CAS: 73250-68-7; Mefenacet
该化合物是一种化学化合物,其独特的结构特征包括苯异氮酸盐和乙酰胺功能组,该化合物通常具有芳香化合物和热循环化合物的特性,有助于其潜在的生物活动,经常研究其药理特性,特别是在医药化学方面,该物质可能具有反炎或止热活动等影响.青蒿素环的存在会增强其亲脂性,从而影响其在生物系统中的吸收和分布.此外,N-甲基和N-苯替代物会影响其与生物目标的结合性.与许多有机化合物一样,其溶性,稳定性和再活性可能因诸如pH和温度等环境条件而不同.
- 英文名称Mefenacet
- 中文名称苯噻草胺
- IUPAC名称2-(Benzothiazol-2-yloxy)-N-methyl-N-phenylacetamide
- 其它别名2-(2-Benzothiazolyloxy)-N-methyl-N-phenylacetamide; Hin°Chloa
- CAS编号73250-68-7
- MFCD编号:MFCD00078691
- EINECS号:277-328-8
- FDA UNII编号:QI0QTA02DG
- 分子式:C16H14N2O2S分子量:298.36
- 产品CID: 1719176
- 产品分类有机原料→分子砌块→芳杂环类化合物→苯并噻唑类化合物
物理性质
MSDS等安全信息
欧盟法规
统一分类与标签ECHA物质ECHA物质C&L通报REACH预注册废弃物危险特性清单上下游产品
CAS号1310-58-3 氢氧化钾 | CAS号615-20-3 2-氯苯并噻唑 | CAS号42404-09-1 N-甲基羟基乙酰苯胺合成工艺路线路线简述
- 合成目标产物 Mefenacet 主要起始原料 2-Benzothiazolol And 2-Chloro-N-Methyl-N-Phenylacetamide
- (文献来源)合成步骤主要原料 2-Benzothiazolol 和 2-Chloro-N-Methyl-N-Phenylacetamide
📜2-氨基苯硫醇置于sodiumsulfide Nonahydrate,Sodium Hydroxide体系中,用 N-甲基吡咯烷酮 作为反应溶剂,化学反应 28.0H,反应生成 苯噻酰草胺
参考文献:利用苯并噻唑酮与2-卤代-N-甲基-N-苯基乙酰胺制备农药苯噻草胺的方法
标题:利用苯并噻唑酮与2-卤代-N-甲基-N-苯基乙酰胺制备农药苯噻草胺的方法
摘要:本发明提供一种利用苯并噻唑酮与2‑卤代‑n‑甲基‑n‑苯基乙酰胺制备苯噻草胺的方法,步骤如下:首先利用co2作为羰基化试剂合成苯并噻唑酮,然后与碱液反应得到苯并噻唑酮的盐溶液,最后与2‑卤代‑n‑甲基‑n‑苯基乙酰胺反应得到苯噻草胺.本发明为苯噻草胺的工业生产提供了一种新路径,缩短了传统方法的合成路线,本工艺实现了co2的化学利用,有利于节能减排,更符合绿色化学的理念.
海关参考信息
- 2912110000-甲醛
2912120000-乙醛
2922110001-单乙醇胺
2924199090-其他无环酰胺 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人：ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.
专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人：DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.
专利号:US-11919928-B2
优先权日:2016-03-16
标题 :Method for producing dihydrotentoxin
发明人：KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
权利人:KUMIAI CHEMICAL INDUSTRY CO
摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.
专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人：KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.
专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人：KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.
专利号:UY-34940-A
优先权日:2012-07-24
标题 :HERBICIDE COMPOSITIONS CONTAINING 4-AMINO-3-CHLORO-5-FLUOR-6- (4-CHLORO-2-FLUOR-3-METOXY-PHENYL) ACID-2-CARBOXYL, OR A DERIVATIVE OF THE SAME AND THE HERBICIDES THAT INHIBIT THE SYNTHESIS OF THE VERY LONG CHAIN FATTY ACIDS AND THE SYNTHESIS OF THE FAT / LIPID ACIDS
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Liu ZY, Guo HQ, He H, Yang SG, Sun C. [Sorption and desorption behavior of the herbicide mefenacet on soils]. Huan Jing Ke Xue. 2009 Jun 15;30(6):1756-61. Chinese. doi: 10.1016/j.ecoenv.2013.03.023. Epub 2013 Apr 15. doi: 10.1107/S1600536810044284.
5: Ye YF, Min H, Du YF. Characterization of a strain of Sphingobacterium sp. and its degradation to herbicide mefenacet. J Environ Sci (China). 2004;16(2):343-7. doi: 10.1016/j.ecoenv.2010.05.008. Chinese. doi: 10.1016/j.jhazmat.2010.01.025. Epub 2010 Jan 13. doi: 10.1016/j.talanta.2005.09.020. Epub 2005 Oct 13. Chinese. doi: 10.1016/j.chroma.2009.01.093. Epub 2009 Feb 2. doi: 10.1007/s00244-009-9364-1. Epub 2009 Jul 17. doi: 10.1002/ps.4934. Epub 2018 Jun 1. Erratum in: Korean J Intern Med. 2012 Dec;27(4):483.
18: Chang GR, Chen HS, Lin FY. Analysis of banned veterinary drugs and herbicide residues in shellfish by liquid chromatography-tandem mass spectrometry (LC/MS/MS) and gas chromatography-tandem mass spectrometry (GC/MS/MS). Mar Pollut Bull. 2016 Dec 15;113(1-2):579-584. doi: 10.1016/j.marpolbul.2016.08.080. Epub 2016 Sep 6. doi: 10.1016/j.ecoenv.2018.10.028. Epub 2018 Oct 26. doi: 10.1007/s10661-008-0701-z.
合成参考文献
参考文献:10.3904/kjim.2008.23.1.42
摘要:Shim YS, Gil HW, Yang JO, Lee EY, Kim SH, Hong SY. A case of green urine after ingestion of herbicides. Korean J Intern Med. 2008 Mar;23(1):42–4.
参考文献:10.1107/s1600536810044284
摘要:Cheon S, Kim TH, Moon SH, Kim J. Mefenacet [2-(1,3-benzothia-zol-2-yl-oxy)-N-methyl-N-phenyl-acetamide]. Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 13;66(Pt 12):o3153.
参考文献:10.1002/ps.786
摘要:Kuk YI, Kim KH, Kwon OD, Lee DJ, Burgos NR, Jung S, Guh JO. Cross‐resistance pattern and alternative herbicides for Cyperus difformis resistant to sulfonylurea herbicides in Korea. Pest Management Science. 2003 Nov 03;60(1):85–94. doi: 10.1002/ps.786.
参考文献:10.1007/s11248-005-0199-x
摘要:Kawahigashi H, Hirose S, Ozawa K, Ido Y, Kojima M, Ohkawa H, Ohkawa Y. Analysis of substrate specificity of pig CYP2B22 and CYP2C49 towards herbicides by transgenic rice plants. Transgenic Res. 2005 Dec;14(6):907–17. doi: 10.1007/s11248-005-0199-x.
参考文献:10.1016/j.chemosphere.2008.04.062
摘要:Wei D, Lin Z, Kameya T, Urano K, Du Y. Application of biological safety index in two Japanese watersheds using a bioassay battery. Chemosphere. 2008 Jul;72(9):1303–8. doi: 10.1016/j.chemosphere.2008.04.062.
📝 需求与反馈
尽可能描述清楚需求与问题信息
