CAS: 4090-60-2; 5,5-Dimethyl-1,3,2-Dioxaphosphinane 2-Oxide

该化合物是一种循环有机磷化合物,其特点是六人组成的二氧磷环状结构,五分之一的石化二甲基组的存在增强了其消毒稳定性,而二分之一的磷(P=O)功能有助于其在协调化学和催化过程中的活性.这一复合物对合成应用具有兴趣,因为它在磷含量材料的制作中能够发挥离心或中间作用,其硬性循环框架和电子饱和特性使它适合进行不对称合成研究,并成为先进的分子结构的建筑块.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

2,2-Dimethyl-1,3-propanediol phosphonic acid diethyl ester phosphinic acid 3-hydroxy-2,2-dimethyl-propyl ester 5,5-dimethyl-2-H-1,3,2-dioxaphosphorinane 5-[1,3,2]dioxaphosphinan-2-yl)-cyclohexyl]-hydrazineN-Cyclohexylidene-N'-[1-(5,5-dimethyl-2-oxo-2λ5-[1,3,2]dioxaphosphinan-2-yl)-cyclohexyl]-hydrazine 2-Oxo-2-(α-propylamino-benzyl)-5,5-dimethyl-PV-1,3,2-dioxaphosphorinan 5-[1,3,2]dioxaphosphinan-2-yl)-cyclohexyl]-N'-[1-phenyl-meth-(Z)-ylidene]-hydrazineN-[1-(5,5-Dimethyl-2-oxo-2λ5-[1,3,2]dioxaphosphinan-2-yl)-cyclohexyl]-N'-[1-phenyl-meth-(Z)-ylidene]-hydrazine 5-[1,3,2]dioxaphosphinan-2-yl)-phenyl-methyl]-N'-[1-phenyl-meth-(E)-ylidene]-hydrazineN-[(5,5-Dimethyl-2-oxo-2λ5-[1,3,2]dioxaphosphinan-2-yl)-phenyl-methyl]-N'-[1-phenyl-meth-(E)-ylidene]-hydrazine

合成工艺路线路线简述

  • 合成目标产物 5 5-Dimethyl-1 3 2-Dioxaphosphorinan-2-& 主要起始原料 Neopentyl Glycol
  • (文献来源)合成步骤主要原料 Neopentyl Glycol
2-氯-5,5-二甲基-1,3,2-二氧磷杂环己烷置于水,三乙胺体系中,用 四氢呋喃,苯 作为反应溶剂,化学反应生成 5,5-二甲基-1,3,2-二氧磷杂环己烷-2-酮
参考文献:环状有机磷化合物.一,环状亚磷酸氢酯和硫代亚磷酸酯的合成及红外光谱研究
标题:环状有机磷化合物.一,环状亚磷酸氢酯和硫代亚磷酸酯的合成及红外光谱研究
摘要:已经设计了导致环状亚磷酸氢酯的一般合成程序.研究了溶剂对环状亚磷酸氢酯和硫代亚磷酸酯的 P==o 和 P-H 红外伸缩模式的影响.结论是环状亚磷酸氢盐的缔合归因于偶极-偶极相互作用而不是氢键.
DOI:10.1139/v67-411

海关参考信息

专利信息


专利号:US-2017267706-A1
优先权日:2014-08-19
标 题:Method for the synthesis of heterocyclic hydrogen phosphine oxide
发明人:BRUYNEEL FREDERIC; NOTTE PATRICK PIERRE
权利人:STRAITMARK HOLDING AG
摘要:A method for the synthesis of a heterocyclic hydrogen phosphine oxide, having the general formula: n n n n n n n n n n wherein:n nR is a aliphatic or aromatic divalent group optionally including one or more heteroatoms and optionally having one or more substituents andn nX and Y are independently selected from —O—, —C(O)O— and —NR′—n nwherein R′ is a monovalent group optionally having one or more heteroatoms including the steps of:n na) forming a reaction mixture by mixing a compound having the general formula HX—R—YH and tetraphosphorus hexaoxide; andn nb) recovering the resulting compound comprising the heterocyclic hydrogen phosphine oxide.

专利号:US-12291489-B2
优先权日:2016-07-01
标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition
发明人:BISWAS PRATIM; RALIYA RAMESH
权利人:BISWAS PRATIM; RALIYA RAMESH; WASHINGTON UNIVERSITY ST LOUIS
摘要:The present disclosure is related to the development of improved fertilizer for precision and sustainable agriculture. A method was developed wherein efficient NPK nanocomposite for plant nutrition was synthesized in a single step using aerosol science and technology concepts. Further a formulation was prepared by addition of ZnO, TiO 2 and other nanoparticles to the NPK nanocomposite. Also, an aerosol based foliar application technique was developed for the precise delivery of nanoparticles to the plants.

专利号:US-2019202750-A1
优先权日:2016-07-01
标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition

专利号:US-7709465-B2
优先权日:2006-05-19
标 题:Phosphorous containing compounds including triphenylmethylphosphonate esters for the treatment of melanoma and other cancers
发明人:HERGENROTHER PAUL J; NESTERENKO VITALIY; PUTT KARSON S; PALCHAUDHURI RAHUL
权利人:UNIV ILLINOIS
摘要:Compounds and related methods for synthesis, and the use of compounds and combination therapies for the treatment of cancer and modulation of apoptosis in cells are disclosed. Particularly disclosed are phosphonate esters. Compounds, methods of making the compounds, medicaments and method of manufacture of medicaments and therapeutic methods with applications against cancer including breast cancer, melanoma, colon cancer, leukemia and lymphoma, and other cancer cells are described.

专利号:EP-3183258-A1
优先权日:2014-08-19
标 题:Method for the synthesis of heterocyclic hydrogen phosphine oxide

专利号:WO-2016026871-A1
优先权日:2014-08-19
标 题:Method for the synthesis of heterocyclic hydrogen phosphine oxide
维赛诺化学技术(北京)有限公司
⚠️ 未注册 · 未认证企业
⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
数据来源于公开网络搜索,平台未作核实,请自行辨别。
🏢敬请 企业认领
🏬开设公司展台
📢获取免费会员权益
🎖️点亮专属注册企业标签
📇展现公司完整信息 样本查看立即注册认领 →
网址: http://www.vscichem.com
企业联系电话:13811761079👤
📞维赛诺化学技术(北京)有限公司 ⚠️参考联系方式
联系人:黎经理
电话:13811761079
手机:13811761079

邮箱:vscichem@163.com
通信地址: 北京市石景山八大处高科技园区西井路3号3号楼5575房间
邮编: 102600
🆔 联系时候可告知是从"百琢研"平台获取的信息.
⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

地址:北京市石景山八大处高科技园区西井路3号3号楼5575房间
⚠️ 未注册 · 未认证企业
注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
第 1 / 1 页

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Kashemirov, B. A.; Błażewska, K.; Justyna, K.; Lyu, J.; McKenna, C. E., Science of Synthesis Knowledge Updates, (2021) 1, 416.
摘要:Chen, T.; Li, C.; Han, L.-B., Science of Synthesis: Cross-Dehydrogenative Coupling, (2023) nan, 521.
📝 需求与反馈
尽可能描述清楚需求与问题信息
×

通知