CAS: 1074-51-7; Cyclooctanone Oxime

该化合物是一种循环氢氧基胺衍生物,其特点是由八人组成的环状结构,具有独特的回活动性和稳定性.该化合物主要用作有机合成的中间体,特别是在形成硝基苯或协调化学中作为离子体.其硬性环烷基框架加强了反应的消毒控制,改善了复杂转化中的选择性.该化合物在环境条件下的稳定性使其适合储存和处理实验室环境.此外,其明确界定的结构允许可预测的再活动,便利其在机械研究和催化应用中的使用. N-Cyclocloctimedidenydydroxylamine因其在合成和工业化学中的多功能而备受重视.

结构式图片

相似化合物

502-49-8 2158-31-8 100-64-1

上下游产品

cycloactanone Cyclo°Ctan α-Chlorcyclo°Ctanonoxim chlorineO-picryl oxime )cyclo°Ctanone-(O-picryl oxime ) 2-azacyclononanone °Ct-7-enenitrile cyclo°Ctylamine

合成工艺路线路线简述

    📜环辛烷置于亚硝酸特丁酯,N-羟基邻苯二甲酰亚胺,溶剂黄146体系中,化学反应 6.0H,以65%的收率获得环辛酮肟
    参考文献:从环烷烃制备内酰胺前体的新途径:使用亚硝酸叔丁酯和n-羟基邻苯二甲酰亚胺直接生产亚硝基环烷烃或环烷酮肟.
    标题:从环烷烃制备内酰胺前体的新途径:使用亚硝酸叔丁酯和n-羟基邻苯二甲酰亚胺直接生产亚硝基环烷烃或环烷酮肟.
    摘要:
    Doi:10.1002/anie.200352741

    专利信息


    专利号:US-4365027-A
    优先权日:1981-12-28
    标 题 :Removal of acrylonitrile from latex with oximes
    发明人:SENYEK MICHAEL L; COSTANZA ALBERT J
    权利人:GOODYEAR TIRE & RUBBER
    摘要:Acrylonitrile is a monomer that is widely used in the synthesis of a vast variety of polymers. Undesirable quantities of unpolymerized residual acrylonitrile are often present in these acrylonitrile polymers. This residual or free acrylonitrile dissolved in an acrylonitrile polymer and/or its emulsifier system and the water phase used in its polymerization can be reduced significantly in concentration by treatment with oximes. Oximes react with acrylonitrile by an oxygen-cyanoethylation reaction which results in the formation of a cyanoethyl oximino ether linkage.

    专利号:WO-2024146948-A1
    优先权日:2023-01-05
    标题:Peptide synthesis method involving sterically hindered tri-tert-butyl-tryptophan (tbt) residue
    发明人:EKSTEEN JACOBUS JOHANNES; SVENDSEN JOHN SIGURD; MALMEDY FLORENCE; GUEVARA JONATHAN
    权利人:AMICOAT AS
    摘要:The invention is directed to a method of peptide synthesis comprising reacting a compound of Formula (I) or a salt thereof with a carbodiimide reagent to form an O-acylisourea intermediate; reacting the O-acylisourea intermediate with an additive to form an activated ester; and reacting the activated ester with an amino-containing moiety which is an amino acid, a peptide or a salt thereof comprising an amino group, wherein the amino group forms an amide bond with the carbonyl marked * in Formula (I); wherein the compound of Formula (I) has the structure: and wherein R1 and R2 are as defined in the disclosure. The invention is also directed to a compound of Formula (III) as defined in the disclosure or a salt thereof.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Chiba, S.; Narasaka, K., Science of Synthesis Knowledge Updates, (2011) 4, 454.
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