专利号:US-3888844-A 优先权日:1971-09-10 标 题:Halogenated esters of phosphorus-containing acids (ii) 发明人:D ALELIO GAETANO F 权利人:ALELIO GAETANO F D 摘要:This invention deals with new phosphorus containing polymeric esters having pendent groups therein of the formula OBTAINED BY THE REACTION OF A POLYMER HAVING AT LEAST 2 AND PREFERABLY AT LEAST 4 HYDROXY GROUPS THEREIN WITH A PHOSPHORUSHALOGEN COMPOUND OF THE FORMULA XP(O) (ORCX CXR'')2 wherein: R represents a divalent hydrocarbon radical containing 1-20 carbon atoms; R'' represents X, hydrogen or R''''; R'''' represents a monovalent hydrocarbon radical containing 1-20 carbon atoms; and X represents chlorine or bromine. Somewhat related polymers are also disclosed as derived by the reaction of WHEREIN Q'' is an organic moiety, n'' has a value of at least one, n'''' is one or two, R'''''' represents hydrogen or a monovalent hydrocarbon group of 1-20 carbon atoms, and the other symbols have the same meaning as defined above. Also disclosed are the reaction products of the phosphite compound HOP(ORCX CXR'')2 with an aldehyde and an organic nitrogen compound having one or two hydrogen atoms on the nitrogen, or with a compound having an ethylenic group therein. These new ester polymers and compounds are useful particularly as fire retardants, agricultural chemicals, fuel additives, plasticizers, monomers and intermediates for the synthesis of other useful derivatives.
专利号:US-3985835-A 优先权日:1973-07-30 标题 :Halogenated esters of phosphorus-containing acids 发明人:D ALELIO GAETANO F 权利人:ALELIO GAETANO F D 摘要:This invention deals with new phosphorus-containing esters having the formula R'''2NP(O) (ORCX=CXR')2 wherein X represents Cl or Br; R represents a divalent hydrocarbon radical of 1-20 carbon atoms; R' represents H, X or R''; R'' represents a monovalent hydrocarbon radical of 1-20 carbon atoms; R''' represents hydrogen, a monovalent hydrocarbon radical of 1-20 carbon atoms, a divalent saturated aliphatic hydrocarbon group having 5 carbon atoms between valencies and forming a cyclic structure with the N, or a derivative of said monovalent hydrocarbon radical in which the derivative group is hydroxy, NH2, NHR'', NR''2, -NR''''K, R''''NHNHC(O)-, R''''NHC(O)NH-, -(N-R-)n-NR'''' , ¦¦ KK R''COO-, R''CONH- or R''O, R'''' represents hydrogen or R''; n represents an integer having a value of 0-50; and K represents hydrogen, R'' or -P(O) (ORCX=CXR')2. These new esters are useful particularly as fire retardants, agricultural chemicals, fuel additives, plasticizers, monomers and intermediates for the synthesis of other useful derivatives.
专利号:US-3886237-A 优先权日:1971-09-10 标题 :Halogenated phosphonates 发明人:D ALELIO GAETANO F 权利人:ALELIO GAETANO F D 摘要:This invention deals with new phosphorus-containing esters having the formula AND DERIVATIVES THEREOF OBTAINED BY REACTION WITH AN AMINE COMPOUND HAVING AT LEAST ONE HYDROGEN ATTACHED TO THE NITROGEN OF THE AMINE, WHEREIN R represents a divalent hydrocarbon radical containing 1-20 carbon atoms; R'' represents X, hydrogen or R''''; R'''' represents a monovalent hydrocarbon radical containing 1-20 carbon atoms; and X represents chlorine or bromine. These new esters are useful particularly as fire retardants, agricultural chemicals, fuel additives, plasticizers, monomers and intermediates for the synthesis of other useful derivatives.
专利号:CN-116375608-A 优先权日:2022-12-29 标题:Synthesis of phenylsemicarbazone and identification of iron ions by phenylsemicarbazone
专利号:CN-115974728-B 优先权日:2022-12-29 标 题 :Synthesis of phenylsemicarbazone and identification of hexavalent chromium ions by phenylsemicarbazone
专利号:CN-102936222-A 优先权日:2012-11-20 标 题 :Synthesis and Application of Pyrazolone Thermochromic Compounds
参考标题:Synthesis Of Nitrogen‐containing Goniothalamin Analogues With Higher Cytotoxic Activity And Selectivity Against Cancer Cells 作者:Matheus A. Meirelles,Carolyne B. Braga,Catia Ornelas,Ronaldo A. Pilli |发布日期:2019.8.6 摘要:Goniothalamin Analogues Displaying Nitrogen‐containing Groups Were Designed And Synthesized. A Total Of 19 Novel Analogues Were Evaluated Against A Panel Of Four Different Cancer Cell Lines, Along With The Normal Prostate Cell Line Pnt2 To Determine Their Selectivity. Among Them, Goniothalamin Chloroacrylamide 13 E Displayed The Lowest Ic50 Values For Both Mcf‐7 (0.5 μm) And Pc3 (0.3 μm) Cells, About 26‐fold
合成参考文献
参考文献:10.1039/c1pp05110e 摘要:Yuan H, Guo J, Jia D, Guo M, Liu L, Wu D, Li F. Photochromism of a pyrazolone derivative in crystalline state and in HPMC composite film. Photochemical & Photobiological Sciences. 2011 Oct;10(10):1562–7. doi: 10.1039/c1pp05110e.