CAS: 3151-41-5; Tribenzyl(Chloro)Stannane

该化合物是一种有机锡化合物,其特点是有3个苯基组和与中央锡原子相连接的氯原子,该化合物主要用于有机合成和催化,作为生产其他有机锡衍生物的多用途中间体,在标准条件下保持稳定,且定义明确的再活性使它成为选择性转化(包括交叉组合和聚合反应)的宝贵试剂;苯基化合物增强有机溶剂的溶性,便于合成应用的处理;三氯氯丁基锡还被用于改变表面特性的材料科学以及协调化学作为离子前体,建议妥善处理,因为其潜在毒性.

结构式图片

上下游产品

benzylmagnesium chloride benzyl chloride acetyl chloride tinethyl-tribenzyl stannane iodomethylbenzene tribenzyltin hydride

合成工艺路线路线简述

    📜乙基三苄基锡烷置于盐酸体系中,化学反应生成 三苄基氯化锡
    参考文献:Kipping,F. B.,Journal Of The Chemical Society,1928,Vol. 131,P. 2365-2373
    标题:Kipping,F. B.,Journal Of The Chemical Society,1928,Vol. 131,P. 2365-2373

    海关参考信息

    专利信息


    专利号:US-6624116-B1
    优先权日:1998-09-03
    标 题 :On-line synthesis and regeneration of a catalyst used in autothermal oxidation
    发明人:BHARADWAJ SAMEER S; MAJ JOSEPH J; SIDDALL JONATHAN H
    权利人:DOW GLOBAL TECHNOLOGIES INC
    摘要:An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.

    专利号:US-8329923-B2
    优先权日:2010-06-17
    标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
    发明人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
    权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
    摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

    专利号:WO-0014037-A1
    优先权日:1998-09-03
    标题:On-line synthesis and regeneration of a catalyst used in autothermal oxidation

    专利号:US-6166283-A
    优先权日:1998-09-03
    标题:On-line synthesis and regenerating of a catalyst used in autothermal oxidation

    专利号:CN-1316982-A
    优先权日:1998-09-03
    标 题 :On-line synthesis and regeneration of catalysts used in autothermal oxidation

    专利号:CN-1168688-C
    优先权日:1998-09-03
    标 题 :On-line synthesis and regeneration of catalyst used in autothermal oxidation

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Prehled Prumyslove Toxikologie; Organicke Latky, Marhold, J., Prague, Czechoslovakia, Avicenum, 1986, -(1254), 1986
    摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/S_schafer851.pdf
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