CAS: 100-23-2; N,N-Dimethyl-4-Nitroaniline

上下游产品

N,N-dimethylaniline N-oxide 4-bromo-N,N-dimethylaniline 4-Iodo-N,N-dimethylaniline 1,1-bis-(4-dimethylamino-phenyl)-ethanepyridine4-(p-dimethylaminophenyl)azopyridine pyridine-azo-p-dimethyl aniline N,N-dimethyl-4-(6-methyl-[2]pyridylazo)-anilineN,N-dimethyl-4-(6-methyl-[2]pyridylazo)-aniline N,N-dimethyl-4-(4-methyl-[2]pyridylazo)-anilineN,N-dimethyl-4-(4-methyl-[2]pyridylazo)-aniline

📜4-溴-N,N-二甲基苯胺置于potassium Phosphate,Copper(L) Iodide,N1,N2-双(2-噻吩甲基)-乙二酰胺,Sodium Nitrite体系中,用 二甲基亚砜 用作溶剂,以99 %的收率获得n,N-二甲基对硝基苯胺
参考文献:Cui/草酰胺催化(杂)芳基卤化物与亚硝酸钠的偶联反应
标题:Cui/草酰胺催化(杂)芳基卤化物与亚硝酸钠的偶联反应
摘要:N,N '-双(噻吩-2-基甲基)草酰胺(btmo)被发现是铜催化(杂)芳基卤化物(br,I)原位硝化的有效配体,与钠发生偶联反应亚硝酸盐在 100-120 oc 下与 1-5 Mol% Cui 和 Btmo 顺利进行.富电子底物是最好的偶联伙伴,可以在 100 oc 下以非常好至优异的收率提供所需的偶联产物.电子中性基材需要在 120 oc 下加热才能完全转化,而在缺电子(杂)芳基溴的情况下观测到相当低的转化率.
Doi:10.1021/acs.Joc.4C00463

专利信息

专利号:US-9932423-B2
优先权日:2015-09-24
标题:Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such
发明人：MCCULLOUGH LAUGHLIN G
权利人:EXXONMOBIL CHEMICAL PATENTS INC
摘要:Disclosed are methods for making partially hydrogenated annulated cyclopentadienyl complexes which can provide efficient synthesis of metallocene catalysts desired for olefin polymerization.

专利号:US-8168556-B2
优先权日:2007-10-25
标 题 :Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
发明人：SCHULTE JOERG; SELL THORSTEN; THORN MATTHEW GRANT; WINTER ANDREAS; DIMESKA ANITA
权利人:SCHULTE JOERG; SELL THORSTEN; THORN MATTHEW GRANT; WINTER ANDREAS; DIMESKA ANITA; LUMMUS NOVOLEN TECHNOLOGY GMBH
摘要:A metallocene compound with the 4- and 7-positions on the indenyl moiety possessing large aromatic substituents is prepared in accordance with a method which produces substantially 100 percent racemic isomer. Advantageously, polymerization catalysts including the metallocene of the invention provide superior olefin polymerization results.

专利号:US-9765042-B2
优先权日:2013-10-07
标题 :Methods of chemical synthesis of diaminophenothiazinium compounds including methylthioninium chloride (MTC)
发明人：SINCLAIR JAMES PETER; NICOLL SARAH LOUISE; STOREY JOHN MERVYN DAVID
权利人:WISTA LAB LTD
摘要:Methods of synthesizing and purifying certain 3,7-diamino-phenothiazin-5-ium compounds (referred to herein as “diaminophenothiazinium compoundsâ€?) including Methythioninium Chloride (MTC) (also known as Methylene Blue) are provided.

专利号:US-6518444-B1
优先权日:2000-12-18
标题 :Preparation of polymerization catalysts
发明人：MCCONVILLE DAVID H; SHER JAIMES
权利人:UNIVATION TECH LLC
摘要:A method to synthesize a Group 15 containing metal polymerization catalyst is disclosed. The method includes an efficient high temperature synthesis of Group 15 containing ligands, especially arylamine ligands, for use in preparing polymerization catalysts and catalyst systems.

专利号:US-7285608-B2
优先权日:2004-04-21
标题:Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
发明人：SCHOTTEK JOERG; PACZKOWSKI NICOLA STEFANIE; WINTER ANDREAS; SELL THORSTEN
权利人:NOVOLEN TECH HOLDINGS CV
摘要:A catalyst system includes a metallocene compound having the formula R 9 L 1 L 2 M 1 R 1 R 2 wherein R 9 is a bridge between ligands L 1 and L 2 and M 1 is a metal of Group IVB of the Periodic Table such as titanium, zirconium and hafnium and R 1 and R 2 can be hydrogen or aliphatic or aromatic groups. Bridge R 9 can include silicon, germanium or tin. The metallocene compound of the invention as synthesized has a racemic to meso isomer ratio of greater than 5 to 1, thereby precluding the need for subsequent separation of the meso isomer.

专利号:US-7169864-B2
优先权日:2004-12-01
标题 :Metallocene catalysts, their synthesis and their use for the polymerization of olefins
发明人：PACZKOWSKI NICOLA S; WINTER ANDREAS; LANGHAUSER FRANZ
权利人:NOVOLEN TECH HOLDINGS CV
摘要:A process for the preparation of a catalyst system includes the steps of combining a support material with a first composition which includes at least one aluminoxane in a first solvent to provide an aluminoxane loaded support; and, contacting the aluminoxane loaded support with a second composition which includes at least one metallocene compound, a second solvent, and a cocatalyst, wherein the cocatalyst includes a second portion of the at least one aluminoxane alone or in combination with an ionic compound and/or a Lewis acid.