
MSDS等安全信息
- GHS象形图



- GHS符号GHS08 & GHS07 & GHS09;
注释: Health hazard & Exclamation mark & Environment - 危险类别致癌性 类别1B
致突变性 类别2
特定目标器官毒性-单次接触 类别1
特定目标器官毒性-重复接触 类别2
皮肤致敏 类别1
水生慢性毒性 类别2
急性毒性 类别3(经口)
水生急性毒性 类别1
水生慢性毒性 类别1
急性毒性 类别4(经口)
严重眼刺激 类别2 - 警示词Danger(危险)
- 危险描述H350 |可能致癌.
H341 |怀疑导致遗传缺陷.
H370 |损害器官.
H373 |长期或反复接触可能损害器官.
H317 |可能引起皮肤过敏反应.
H411 |对水生生物有毒并具有长期持续影响.
H301 |吞咽会中毒.
H400 |对水生生物毒性极大.
H410 |对水生生物毒性极大并具有长期持续影响.
H302 |吞咽有害.
H319 |造成严重眼刺激. - 防范说明P203, P260, P261, P264, P270, P272, P273, P280, P302+P352, P308+P316, P318, P319, P321, P333+P317, P362+P364, P391, P405, and P501
- UN编号2651.0
- 危险品标志T:Toxic;N:Dangerousfortheenvironment;
- 安全声明S53-S45-S61
- 危险类别码R43,R45,R48/20/21/22,R51/53,R39/23/24/25
- WGK Germany3
欧盟法规
《欧盟PIC法规》统一分类与标签压力设备指令-第1组危险流体REACH注册ECHA物质食品接触材料-禁用CMR物质OtherC&L通报欧盟授权物质清单REACH预注册欧盟《致癌物和致突变物指令》废弃物危险特性清单"欧盟管控危险化学品"工作场所安全标识要求ECHA物质化妆品禁用物质清单欧盟候选物质清单上下游产品
CAS号1817-74-9 4,4'-二硝基二苯基甲烷 | CAS号50-00-0 甲醛 | CAS号2719-05-3 4,4'-二乙酰胺基二苯基甲烷 | CAS号2915-44-8 1,1'-Methyleneb... | CAS号98-95-3 硝基苯 | CAS号71840-36-3 chloromethylmer... | CAS号622-14-0 N,N'-diphenylme... | CAS号142-04-1 苯胺盐酸盐 | CAS号101-65-5 N,N’-[亚甲基二(4,1-... | CAS号1092-56-4 Benzene,1,1'-me... | CAS号1092-55-3 Benzene,1,1'-me... | CAS号457-68-1 双(4-氟苯基)甲烷 | CAS号92-62-6 吖啶-3,6-二胺 | CAS号184170-01-2 N-[4-[(4-acetam... | CAS号192586-42-8 1-pyridin-2-yl-... | CAS号2536-05-2 2,2'-亚甲基二苯基二异氰酸酯 | CAS号101-68-8 4,4'-亚甲基双(异氰酸苯酯) | CAS号5873-54-1 1-异氰酸根-2-[(4-异氰...6,6'-双氨基-3,3'-甲叉基二苯甲酸置于盐酸体系中,化学反应生成4,4'-二氨基二苯甲烷
参考文献:Heller Et Al.,Justus Liebigs Annalen Der Chemie,1902,Vol. 324,P. 134 Anm. 17
标题:Heller Et Al.,Justus Liebigs Annalen Der Chemie,1902,Vol. 324,P. 134 Anm. 17
专利信息
专利号:US-4801744-A
优先权日:1985-03-01
标 题 :Catalytic synthesis of urea from carbon monoxide and amine compound
发明人:HERMAN JEAN-JACQUES; LECLOUX ANDRE
权利人:SOLVAY
摘要:Process for the catalytic synthesis of nitrogen-containing organic compounds, comprising the reaction of carbon monoxide with at least one amino compound in a reaction mixture containing a catalyst based on selenium and a substituted pyridine. The process is particularly suitable for the synthesis of ureas and of their polymers.
专利号:US-9957355-B2
优先权日:2013-06-12
标 题 :Device and method for synthesis of a polymer under separation of a gaseous substance
发明人:ZHU NING; STAMMER ACHIM; CLAUSS JOACHIM; KORY GAD
权利人:BASF SE
摘要:The invention relates to a device for synthesis of a polymer under separation of a gaseous substance. Said device comprises a reaction chamber ( 1 ), which has a top section ( 11 ), a middle section ( 12 ) and a bottom section ( 13 ), an inlet opening ( 2 ) which is arranged in the middle section ( 12 ), a first outlet opening ( 3 ) which is arranged in the bottom section ( 13 ), a second outlet opening ( 4 ) which is arranged in the top section ( 11 ), a first return opening ( 51 ), which is arranged in the bottom section ( 13 ), a second outlet opening ( 52 ), which is arranged under the top section ( 11 ), a distribution device ( 6 ), which is arranged between the top section ( 11 ) and the middle section ( 12 ), and a removal device ( 7 ) which is arranged to be movable along the top section ( 11 ). The invention further relates to a method for synthesis of a polymer which can be carried out in said device.
专利号:US-7423171-B2
优先权日:2006-06-20
标题 :One-step catalytic process for the synthesis of isocyanates
发明人:SERRANO FERNANDEZ FRANCISCO LU; ALMENA MUNOZ BEATRIZ; PADILLA POLO ANA; OREJON ALVAREZ ARANCHA; CLAVER CABRERO CARMEN; CASTILLON MIRANDA SERGIO; SALAGRE CARNERO PILAR; AGHMIZ ALI
权利人:REPSOL YPF SA
摘要:A one-pot process for the synthesis of isocyanates, polyisocyanates or mixtures thereof which includes the steps of:n i. preparing a mixture comprising an amine, an alcohol, an oxygen-containing gas, carbon monoxide, a metal complex catalyst selected from the group consisting of macrocyclic complex catalysts and cobalt Shiff base catalysts; and a solvent selected from the group consisting of aliphatic or aromatic halocarbons, perhalogenated alcohols, halogenated ethers, halogenated ketones, perfluorinated hydrocarbons, polymers of chlorotrifluoroethylene having the formula —(CF 2 —CFCl) n wherein n is between 2 and 10, and mixtures thereof; ii. subjecting the resulting mixture to a first heating under pressure; iii. cooling and depressurizing the mixture resulting from the previous step; and iv. subjecting the mixture of the previous step to a second heating to separate out the isocyanate product from the mixture.
专利号:WO-2024208875-A1
优先权日:2023-04-03
标题:Organic reinforcement of a polyamide with the in situ synthesis of a polyimide phase by reactive extrusion
发明人:CASSAGNAU PHILIPPE; DELAGE KARIM; BOUNOR-LEGARE VÉRONIQUE; MARESTIN CATHERINE; DUBOIS CHARLOTTE; GAROIS NICOLAS
权利人:TOTALENERGIES ONETECH; UNIV CLAUDE BERNARD LYON 1 UCBL; CENTRE NAT RECH SCIENT; UNIV JEAN MONNET SAINT ETIENNE UJM; INSTITUT NAT DES SCIENCES APPLIQUEES DE LYON INSA LYON
摘要:The disclosure relates to a reinforced polyamide and to a process to produce a reinforced polyamide comprising providing components being one or more polyamides, one or more dianhydrides, and one or more diamines; wherein the one or more polyamides are provided at a content of at least 60 wt.% based on the total weight of the components and wherein the one or more polyamides comprise at least one polyamide having amide groups separated by at least 10 CH2 groups; performing in situ synthesis of a polyimide by reactive extrusion of the components wherein the residence time is less than 10 minutes; and recovering a polyamide-polyimide blend being a reinforced polyamide comprising a continuous polyamide phase and a polyimide dispersed phase.
专利号:US-4472568-A
优先权日:1981-11-12
标 题:Process for the preparation of polyamines from N-monoaryl-N',N'-dialkyl urea compounds and their use for the synthesis of polyurethanes
发明人:RASSHOFER WERNER; GROEGLER GERHARD
权利人:BAYER AG
摘要:This invention relates to an improved process for the preparation of aromatic polyamines containing urethane and/or biuret and/or urea and/or isocyanurate groups and preferably also ether groups by the hydrolysis of poly-N-monoaryl-N',N'-dialkyl urea compounds (1-aryl-3,3-dialkyl ureas). The ureas are obtained by the reaction of secondary aliphatic, cycloaliphatic or saturated heterocyclic amines with divalent to tetravalent isocyanate compounds containing isocyanate end groups attached to aromatic residues. The ureas correspond to the general formula: wherein R1, R2 denote alkyl or cycloalkyl groups, or together form a ring and A denotes a divalent to tetravalent residue attached to the ureas by aromatic groups. Hydrolysis is carried out in the presence of water and up to two equivalents of a base containing hydroxide ions and/or up to two equivalents of a compound containing tertiary amino groups, optionally in the presence of solvents. The use of the polyamines obtained by this process for the synthesis of polyurethanes is also described.
专利号:US-9631051-B2
优先权日:2013-06-12
标 题:Device for the synthesis of a polymer with extraction of a gaseous substance comprising a reaction chamber having at least one circular-cylindrical section
发明人:ZHU NING; STAMMER ACHIM; CLAUSS JOACHIM; KORY GAD
权利人:BASF SE
摘要:An apparatus for synthesis of a polymer with separation of a gaseous substance comprises a reaction space having an essentially circular cylindrical upper section which is bounded by two circular faces and one shell face and has a longitudinal cylinder axis, and a lower section, an inlet orifice disposed in a circular face or the shell face of the upper section, a first outlet orifice disposed in a wall of the lower section, a second outlet orifice disposed in the shell face of the upper section opposite the first outlet orifice, and a removal device which is disposed so as to be rotatable about the longitudinal cylinder axis and is in contact with both circular faces and the shell face. This apparatus can especially be used for performance of a process including the feeding of an oligomer melt into a reaction space through an inlet orifice, the polymerization of the oligomer melt to give a polymer melt, the removal of the polymer melt from the reaction space through a first outlet orifice of the reaction space, and the removal of a gaseous substance from the reaction space through a second outlet orifice of the reaction space, wherein deposits on at least one inner wall of the reaction space are removed by a removal device and transported into the oligomer melt.