专利号:US-8183402-B2 优先权日:2007-06-27 标 题:Industrial method for the synthesis of 17-acetoxy-11β[4-(dimethylamino)-phenyl]-21-methoxy-19-norpregna-4,9-dien-3,20-dione and the key intermediates of the process 发明人:BODI JOZSEF; VISKY GYOERGY; SZELES JANOS; MAHO SANDOR; SANTA CSABA; CSOERGEI JANOS; TUBA ZOLTAN; TERDY LASZLO; MOLNAR CSABA; ARANYI ANTAL; HORVATH ZOLTAN; BALOGH GABOR 权利人:BODI JOZSEF; VISKY GYOERGY; SZELES JANOS; MAHO SANDOR; SANTA CSABA; CSOERGEI JANOS; TUBA ZOLTAN; TERDY LASZLO; MOLNAR CSABA; ARANYI ANTAL; HORVATH ZOLTAN; BALOGH GABOR; RICHTER GEDEON NYRT 摘要:The present invention relates to a process for the synthesis of the 17-acetoxy-11β-[4-(dimethylamino)-phenyl]-21-methoxy-19-norpregna-4,9-dien-3,20-dione of formula (I): n nfrom 3,3-[1,2-etandiyl-bis(oxy)]-oestr-5(10),9(11)-dien-17-one of formula (II):
专利号:US-7314544-B2 优先权日:2004-09-07 标题:Electrochemical synthesis of ammonia 发明人:MURPHY OLIVER J; DENVIR ADRIAN J; TEODORESCU SORIN G; USELTON KYLE B 权利人:LYNNTECH INC 摘要:A method for the anodic electrochemical synthesis of ammonia gas. The method comprises providing an electrolyte between an anode and a cathode, providing nitrogen and hydrogen gases to the cathode, oxidizing negatively charged nitrogen-containing species and negatively charged hydrogen-containing species present in the electrolyte at the anode to form adsorbed nitrogen species and adsorbed hydrogen species, respectively, and reacting the adsorbed nitrogen species with the adsorbed hydrogen species to form ammonia. Nitrogen and hydrogen gases may be provided through a porous cathode substrate. The negatively charged nitrogen-containing species in the electrolyte may be produced by reducing nitrogen gas at the cathode and/or by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte. Similarly, the negatively charged hydrogen-containing species in the electrolyte may be produced by reducing hydrogen gas at the cathode and/or by supplying a hydrogen-containing salt, such as lithium hydride, into the molten salt electrolyte.
专利号:WO-2012089181-A1 优先权日:2010-12-30 标题 :O-substituted (2r,3r)-3-(3-hydroxyphenyl)-2-methyl-4-pentenoic acids and a method of obtaining the same 发明人:VLASAKOVA RUZENA; HAJICEK JOSEF; ZEZULA JOSEF 权利人:ZENTIVA KS; VLASAKOVA RUZENA; HAJICEK JOSEF; ZEZULA JOSEF 摘要:The compounds of general formula II are new and represent important intermediates in the synthesis of tapentadol. In the synthesis of tapentadol of formula I and its pharmaceutically acceptable salts, O-protected (2R,3R)-acids of general formula II, in step A, are reacted in an inert organic solvent with an activating agent, optionally in presence of a catalyst or a base; in step B, the obtained compounds of general formula V, wherein R has the above mentioned meaning and X stands for chlorine or alkoxycarbonyloxyl group O-CO-OR 1 or pivaloyloxyl O-CO-t-Bu group, wherein R 1 is methyl or ethyl, are reacted with dimethylamine or its salts optionally in presence of a base; in step C, the obtained N, N-dimethylamides of general formula VI, wherein R has the above mentioned meaning, are reduced by means of hydride agents in a suitable solvent; in step D, the produced alkeneamines of general formula VII, wherein R has the above mentioned meaning, are hydrogenated on a metal catalysts in a suitable solvent; and, finally, in step E, the produced alkaneamines of general formula VIII, wherein R has the above mentioned meaning, are O-dealkylated by means of dealkylating agents, and, if required, the obtained tapentadol is converted by the action of a pharmaceutically acceptable acid to respective salts, e.g. hydrochloride.
专利号:US-4233282-A 优先权日:1979-10-18 标 题:Molten salt synthesis of barium and/or strontium titanate powder 发明人:ARENDT RONALD H 权利人:GEN ELECTRIC 摘要:A particulate mixture of an alkali chloride solvent salt, titanium oxide and an alkaline earth reactant selected from the group consisting of barium oxide, strontium oxide, and mixtures thereof, is heated to melt the chloride salt solvent in which the titanium oxide and alkaline earth reactant dissolve and react precipitating a titanate selected from the group consisting of barium titanate, strontium titanate and mixtures thereof.
专利号:US-10193132-B2 优先权日:2010-08-02 标 题 :Synthesis of submicrometer to micrometer-sized cathode materials 发明人:AXELBAUM RICHARD LOUIS; ZHANG XIAOFENG 权利人:AXELBAUM RICHARD LOUIS; ZHANG XIAOFENG; UNIV WASHINGTON 摘要:A method of producing submicrometer- to micrometer-sized spherical particles, the method comprising dissolving a lithium salt and a metal salt in water or alcohol forming a precursor solution, spraying the precursor solution to form fine aerosolized droplets, flowing the aerosolized droplets into a pyro lysis flame producing submicrometer- to micrometer-sized spherical particles. The submicrometer- to micrometer-sized spherical lithium-metal oxide powders produced are cathode materials for Li-ion batteries.
专利号:WO-2025124974-A1 优先权日:2023-12-11 标题:Synthesis of fumed nanostructured lithium borate powder 发明人:TAKATA Ryo; SCHMIDT FRANZ; SCHÄFER DURDU; WIEGAND ARMIN; HEINDL NICO; KANEEDA MASANOBU; ESKEN DANIEL; HERZOG MARCEL; KANNO RYOJI; NOMOTO KUNIHARU 权利人:EVONIK OPERATIONS GMBH 摘要:A method for making fumed lithium borate, the method comprising: preparing a solution of a lithium precursor, preferably a lithium carboxylate containing 5 to 20 carbon atoms, and a boron source, preferably an organic boron compound, feeding the solution to a flame burning in a flame reaction zone to produce a fumed product comprising fumed lithium borate particles; and obtaining the fumed product.
[参考文献]: Shan-Li Wang, Et Al. Phosphate Removal From Water Using Lithium Intercalated Gibbsite. J Hazard Mater. 2007 Aug 17;147(1-2):205-12. [参考文献]: Tatiana Avalos-Rendón, Et Al. Thermochemical Capture Of Carbon Dioxide On Lithium Aluminates (Lialo2 And Li5Alo4): A New Option For The Co2 Absorption. J Phys Chem A. 2009 Jun 25;113(25):6919-23. [参考文献]: Wen-Yuan Pang, Et Al. Current Development And Patents On High-Brightness White Led For Illumination. Recent Pat Nanotechnol. 2010 Jan;4(1):32-40.
合成参考文献
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