Alpha-(乙酰亚肼基)苯乙酰肼置于水体系中,用 乙醇 作为反应溶剂,化学反应 12.0H,以123 G (76% Of Theory) Of 4-Amino-3-Methyl-6-Phenyl-1,2,4-Triazin-5-(4H)-One Of Melting Point 160°-163oc. Were Obtained的收率获得产物苯嗪草酮 参考文献:4-Amino-1,2,4-Triazin-5-Ones 标题:4-Amino-1,2,4-Triazin-5-Ones 摘要:该文段的翻译如下: 该式的新型甘醛酸肼基-2-酰肼酮:##str1## 其中r1为氢或烷基,R2为烷基或可选择取代的苯基.通过将相应的甘醛酸酯2-酰肼酮与肼水合物反应制备出(I)化合物.这些化合物(I)在制备除草活性的4-氨基-1,2,4-三嗪-5-酮化合物方面有用.
专利号:WO-2024256370-A1 优先权日:2023-06-13 标 题 :Synthesis of glufosinate using an amidase-based process 发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.
专利号:US-4360479-A 优先权日:1980-07-04 标题:Process for the preparation of acyl cyanide compounds 发明人:FINDEISEN KURT; KRAETZER HANS; LENTHE MANFRED 权利人:BAYER AG 摘要:This invention relates to a new process for the preparation of acyl cyanides of the general formula n n R.sup.1 --CO--CN (I) n n wherein R 1 is an optionally substituted alkyl radical up to 18 carbon atoms, an optionally substituted cycloalkyl radical with 3 to 12 carbon atoms, an optionally substituted aryl radical or an optionally substituted 5- or 6-membered heterocyclic radical, which can additionally also be fused with a benzene ring, which process comprises reacting a carboxylic acid anhydride of the formula n n R.sup.1 --CO--O--CO--R.sup.1 (II) n n with an alpha-hydroxynitrile of the formula ##STR1## in which R 2 and R 3 are identical or different and represent a hydrogen atom, an optionally substituted alkyl radical with 1 to 18 carbon atoms, an optionally substituted cycloalkyl radical with 3 to 12 carbon atoms, an optionally substituted aryl radical or an optionally substituted 5- or 6-membered heterocyclic radical, which can additionally also be fused with a benzene ring. The acyl cyanides (I) are known compounds and can be used as starting material for the synthesis of herbicides.
专利号:US-4555370-A 优先权日:1980-04-23 标题 :Process for the preparation of acyl cyanides 发明人:KLAUKE ERICH; FINDEISEN KURT 权利人:BAYER AG 摘要:A novel process for the preparation of acyl cyanides of the general formula R-CO-CN (I) wherein R represents an optionally substituted alkyl radical with 1 to 8 carbon atoms, an optionally substituted cycloalkyl radical with 3 to 12 carbon atoms, an optionally substituted aryl radical or an optionally substituted 5-membered or 6-membered heterocyclic radical, which can additionally be fused to a benzene ring, in which a carboxylic acid fluoride or the general formula R-CO-F (II) in which R has the abovementioned meaning is reacted with an alkali metal cyanide, optionally in the presence of a diluent, at a temperature between 10 DEG and 200 DEG C. The acylcyanides (I) can be used as intermediates in the synthesis of known herbicides.
专利号:US-2025120400-A1 优先权日:2021-12-10 标题:Synthesis of glufosinate using a hydantoinase-based process 发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.
专利号:US-11919928-B2 优先权日:2016-03-16 标题 :Method for producing dihydrotentoxin 发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI 权利人:KUMIAI CHEMICAL INDUSTRY CO 摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.
专利号:US-2021386068-A1 优先权日:2018-11-07 标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides 发明人:KISTER JEREMY; SATCHIVI NORBERT M 权利人:CORTEVA AGRISCIENCE LLC 摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.
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合成参考文献
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