CAS: 22002-45-5; 2-Bromo-4-Methylanisole

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CAS号6627-55-0 2-溴-4-甲基苯酚 | CAS号77-78-1 硫酸二甲酯 | CAS号104-93-8 4-甲基苯甲醚(MSO) | CAS号74-88-4 碘甲烷 | CAS号136538-22-2 3-Bromo-4,4-dim... | CAS号106-44-5 对甲酚 | CAS号583-68-6 2-溴-4-甲基苯胺 | CAS号120-71-8 2-甲氧基-5-甲基苯胺 | CAS号64-19-7 冰醋酸 | CAS号67-66-3 氯仿 | CAS号494-99-5 3,4-二甲氧基甲苯 | CAS号50868-72-9 5-甲氧基-2-甲基苯胺 | CAS号144061-57-4 6-methoxy-3-met... | CAS号2830-53-7 1-(苄氧基)-2-溴-4-甲基苯 | CAS号99-58-1 3-溴-4-甲氧基苯甲酸 | CAS号25045-36-7 2-甲氧基-5-甲基苯甲酸 | CAS号7083-19-4 2-甲氧基-5-甲基苯甲醛 | CAS号53078-70-9 2-甲氧基-5-甲基苯腈 | CAS号6981-18-6 奥美普林 | CAS号6627-55-0 2-溴-4-甲基苯酚

对甲苯甲醚置于oxone,Potassium Bromide体系中,用 水,乙腈 用作溶剂,化学反应 24.0H,以85%的收率获得3-溴-4-甲氧基甲苯
参考文献:碱金属溴化物作为溴化物催化剂对醇的选择性氧化:反应机理的实验研究
标题:碱金属溴化物作为溴化物催化剂对醇的选择性氧化:反应机理的实验研究
摘要:开发了溴化物催化的醇的氧化反应,该氧化反应在碱金属溴化物和氧化剂的存在下于温和的条件下进行.该反应涉及使用kbr和oxone进行无有机分子的氧化,以及使用kbr和h 2 O 2水溶液进行布朗斯台德酸辅助氧化,以高收率提供各种羰基化合物.而且,在tempo存在下,在两种反应条件下,溴化物催化的伯醇的氧化使得羧酸和醛的发散合成成为可能.在各种机理研究的基础上,提出了一种可能的催化机理.
Doi:10.1021/jo5008064

专利信息

专利号:US-2006089405-A1
优先权日:2004-10-21
标 题 :Asymmetric synthesis of dihydrobenzofuran derivatives
发明人：ZHOU DAHUI; STACK GARY P; GONTCHAROV ALEXANDER V
权利人:WYETH CORP
摘要:This invention concerns a process for the preparation of benzofuran derivatives. In some aspects, these compounds are of formula I: n n nwherein each of R 1 , R 2 , R 3 , and R 4 is as defined herein.

专利号:US-8703996-B2
优先权日:2010-03-09
标题:Short synthesis of tolterodin, intermediates and metabolites
发明人：STERK DAMJAN
权利人:STERK DAMJAN; LEK PHARMACEUTICALS
摘要:A process is described for the preparation of intermediates which can be used for preparation of agents for urinary incontinence therapy, specifically to 2-(3-(diisopropylamino)-1-phenylpropyl)-4-(hydroxymethyl)phenol and its prodrugs.

专利号:US-7833926-B2
优先权日:2005-07-01
标题 :Arylphenoxy catalyst system for producing ethylene homopolymer or copolymers of ethylene and α-olefins
发明人：WOO TAE WOO; OK MYUNG AHN; HAHN JONG SOK; LEE MAL-OU; KANG SANG OOK; KO SUNG-BO; KIM TAE-JIN; KIM SUNG-KWAN
权利人:SK ENERGY CO LTD
摘要:The present invention relates to an arylphenoxy catalyst system producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group IV arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group IV transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.

专利号:WO-9729091-A1
优先权日:1996-02-09
标题:Balanol analogues
发明人：NIELSEN JOHN; LYNGSOE LARS OLE
权利人:AUDA PHARMACEUTICALS APS; NIELSEN JOHN; LYNGSOE LARS OLE
摘要:The present invention relates to a solid phase methodology for the preparation of a combinatorial library of structural analogues of the natural product balanol (ophiocordin, azepinostatin), which is a protein kinase C (PKC) and protein kinase A (PKA) inhibitor. The method comprises solid-phase synthesis of the analog variants of balanol whereby a high molecular diversity is introduced. The synthetic scheme is based on a retrosynthetic analysis of the native structure which revealed three main building blocks suitable as templates for modification. The dicarboxy-functional moiety can be immobilised to the polymer support either as the monoallyl ester or as the internal anhydride. The libraries produced by the method are especially suited for high throughput screening of potential drug candidates for the treatment of mammals, especially humans.

专利号:AU-2005299757-A1
优先权日:2004-10-21
标 题:Asymmetric synthesis of dihydrobenzofuran derivatives

专利号:CA-2584775-A1
优先权日:2004-10-21
标题:Asymmetric synthesis of dihydrobenzofuran derivatives