CAS: 1309-60-0; Lead(Iv) Oxide

该化合物是无机化合物,其特征是深褐色至黑色外观,化学配方PbO2;是一种强氧化剂,主要用于铅酸电池,用作正板材料;二氧化铅在水中溶解,但可溶于强酸,形成铅离子和其他铅化合物;该化合物呈现四角晶体结构,熔点较高,在各种条件下保持稳定;二氧化二氧化铅+4的氧化状态有助于其再活动,特别是在红氧化反应中;由于其毒性性质,二氧化铅构成健康和环境风险,需要小心处理和处置;此外,它可参与各种化学反应,包括有机化合物氧化和其他铅材料的合成;

结构式图片

欧盟法规

《欧盟PIC法规》REACH注册ECHA物质ECHA物质OtherC&L通报REACH预注册

合成工艺路线路线简述

    Lead(II) Sulfate 反应生成二氧化铅
    参考文献:Kolikova,G. A.;Barsukova,M. M.;Demin,G. E.,Issled. V Obl. Ehlektr. Akkumulyatorov,L.,(1988) S. 8-14
    标题:Kolikova,G. A.;Barsukova,M. M.;Demin,G. E.,Issled. V Obl. Ehlektr. Akkumulyatorov,L.,(1988) S. 8-14

    专利信息


    专利号:US-12281398-B2
    优先权日:2022-02-07
    标题:Microfluidic process for the general electrochemical synthesis of geminal dipseudohalide or halide-pseudohalide compounds
    发明人:SCHROER THORSTEN G; LECROY GREGORY E; AGUILA MIGUEL; RODRIGUEZ MAYRA P; DOWNARD TYLER J; MACLEOD BRIANNA L
    权利人:US GOV AIR FORCE; US AIR FORCE
    摘要:A process for the microfluidic electrochemical synthesis of geminal dipseudohalide or halide-pseudohalide compounds comprising the steps ofpumping a solution comprising a compound of Formula Iinto a microfluidic electrochemical reactor in the presence of a base, one of a halide or pseudohalide salt (MY), and a mediator;applying an electrical current through the microfluidic electrochemical reactor; andperforming oxidative addition to create a geminal dipseudohalide or halide-pseudohalide compound of the general Formula II

    专利号:US-5002641-A
    优先权日:1990-06-28
    标题:Electrochemical synthesis of niacin and other N-heterocyclic compounds
    发明人:TOOMEY JR JOSEPH E
    权利人:REILLY IND INC
    摘要:An electrochemical oxidation of a pi-deficient N-heterocyclic precursor compound having an oxidizable organic group attached by a carbon-to-carbon linkage. This precursor compound is at least sparingly water soluble. The preferred electro-oxidation is conducted at an effective anode and in a medium which consists essentially of water, carboxylic acid, and the precursor compound. Preferred are electro-oxidations of substituted pyridine and quinoline bases and a particularly preferred aspect provides a convenient electrochemical synthesis of niacin from 3-methylpyridine.

    专利号:US-4592867-A
    优先权日:1984-10-19
    标题:Synthesis method for reductant precursor
    发明人:YU TERRY T; YEN MEI-RONG
    权利人:ENERGY CONVERSION DEVICES INC
    摘要:A synthesis method is provided for the synthesis of quinone compounds of the formula ##STR1## where n is 0-3, Y 1 is alkoxy, Y 2 is alkoxy, chloro, bromo or hydrogen and R' and R' each and independently are hydrogen, alkyl or phenyl. These compounds are useful as reductant precursors in tellurium imaging compositions.

    专利号:EP-1548006-B1
    优先权日:2003-12-12
    标题 :Synthesis of tetraazapentamethine derivatives, keratin fibers dyeing process which uses such synthesis
    发明人:PEREIRA RUI; BURGAUD HERVE
    权利人:OREAL
    摘要:Producing tetraazapentamethine compounds (I) comprising reacting an azine compound with an oxidizing agent, is new. Producing tetraazapentamethine compounds of formula (I) comprises reacting an azine compound of formula (VI) or (VII) with an oxidizing agent; [Image] [Image] W1a cationic heteroaromatic group of formula (II) or (III); W2a heteroaromatic group of formula (IV) or (V); Z14Z7 or Z1; Z15Z8 or Z2; Z16Z13 or Z0; R25R5 or R1; Z17Z9 or Z3; Z18Z10 or Z4; Z19Z11 or Z5; Z20Z12 or Z6; R26R8 or R3; R27R7 or R4; R28, R29H, 1-6C alkyl or 1-6C alkoxy, but not both H; Z0CR2, N or NR21; Z1O, S or NR9; Z2N or CR10; Z3N or CR11; Z4N or CR12; Z5N or CR13; Z5N or CR13; Z6N or CR14; Z7O, S or NR15; Z8N or CR16; Z9N or CR17; Z10N or CR18; Z11N or CR19; Z12N or CR20; Z13CR6, N or NR22; R2, R6, R10, R16H; 1-4C alkyl substituted with 0-3 of OH, 1-2C alkoxy, 2-4C (poly)hydroxyalkoxy, NH2, 1-2C (di)alkylamino, COOH or SO3H; phenyl substituted with 0-2 of OH, 1-2C alkoxy, 2-4C (poly)hydroxyalkoxy, NH2, 1-2C (di)alkylamino; COOH; sulfonylamino; R1, R4, R5, R7, R9, R15, R21, R221-6C alkyl substituted with 0-3 of OH, 1-2C alkoxy, 2-4C (poly)hydroxyalkoxy, NH2, 1-2C (di)alkylamino, COOH or SO3H; R0, R3, R8, R11-R14, R17-R20H; 1-6C linear or branched hydrocarbyl with 0-3 unsaturations, optionally substituted with 1-3 of OH, 1-2C alkoxy, 2-4C (poly)hydroxyalkoxy, NH2, 1-2C (di)alkylamino, COOH, SO3H, sulfonylamino, 2-4C (poly)hydroxyalkylamino or halo and optionally interrupted by O, N, S or SO2; phenyl optionally substituted with 1-3 of OH, 1-2C alkoxy, 2-4C (poly)hydroxyalkoxy, NH2, 1-2C (di)alkylamino, COOH, SO3H, sulfonylamino, 2-4C (poly)hydroxyalkylamino or halo; pyrazolyl, pyrrolyl, imidazolyl, thiazolyl, oxazolyl, triazolyl, pyridyl, pyrimidinyl, triazinyl, pyrazinyl or pyridazinyl; X : an anion; R2+R10, R11+R12, R6+R16, R17+R18 can form a 5-6C aromatic ring substituted with 0-2 of OH, NH2, 1-2C (di)alkylamino, 1-2C alkoxy, 2-4C (poly)hydroxyalkylamino. An independent claim is also included for dyeing keratinic fibers by applying (VI) or (VII) onto the wet or dry fibers in the presence of an oxidizing agent. [Image].

    专利号:US-4777293-A
    优先权日:1984-08-13
    标题 :Method for the synthesis of pharmacologically active compounds and intermediates for such synthesis
    发明人:LAMM BO R
    权利人:HAESSLE AB
    摘要:A process for the preparation of an aryloxypropanolamine of the formula n n Ar--OCH.sub.2 CH(OH)CH.sub.2 NH--R I n n wherein Ar is a carbocyclic or heterocyclic aromatic group and R is an alkyl or substituted alkyl group having 1 to 6 carbon atoms, characterized in subjecting a compound of the formula ##STR1## to oxidative cleavage to a dialdehyde of the formula ##STR2## which is then made subject to reduction, amination, acetal hydrolysis, and, where required, removal of a nitrogen protective group, to the formation of a compound of formula I, or an acid addition salt thereof, a compound of formula II and the preparation thereof from mannitol.

    专利号:WO-2025017286-A1
    优先权日:2023-07-14
    标 题 :Novel synthesis of colloidal quantum dot ink and applications in semiconductor devices
    发明人:VASHISHTHA PARTH; HE XIN; MEHTA JOSHUA; LIU JUNPENG; VO CONG-DUAN
    权利人:QUANTUM SCIENCE LTD
    摘要:The present invention provides a method for producing a nanocrystal composition comprising an inorganic ligand via a one-pot synthesis. The present invention also provides nanocrystals comprising novel inorganic ligands and the use of these nanocrystals. The present invention further provides the use of the novel inorganic ligands in the preparation of nanocrystals.
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    合成参考文献


    摘要:Lu, J.-M.; Shao, L.-X., Science of Synthesis Knowledge Updates, (2020) 3, 357.
    摘要:Chemla, F.; Ferreira, F.; Pérez-Luna, A., Science of Synthesis Knowledge Updates, (2012) 1, 480.
    摘要:International Maritime Organization. IMDG Code. International Maritime Dangerous Goods Code Volume 2 2014, p. 92
    摘要:USEPA/Office of Water; Federal-State Toxicology and Risk Analysis Committee (FSTRAC). Summary of State and Federal Drinking Water Standards and Guidelines (11/93) To Present
    摘要:Bretherick, L. Handbook of Reactive Chemical Hazards. 4th ed. Boston, MA: Butterworth-Heinemann Ltd., 1990, p. 170
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