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      专利号:US-2016207894-A1
      优先权日:2013-10-17
      标 题:Synthesis of Diacids, Dialdehydes, or Diamines from THF-Diols
      发明人:STENSRUD KENNETH
      权利人:ARCHER DANIELS MIDLAND CO
      摘要:A simple and elegant chemical process for the synthesis of oxygenated products, such as acids and aldehydes, or other derivative products, such as amines and nitriles, of cyclic bifunctional molecules made from renewable, bio-based sources such as HMF and/or its reduction product, 2,5-bis(hydroxymethyl)-tetrahydrofuran (bHMTHF) is described. In general, the process involves: a) generating a tetrahydrofuran-2,5-diyl-bis(methylene)-bis(sulfonate) from bHMTHFs using a sulfonate; b) displacing nucleophilically at least a sulfonate leaving group from the tetrahydrofuran-2,5-diyl-bis(methylene)-bis(sulfonate) to form a THF-dinitrile; and either c) oxidizing the THF-dinitrile with an acid having a pKa of ≦0 to generate a di-acid, or d) reducing partially the THF-dinitrile to generate a di-aldehyde, or e) reducing fully the THF-dinitrile to generate a di-amine.

      专利号:US-4222996-A
      优先权日:1979-10-01
      标 题:Preparation of gold cyanide
      发明人:OKINAKA YUTAKA; SMITH LAWRENCE E
      权利人:BELL TELEPHONE LABOR INC
      摘要:A synthesis of gold (I) cyanide is described which exhibits high yields and does not yield toxic gases (e.g., HCN). Gold (I) cyanide is important as a source of gold for gold plating baths. A synthesis of AuCN that does not involve evolution of toxic gases (e.g., HCN) is highly advantageous because no disposal problem is involved and the procedure is simpler and more straightforward.

      专利号:US-9556123-B2
      优先权日:2004-07-19
      标题:Synthesis of triethylenetetramines
      发明人:JONAS MARCO; VAULONT IRENE; SOI ANTONIO; SCHMIDT GUNTHER
      权利人:PHILERA NEW ZEALAND LTD
      摘要:Methods and intermediates for synthesizing triethylenetetramine and salts thereof, as well as novel triethylenetetramine salts and their crystal structure, and triethylenetetramine salts of high purity.

      专利号:US-10384201-B2
      优先权日:2016-02-17
      标题:Direct synthesis method of nanostructured catalyst particles on various supports and catalyst structure produced by the same
      发明人:JEONG NAMJO; KIM CHAN-SOO; JWA EUN-JIN; CHOI JI YEON; NAM JOO-YOUN; PARK SOON-CHUL; JANG MOON-SEOK; SEO YONG SEOK; HWANG KYO SIK; KIM HAN KI; HAN JI HYUNG; KIM TAE YOUNG; YOON YOUNG GI
      权利人:KOREA INST ENERGY RES
      摘要:Disclosed is a direct synthesis method of nanostructured catalyst particles on surfaces of various supports. In the disclosed synthesis method of a catalyst structure having a plurality of nanostructured catalyst particles dispersed in a support by a one-step process using a high-temperature high-pressure closed reactor, the one-step process includes supplying the support and a catalyst source into the high-temperature high-pressure closed reactor; supplying an atmosphere forming gas of the reactor into the reactor; perfectly sealing the high-temperature high-pressure closed reactor and heating the reactor to produce the catalyst structure in the reactor under self-generated pressure and synthesis temperature conditions, the catalyst structure including the plurality of nanostructured catalyst particles dispersed in the support; removing internal gases of the reactor to allow the reactor to be in a high-temperature, atmospheric pressure state and supplying an inert gas into the reactor to remove unreacted materials and byproducts remaining in the reactor; and cooling the reactor to room temperature while supplying the inert gas to synthesize the catalyst structure.

      专利号:US-2020148647-A1
      优先权日:2004-07-19
      标题:Synthesis of Triethylenetetramines

      专利号:US-8450235-B2
      优先权日:2007-10-26
      标题 :Supported composite particle material, production process of same and process for producing compounds using supported composite particle material as catalyst for chemical synthesis
      发明人:SUZUKI KEN; YAMAGUCHI TATSUO
      权利人:SUZUKI KEN; YAMAGUCHI TATSUO; ASAHI KASEI CHEMICALS CORP
      摘要:A supported composite particle material comprises: a composite particle formed of an oxidized nickel and X (wherein X represents at least one of elements selected from the group consisting of nickel, palladium, platinum, ruthenium, gold, silver and copper); and a support on which the composite particle is supported, the supported composite particle material having a supported layer in which the composite particle is localized.

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      合成参考文献


      参考文献:10.1007/978-3-031-06825-6_4
      摘要:Tiganea OC, Vigotti F. Community-Driven Initiatives for Heritage Acknowledgement, Preservation and Enhancement in European Marginal Area. 2022. In: Lecture Notes in Networks and Systems.
      参考文献:10.1007/978-981-99-0260-6_10
      摘要:Nakayama N, Goto H. Molecular Crystal Calculation Prospects for Structural Phase Transitions. 2023. In: The Materials Research Society Series.
      参考文献:10.1007/s43153-023-00326-x
      摘要:Li J, Chen S, Chen Y, Hu X, Zi F. Method for improving adsorption capacity of gold(I) thiosulfate complex on mercapto-functionalized silica gel by masking copper with ethylenediamine. Braz. J. Chem. Eng. 2023 Apr 18;41(1):325–37. doi: 10.1007/s43153-023-00326-x.
      参考文献:10.1007/s11270-023-06593-1
      摘要:Yan J, Li Z, Liu X, Qian P, Liu X, Ye S. Thiocyanate Removal from Aqueous Solution by a Synthetic CoAl-Layered Double Hydroxide with Nitrate Intercalation. Water Air Soil Pollut. 2023 Aug 23;234(9). doi: 10.1007/s11270-023-06593-1.
      参考文献:10.2991/978-94-6463-415-0_63
      摘要:Li G, Meng W, Shi B, Wang J, Zhu X, Chen Y, Zhang X. Process mineralogy detection and analysis of a cyanide tailings. 2024. In: Atlantis Highlights in Engineering.
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