专利号:US-4988806-A 优先权日:1988-06-13 标 题:Nitrogen-containing derivatives of carboxymethylcellulose, their synthesis and their use in cosmetic preparations 发明人:GRUENING BURGHARD; HOFFMANN KLAUS; KOERNER GOETZ; KOLLMEIER HANS-JOACHIM 权利人:GOLDSCHMIDT AG TH 摘要:Derivatives of carboxymethylcellulose are disclosed in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula in which R1 is a hydrogen or methyl group, R2 is a divalent aliphatic hydrocarbon group with 2 to 5 carbon atoms, R3, R4 are alkyl groups with 1 to 4 carbon atoms, R5 is an alkyl group with 1 to 4 carbon atoms or a benzyl group, X is a halogen or sulfate group or a sulfonic acid group, with the proviso that, on the average, at least 0.1 quaternary ammonium groups are contained per anhydroglucose unit of the polymeric molecule. The invention furthermore relates to derivatives of carboxymethylcellulose, in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula in which the substituents R1, R2, R3 and R4 have the above meaning, with the proviso that, on the average, at least 0.1 tertiary amino groups are contained per anhydroglucose unit of the polymeric molecule, as intermediates for the synthesis of the aforementioned derivatives. The invention furthermore is directed to a method for the synthesis of the derivatives of carboxymethylcellulose and their use in cosmetic preparations, especially for the care of hair.
专利号:US-5023246-A 优先权日:1988-06-13 标 题:Betaine group-containing derivatives of carboxymethylcellulose, their synthesis and their use in cosmetic preparations 发明人:GRUENING BURGHARD; HOFFMANN KLAUS; KOERNER GOETZ; KOLLMEIER HANS-JOACHIM 权利人:GOLDSCHMIDT AG TH 摘要:Betain group-containing derivatives of carboxymethylcellulose are disclosed. They are characterized in that all or a portion of the carboxymethyl groups are or is replaced by groups of the general formula wherein R1 is hydrogen or methyl group, R2 is a divalent aliphatic hydrocarbon group with 2 to 5 carbon atoms, R3, R4 is an alkyl group with 1 to 4 carbon atoms, R5 is a divalent aliphatic hydrocarbon group with 1 to 10 carbon atoms, with the proviso that, on the average, at least 0.1 betaine groups are contained for each anhydroglucose unit of the polymeric molecule. Also, a method for the synthesis of these compounds and their use in cosmetic preparations, especially for the care of hair, are disclosed. In addition, novel derivatives of carboxymethylcellulose with tertiary amino groups are taught as intermediates. In these derivatives, all or a portion of these groups are or is replaced by groups of the general formula in which the substituents R1, R2, R3 and R4 have the above meaning, with the proviso that, on the average, at least 0.1 tertiary amino groups are contained per anhydroglucose unit of the polymeric molecule.
专利号:US-4412075-A 优先权日:1981-01-16 标题 :Process for the preparation of quinolin-4-ones 发明人:BAUDOUIN MICHEL; DESBOIS MICHEL 权利人:RHONE POULENC SANTE 摘要:1,2,3,4-Tetrahydroquinolin-4-ones of the formula: ##STR1## wherein R represents a hydrogen or halogen atom, an alkyl radical (1 to 4 carbon atoms), an alkoxy radical (1 to 4 carbon atoms) or the trifluoromethyl radical, and R 1 represents a hydrogen atom, an alkyl radical (1 to 4 carbon atoms) or the trifluoromethyl radical, are prepared by cyclizing a 3-anilinopropionic acid of the formula: ##STR2## (wherein R and R 1 are as hereinbefore defined) in a mixture of hydrofluoric acid and boron trifluoride. n The quinolinone products are useful intermediates in the synthesis of therapeutically active substances.
专利号:US-2013102730-A1 优先权日:2010-04-02 标 题:Polyamine-containing polymers and methods of synthesis and use 发明人:JOST ROBERT W; ULUDAG HASAN; BOLUK MEHMET YAMAN 权利人:JOST ROBERT W; ULUDAG HASAN; BOLUK MEHMET YAMAN; ALBERTA INNOVATES TECHNOLOGY FUTURES 摘要:The present invention relates to polyamine-containing polymers and methods of their synthesis and use. The polymer may be hydroxyethylcellulose, dextran, poly(vinyl alcohol) or poly(methyl acrylate).
专利号:US-6417195-B1 优先权日:1999-02-22 标题 :Isoquinoline derivatives and isoquinoline combinatorial libraries 发明人:LEBL MICHAL 权利人:LION BIOSCIENCE AG 摘要:The present invention provides the synthesis of heterocyclic compounds based on the isoquinoline ring. More specifically, the invention provides novel isoquinoline derivatives as well as novel libraries comprised of such compounds.
摘要:Joule, J. A., Science of Synthesis Knowledge Updates, (2018) 2, 34. 摘要:Scholz, U.; Dong, W.; Feng, J.; Shi, W., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 2, 76. 摘要:Adriaensen, K.; De Vos, D., Science of Synthesis, (2022) , 167. 摘要:J. C. Gage. J. Chem. Soc. 1949, 1458.