CAS: 2245-30-9; 2-(Tert-Butyl)Oxirane

📜3,3-二甲基-1-丁烯置于过氧乙酸体系中,化学反应生成3,3-二甲基-1,2-环氧丁烷
参考文献:使用空间效应和电子效应的比较来推断涉及三元环状中间体的逐步亲电加成反应中的机理信息
标题:使用空间效应和电子效应的比较来推断涉及三元环状中间体的逐步亲电加成反应中的机理信息
摘要:Ip与烯烃与arscl,Meco 3 H,Ag +或hgcl 2的反应的相对反应性或形成常数的相关性表明,络合反应显示出空间依赖性,第一步确定反应速率的加成反应是空间独立的,并且第二步的速率确定在空间上是依赖的.
Doi:10.1016/s0040-4039(00)82306-0

专利信息

专利号:US-2005239767-A1
优先权日:2003-10-28
标题 :Intermolecular SNAr of the heterocycle-activated nitro and fluoro groups-application in the synthesis of polyazamacrocyclic ligands
发明人：CHAN MICHAEL K; FEKNER TOMASZ
权利人:CHAN MICHAEL K; FEKNER TOMASZ
摘要:A new class of tetracylic benzimidazole compounds and derivatives thereof. Additionally provided is a synthetic route for the generation of these and related compounds via Intramolecular Aromatic Nucleophilic Substitution (S N Ar) of the Benzimidazole-Activated Nitro Groups. Additionally, a facile route for the generation of novel phenol species as thermal decomposition of compounds the S N Ar product, which occurs at high temperature resulting in cleavage of the ether linkage and formation of a vinyl group and phenol is provided. Also provided are methods of using the compounds described herein in the treatment HIV.

专利号:US-4339612-A
优先权日:1980-03-05
标题:Preparation of 3,3-dimethyl-1-phenoxy-butan-2-ols as fungicide intermediates
发明人：KRANZ ECKART; SIEGLE PETER
权利人:BAYER AG
摘要:3,3-Dimethyl-1-phenoxy-butan-2-ols of the formula ##STR1## in which Y is a halogen atom, an optionally substituted phenyl radical, an optionally substituted phenoxy radical or a nitro, cyano, alkyl, alkoxy, alkoxycarbonyl or cycloalkyl radical, and n is 0, 1, 2 or 3, n exhibit plant growth stimulating properties and are also useful in the synthesis of known fungicides. They are produced from tert-butyloxirane and the corresponding phenols.

专利号:US-7220870-B2
优先权日:1995-03-14
标 题:Hydrolytic kinetic resolution of cyclic substrates
发明人：JACOBSEN ERIC N; TOKUNAGA MAKOTO; LARROW JAY F
权利人:HARVARD COLLEGE
摘要:The present invention relates to a process for stereoselective or regioselective chemical synthesis which generally comprises reacting a nucleophile and a chiral or prochiral cyclic substrate in the presence of a non-racemic, chiral catalyst to produce a stereoisomerically- and/or regioisomerically-enriched product. The present invention also relates to hydrolytic kinetic resolutions of racemic and diastereomeric mixtures of epoxides.

专利号:WO-2024056715-A1
优先权日:2022-09-15
标 题:Epoxidation of porous amine-based phenylic polymer resins and methods of use for carbon dioxide capture
发明人：WANG HAO; ALBANI DAVIDE; AZTIRIA TOMAS; AMORUSO GIORDANO
权利人:SVANTE TECH INC; CLIMEWORKS AG
摘要:A solid epoxidized aminated porous phenylic polymer without the use of a porous silica support structure is described herein along with its method of synthesis and its application to the adsorption of carbon dioxide (CO2) from a feed gas. As compared to the prior art, this epoxidized porous aminated phenylic polymer is lower cost and exhibits improved long-term stability and reliability to degradation by oxygen at the elevated temperatures of temperature swing adsorption of CO2 and subsequent desorption at temperatures in the range of 120°C or greater. In addition, the active materials of this solid adsorbent do not leach from the polymer when exposed to water or condensing steam at the elevated temperatures of temperature swing adsorption. An illustrative example of the use of 1,2-propylene oxide (epoxypropane) to epoxidize a solid porous phenylic aminated resin substrate based upon a simple one-step reaction at room temperature is described herein. This epoxidized IER exhibits approximately a three-fold improvement in lifetime upon exposure to oxygen in dry air at 110°C-120°C as compared to the non-epoxidized polymeric starting material.

专利号:CN-114605641-B
优先权日:2022-03-18
标题 :A kind of preparation method and its product and application of in-situ initiation synthesis of sulfur-containing polymer by nanofiller

专利号:US-7625988-B2
优先权日:2003-06-20
标 题:Flame retardant polymers having pendant groups related to bisphenol-C and monomers for synthesis thereof
发明人：TOUR JAMES M; JURS JOSHUA L; STEPHENSON JASON J
权利人:UNIV RICE WILLIAM M
摘要:The present invention is directed to novel flame retardant monomers and polymers, wherein the flame retardant properties of the polymers are provided by functionality in pendant groups attached to a polymer backbone (as opposed to the polymer backbone itself possessing flame retardant properties. The present invention is also directed to methods of making such polymers and monomers, and articles of manufacture incorporating such monomers and polymers.