专利号:US-6479599-B1 优先权日:1997-04-04 标题:Catalyst system for high yield synthesis of polyolefins 发明人:PEIL KEVIN P; WILSON DAVID R 权利人:BP CHEM INT LTD 摘要:This invention relates to a supported metallocene catalyst system for the high yield synthesis of polyolefins, to methods of preparation of the catalyst system, to polymerization processes which use the catalyst system and to polyolefin polymers produced by the polymerization processes.
专利号:US-4565896-A 优先权日:1984-10-22 标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas 发明人:KNIFTON JOHN F; DURANLEAU ROGER G 权利人:TEXACO INC 摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.
专利号:US-4609768-A 优先权日:1984-10-22 标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent 发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J 权利人:TEXACO INC 摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.
专利号:US-4568780-A 优先权日:1984-10-22 标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane 发明人:KNIFTON JOHN F 权利人:TEXACO INC 摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silane or germane-containing promoter dispersed in a hydrocarbon solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi, where the particular solvents used allow the desired product to be separated from the reaction mixture by phase separation.
专利号:US-2024239924-A1 优先权日:2021-04-30 标题:Synthesis of sulfonyl halide terminated polyethylene 发明人:BROONER RACHEL E M; SENECAL TODD D; KEAN ZACHARY S 权利人:DOW GLOBAL TECHNOLOGIES LLC 摘要:Methods for preparing end-functionalized polyolefin, The methods include polymerizing one or more olefin monomers in the presence of an aluminum chain transfer agent to produce a polymeryl aluminum species; treating the polymeryl aluminum species with sulfur oxide compound at a reactor temperature to form a polymeryl sulfinate; and oxidizing the polymeryl sulfinate; wherein the end-functionalized polyolefin comprises a polymer backbone having at least 30 carbon atoms; and the end-functionalized polyolefin comprises a sulfur containing group,
专利号:WO-2024100281-A1 优先权日:2022-11-10 标题:Solution-based synthesis of composites. 发明人:RYAN KEVIN M; COLLINS GEAROID 权利人:UNIV LIMERICK 摘要:A method for synthesizing an Si and/ or Ge NW/carbon composite in a solution-based approach is provided. The method comprises combining (i) a mixture of a lithium alloying metal and a carbon particle, (ii) an Si and/or Ge precursor and (iii) a refluxing solvent under reflux conditions and reacting to form the composites.
[参考文献]: E Mullane, Et Al. Synthesis Of Silicon-Germanium Axial Nanowire Heterostructures In A Solvent Vapor Growth System Using Indium And Tin Catalysts. Phys Chem Chem Phys. 2015 Mar 14;17(10):6919-24. [参考文献]: Grace Flynn, Et Al. Solvent Vapor Growth Of Axial Heterostructure Nanowires With Multiple Alternating Segments Of Silicon And Germanium. Nano Lett. 2016 Jan 13;16(1):374-80.
合成参考文献
摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 24. 摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 50. 摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 73. 摘要:Marschner, C., Science of Synthesis Knowledge Updates, (2020) 3, 120. 摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 5.