CAS: 1829-40-9; 1,1,1,3,3,3-Hexaphenyldisiloxane

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CAS号1516-80-9 乙氧基三苯基硅烷 | CAS号791-31-1 三苯基硅醇 | CAS号76-86-8 三苯基氯硅烷 | CAS号14986-21-1 六氯二硅氧烷 | CAS号789-25-3 三苯基硅烷 | CAS号591-51-5 苯基锂 | CAS号1829-41-0 甲氧基三苯基硅烷 | CAS号1825-58-7 苯基二甲基乙氧基硅 | CAS号4131-46-8 triphenyl(2-phe... | CAS号17964-41-9 butyl-hydroxy-d... | CAS号791-31-1 三苯基硅醇 | CAS号789-25-3 三苯基硅烷 | CAS号76-86-8 三苯基氯硅烷 | CAS号98-11-3 苯磺酸 | CAS号16527-35-8 Silanol,1,1,1-t... | CAS号2117-32-0 butyl(triphenyl...

📜三苯基硅烷置于n-苄基乙酰胺,二氧化碳,氢化钾,C22H14Mnn2O4(1+)*bf4(1-)体系中,用 氘代乙腈 用作溶剂,20.0 °C,101.33 Kpa 条件下,反应生成六苯基二硅氧烷
参考文献:室温下使用 Co2置于mni 催化的仲酰胺和内酰胺的 N-甲酰化中的金属-配体协同作用
标题:室温下使用 Co2置于mni 催化的仲酰胺和内酰胺的 N-甲酰化中的金属-配体协同作用
摘要:据报道,Mn I络合物与氧化还原非无害苯二甲酰 (Ply) 配体配位,首次在室温下以 Co 2作为 C 1源催化仲酰胺(包括后期药物多样化)和内酰胺的 N-甲酰化时间.实验分析和 Dft 计算的组合方法描绘了一种非常规金属-配体合作的可能的自由基介导途径,涉及以配体为中心的自由基.
Doi:10.1002/chem.202202710

专利信息

专利号:US-5569762-A
优先权日:1994-01-14
标题:Asymmetric synthesis of intermediates for retroviral protease inhibitor compounds
发明人：WISSNER ALLAN; TROVA MICHAEL P
权利人:AMERICAN CYANAMID CO
摘要:The disclosure describes an improved process for producing optically active compounds of Formula II or III, which compounds are useful as intermediates for preparing compounds active as inhibitors of retroviral protease enzymes: ##STR1## wherein R 1 , R 50 and Z are described in the specification. The improved process includes either synthesis of diastereomeric iodolactones which are separated prior to conversion to compounds of Formula II or III or synthesis of an epoxide which is converted directly to compounds of Formula II and III.

专利号:US-3943157-A
优先权日:1971-07-26
标题 :Synthesis of codling moth attractant
发明人：HENRICK CLIVE A; SIDDALL JOHN B
权利人:ZOECON CORP
摘要:Sterospecific synthesis of an attractant for the codling moth by reacting sorbic aldehyde with an organo-metallic reagent to yield a 1-ether of trans-8-trans-10-dodecadiene-1,7-diol which is reduced via a 7-sulfonic acid ester to yield an ether of trans-8-trans-10-dodecadiene-1-ol and hydrolyzed to trans-8-trans-10-dodecadien-1-ol. ##SPC1##

专利号:US-10815194-B2
优先权日:2016-11-14
标题 :Process for the preparation of mono-protected α,ω-diamino alkanes
发明人：MENGE WIRO MICHAEL PETRUS BERNARDUS
权利人:BYONDIS BV
摘要:The present invention relates to a process for the synthesis of mono-protected α,ω-diamino alkanes, the use of said process in a process for the synthesis of a linker drug comprising an α,ω-diamino alkane moiety and the use of the process of the present invention in a process for preparing an antibody-drug conjugate comprising an α,ω-diamino alkane moiety.

专利号:US-2008045726-A1
优先权日:2004-05-10
标题 :Spirolactams and Their Synthesis
发明人：NOHEDA MARIN PEDRO; BERNABE PAJARES MANUEL; MAROTO QUINTANA SERGIO; TABARES CANTERO NURIA
权利人:ESTEVE LABOR DR
摘要:New spirolactams of formula (I) having a cycloexadienone moiety which are highly stable due to pi interactions between the W group and the dienone moiety. They are useful as UV absorbers and as intermediates for the synthesis of active biomolecules.

专利号:WO-2023118045-A1
优先权日:2021-12-21
标 题:Process for the controlled synthesis of voclosporin
发明人：CORDOVILLA LOSADA CARLOS; FERNÃ?NDEZ SAINZ MARÃ?A YOLANDA; LORENTE BONDE-LARSEN ANTONIO
权利人:CURIA SPAIN S A U
摘要:The invention relates to a process for the preparation of mixtures of (E) and (Z)- isomers of Voclosporin in a controlled manner.

专利号:US-2008281094-A1
优先权日:2004-05-10
标题 :Regioselective Functionalisation and Protection of Spirolactams
发明人：NOHEDA MARIN PEDRO; PAJARES MANUEL BERNABE; QUINTANA SERGIO MAROTO; CANTERO NURIA TABARES; ARENAS RAUL BENITO
权利人:ESTEVE LABOR DR
摘要:The invention provides highly functionalised spiro-fused lactams of en formula (I) having a cyclohexane moiety with the desired number of protected or un-protected functional groups or carbonated structures, which are introduced with high stereo and regioselectivity, as well as processes for their obtention. These compounds are useful for the synthesis of abroad range of bioactive molecules, such as condoritols and aminoinositols and their analogues.