CAS: 13991-08-7; 1,2-Bis(Diphenylphosphino)Benzene

上下游产品

CAS号829-85-6 二苯基膦 | CAS号583-53-9 1,2-二溴苯 | CAS号367-11-3 邻二氟苯 | CAS号1079-66-9 氯代二苯基膦 | CAS号861892-41-3 [CuBr(1,2-bis(d... | CAS号583-55-1 2-溴碘苯 | CAS号603-35-0 三苯基膦 | CAS号17154-34-6 二苯基(三甲基硅基)膦 | CAS号615-36-1 2-溴苯胺 | CAS号829-85-6 二苯基膦 | CAS号14221-01-3 四(三苯基膦)钯(0) | CAS号111189-30-1 (1,2-bis(diphen... | CAS号121-46-0 2,5-降冰片二烯 | CAS号28516-49-6 palladium,triph... | CAS号713-36-0 2-甲基二苯甲烷 | CAS号88682-33-1 (2-diphenylphos... | CAS号88682-53-5 (2-diphenylphos...

(二苯基膦基)三甲基锡烷置于lithium Chloro-Isopropyl-Magnesium Chloride,甲基锂体系中,用 四氢呋喃,乙醚 用作溶剂,化学反应 7.0H,反应生成1,2-双(二苯基膦基)苯
参考文献:在arynes中通过c-P和c-Sn键形成邻三烷基锡烷基芳基膦
标题:在arynes中通过c-P和c-Sn键形成邻三烷基锡烷基芳基膦
摘要:一种新颖和有效的方法来邻位由就地与stannylated膦生成arynes的反应-Trialkylstannyl Arylphosphanes(r 3 Sn的 Pr 2)进行说明.并发ç P和c Sn键的形成具有高的收率发生,并且stannylated产品很容易转化成有价值的邻位-取代的arylphosphanes.该反应具有高效率,非常好的区域选择性和优异的实用性的特征.
Doi:10.1002/anie.201509329

专利信息

专利号:WO-0125179-A1
优先权日:1999-10-01
标 题:Preparation of tetracyclic intermediates
发明人：CHEN QING PING; WOODS ROSS ALEXANDER; ELLIOTT ROBYN LOUISE
权利人:INST OF DRUG TECHNOLOGY AUSTRA; CHEN QING PING; WOODS ROSS ALEXANDER; ELLIOTT ROBYN LOUISE
摘要:The invention provides a process for preparing deoxytetracyclic compounds of formula (I) useful in the synthesis of anthracyclines by the rearrangement of thiono ester derivatives followed by reduction, as well as intermediates useful therefor. In said formula, R is H or optionally protected OH.

专利号:US-7538061-B2
优先权日:2001-05-18
标题 :One-step production of 1,3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst
发明人：KNIFTON JOHN FREDERICK; JAMES TALMADGE GAIL; SLAUGH LYNN HENRY; WEIDER PAUL RICHARD; ALLEN KEVIN DALE; POWELL JOSEPH BROUN
权利人:SHELL OIL CO
摘要:Disclosed is a new catalyst composition comprising a bimetallic Co—Fe catalyst, optionally complexed with a ligand selected from a N-heterocycle, phosphine, or porphorine ligand, that provides a lower cost alternative for the one step synthesis of 1,3-propanediol (1,3-PDO) from ethylene oxide and synthesis gas. For example, a catalyst containing cobalt carbonyl: iron carbonyl with no ligand, or a catalyst containing a cobalt carbonyl: octaethylporphine iron acetate provide moderate yields of 1,3-PDO in a one step synthesis under mild conditions.

专利号:US-6166226-A
优先权日:1996-10-10
标题 :Synthesis of aryl ethers
发明人：BUCHWALD STEPHEN L; WOLFE JOHN P; PALUCKI MICHAEL
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:A method for preparing an aryl ether compound is provided in which an alcohol is reacted with an aromatic compound in the presence of a base, and a transition metal catalyst selected from the group consisting of platinum and nickel to form an aryl ether. The aromatic compound comprises an activated substituent, X, said activated substituent being a moiety such that its conjugate acid HX has a pKa of less than 5.0. The catalyst is preferably a soluble palladium complex in the presence of supporting ligands.

专利号:US-5831128-A
优先权日:1996-12-04
标题 :Synthesis of aromatic amines from chloroamatics
发明人：BELLER MATTHIAS; RIERMEIER THOMAS; REISINGER CLAUS PETER; HERRMANN WOLFGANG ANTON; GEISSLER HOLGER
权利人:HOECHST AG
摘要:The present invention relates to a process for the preparation of aromatic amines of the formula (I) n n Ar--NR.sup.1 R.sup.2 (I) n n in which Ar is ##STR1## and R 3 to R 9 independently of one another are hydrogen, C 1 -C 8 -alkyl, alkoxy-(C 1 -C 8 ), acyloxy-(C 1 -C 8 ), OAr, Ar, fluorine, chlorine, bromine, iodine, OH, NO 2 , CN, CO 2 H, CHO, SO 3 H, SO 2 R, SOR, NH 2 , NH-alkyl-(C 1 -C 12 ), N-alkyl 2 -(C 1 -C 12 ), NHCO-alkyl-(C 1 -C 12 ), CO-alkyl-(C 1 -C 12 ), NHCHO, COAr, CO 2 Ar, CF 3 , CONH 2 , CHCHCO 2 R, POAr 2 , PO-alkyl 2 -(C 1 -C 12 ), 5-ring heteroaryl, 6-ring heteroaryl, Si-alkyl 3 -(C 1 -C 12 ), where R=alkyl(C 1 -C 8 ), aryl(C 5 -C 10 ) and R 1 and R 2 independently of one another are hydrogen, C 1 -C 12 -alkyl, Ar as defined above, 5-ring heteroaryl, 6-ring heteroaryl, by reacting chloroaromatics of the formula II n n Ar--Cl (II) n n with ammonia or primary or secondary amines of the formula III n n R.sup.1 R.sup.2 NH (III) n n in which Ar and R 1 and R 2 are as defined above, which comprises reacting the starting materials in the presence of a palladium catalyst, a strong base and a halide cocatalyst in an inert solvent at temperatures of 80°-200° C.

专利号:US-6235871-B1
优先权日:1997-12-03
标题:Synthesis of oligoarylamines, and uses and reagents related thereto
发明人：SINGER ROBERT A; SADIGHI JOSEPH P; BUCHWALD STEPHEN L; MACKEWITZ THOMAS
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:The transition metal-catalyzed amination of aryl halides, in conjunction with an orthogonal protective group scheme, forms the basis of two routes to oligoaniline precursors. The oligoaniline precursors are soluble in a variety of common organic solvents, and are easily converted to the deprotected oligoanilines. The method allows the preparation of oligoanilines of even or odd chain lengths, and the incorporation of a variety of functional groups into the oligomers. Polyanilines of low polydispersity can also be prepared by this method.

专利号:US-2022274930-A1
优先权日:2019-06-14
标题:Processes and compounds for the decarboxylative amination of redox-active esters with diazirines
发明人：LOPCHUK JUSTIN M; CHANDRACHUD PREETI P
权利人:H LEE MOFFITT CANCER CT & RES
摘要:The invention described herein relates generally to processes for the synthesis of amine-containing organic compounds. More specifically, described herein relates to processes for the decarboxylative amination of redox-active esters with diazirines and the products formed thereof. Compounds for use in the above processes are also described.