Jun 18;95(3):670–81. doi: 10.1007/s10971-020-05343-7.