CAS: 60648-70-6; Bis(Tri-T-Butylphosphine)Platinum (0)

该化合物是一个以白金为主要金属原子的协调化合物,作为与三甲基丁基硫磷,和的三甲基丁基磷相协调的中央金属原子,该化合物通常具有成平方平方平面几何学,这是许多(II)复合体的特征;三乙基苯丙基磷的离心机有助于综合体的整体稳定性和不动性,影响其再活性和溶性.白金复合体因其催化特性而闻名,特别是在有机合成和工业应用中,包括氢化和交叉相联反应.散丁基聚物群的存在可以增加反应的选择性,提供抑制性障碍,在某些催化过程中具有优势.此外,对药用化学,特别是抗癌剂的开发,对丙基苯基甲基基苯基甲基磷具有兴趣.

结构式图片

上下游产品

CAS号67901-08-0 trans-bis(tri-t... | CAS号67871-27-6 trans-PtHBr[P(t... | CAS号67870-05-7 trans-[PtH2(P(t... | CAS号85931-06-2 | CAS号85944-38-3 | CAS号10025-99-7 氯亚铂酸钾 | CAS号13716-12-6 三叔丁基膦 | CAS号67950-30-5 bis(tri-tert-bu... | CAS号81476-54-2 trans-PtH(ONO2)... | CAS号67871-28-7 trans-PtH(CF3CO...

合成工艺路线路线简述

    📜Bis(Tri-Tert-Butyl-L5-Phosphanyl)Platinum(Iv) Hydride Iodide置于koh Or Naome体系中,用 苯 作为反应溶剂,以>99的收率获得产物二(三叔丁基膦)铂(0)
    参考文献:Goel,Ram G.; Oginl,William O.; Srivastava,Ramesh C.,Organometallics,1982,Vol. 1,# 6,P. 819-824
    标题:Goel,Ram G.; Oginl,William O.; Srivastava,Ramesh C.,Organometallics,1982,Vol. 1,# 6,P. 819-824

    专利信息


    专利号:US-9914695-B2
    优先权日:2015-07-10
    标题:Two-step process for preparing 3-substituted phenylalkylamines
    发明人:Teramura Doug; LIAO SUBO
    权利人:MALLINCKRODT LLC
    摘要:Processes for preparing 3-substituted phenylalkylamines comprising reacting a phenyl boronic compound with an α-β unsaturated carbonyl-containing compound via an asymmetric 1,4-addition reaction, followed by reductive alkylation. The processes may be useful in the synthesis of tapentadol.

    专利号:US-9556108-B2
    优先权日:2014-07-10
    标题 :Process for preparing substituted phenylalkanes
    发明人:LIAO SUBO; MCCLURG JOSEPH; TRAWICK BOBBY
    权利人:MALLINCKRODT LLC
    摘要:The invention provides methods for preparing substituted phenylalkanes. In particular, the processes comprise reacting a phenyl boronic compound with an α-β unsaturated carbonyl-containing compound via an asymmetric 1,4-addition reaction. The processes may be useful in the synthesis of tapentadol.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Vrána, J.; Růžička, A., Science of Synthesis Knowledge Updates, (2021) 2, 38.
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