CAS: 107-82-4; 1-Bromo-3-Methylbutane

上下游产品

CAS号123-51-3 异戊醇 | CAS号107-84-6 氯代异戊烷 | CAS号628-04-6 乙基異戊基醚 | CAS号563-45-1 异戊烯 | CAS号659-70-1 异戊酸异戊酯 | CAS号544-01-4 异戊醚 | CAS号10035-10-6 氢溴酸 | CAS号78-78-4 异戊烷 | CAS号507-36-8 2-溴-2-甲基丁烷 | CAS号506-96-7 乙酰溴 | CAS号3730-60-7 2,5-二甲基-2-己醇 | CAS号507-36-8 2-溴-2-甲基丁烷 | CAS号18295-25-5 2-溴-3-甲基丁烷 | CAS号544-00-3 二异戊胺 | CAS号544-02-5 二异戊基硫醚 | CAS号2049-94-7 (3-甲基丁基)苯 | CAS号2049-95-8 叔戊基苯 | CAS号4481-30-5 (1,2-二甲基丙基)苯 | CAS号98-82-8 异丙基苯 | CAS号100-41-4 乙苯

异戊醇置于硫酸,Sodium Bromide体系中,化学反应生成1-溴代异戊烷
参考文献:亚结构对双尾三硅氧烷表面活性剂扩展能力和耐水解性的影响
标题:亚结构对双尾三硅氧烷表面活性剂扩展能力和耐水解性的影响
摘要:四种新型的通式me 3 Siosimer 1 Osime 3的新型双尾三硅氧烷表面活性剂(r 1 =-(ch 2)3 Nr 2 Ch 2 Ch(oh)ch 2(och 2 Ch 2)x och 3 ; R 2 =-ch 2 Ch(oh)ch 2 och 2(ch 2)y Ch 3,-ch 2(ch 2)3 Ch 3,-ch2 Ch 2 Ch(ch 3)2;X = 8.4,12.9,17.5,22;Y = 2,6),已经合成.它们的结构以质子和碳核磁共振为特征.它们中的大多数能够在10-5 Mol / L和10-4的浓度水平下将水的表面张力降低至24 Mn / M以下摩尔/升.重点是亚结构对其扩展能力和抗水解性的影响.结果表明,表面活性剂分子的亲水性较弱,整个疏水基团中甲基与亚甲基的摩尔比更大,疏水性基团更灵活以及在间隔基中引入甲基均可改善双尾的扩散能力.低能量固体表面上的三硅氧烷表
Doi:10.1007/s11743-009-1144-4

专利信息

专利号:US-2022267266-A1
优先权日:2019-07-09
标 题 :Improved, cost effective process for synthesis of vitamin d3 and its analogue calcifediol from ergosterol
发明人：DATLA ANUPAMA; NAGRE PRASHANT; TAMORE JAGDISH; PRABHU MANOJKUMAR SADANAND; KADAM SACHIN VASANT
权利人:FERMENTA BIOTECH LTD
摘要:Disclosed herein is an improved and efficient process for synthesis of vitamin D3 and its analogue Calcifediol from Ergosterol. Particularly, the present invention discloses the synthesis of key intermediate 3β-tert-Butyldimethylsilyloxy-22-hydroxy-23,24-bisnorchola-5,7-diene (5), and novel intermediate β-tert-Butyldimethylsilyloxy-22-iodo-23,24-bisnorchola-5,7-diene (9) by a simple and cost effective process. The industrially viable processes for preparation of said intermediate(s) results in providing provitamins with various side chains and the desired products in high yield.

专利号:WO-03031376-A1
优先权日:2001-10-12
标 题 :Solid phase synthesis of substituted 1,5-benzodiazepine-2-one and 1,5-benzothiazepine-2-one
发明人：MORTON GEORGE C; SALVINO JOSEPH M; LABAUDINIERE RICHARD F; HERPIN TIMOTHY F
权利人:AVENTIS PHARMA INC; MORTON GEORGE C; SALVINO JOSEPH M; LABAUDINIERE RICHARD F; HERPIN TIMOTHY F
摘要:A solid phase synthetic method for making substituted 1,5-benzodiazepine-2-one or 1,5-benzothiazepine-2-one. The method is useful for synthesis of large numbers of compounds through automated parallel synthesis or combinatorial library generation and is thus important to rapid discovery or new therapeutic agents containing the base structure of 1,5-benzodiazepine-2-one or 1,5-benzothiazepine-2-one.

专利号:US-4151205-A
优先权日:1975-01-27
标题 :Synthesis of vitamin E
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A synthesis of vitamin E in racemic or optically active forms from methacryolein or beta-hydroxyisobutyric acid including intermediates in this synthesis.

专利号:US-4051153-A
优先权日:1975-01-27
标题 :Intermediates in the synthesis of vitamin E
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A synthesis of vitamin E in racemic or optically active forms from methacryolein or beta-hydroxyisobutyric acid including intermediates in this synthesis.

专利号:US-5554753-A
优先权日:1993-08-25
标 题:Catalytic enantioselective synthesis of α-amino acid derivatives by phase-transfer catalysis
发明人：O'DONNELL MARTIN J; WU SHENGDE; ESIKOVA IRENA; MI AIQIAO
权利人:INDIANA UNIVERSITY FOUNDATION
摘要:Described are improved processes for the enantioselective synthesis of α-amino acids which involve combinations of solvents, highly-mixed and low-temperature reaction conditions, and novel catalysts. Also described are novel catalysts and precursors to α-amino acid derivatives.

专利号:US-9879043-B1
优先权日:2013-06-06
标 题:Synthesis of non-natural cofactor analogs of S-adenosyl-L-methionine using methionine adenosyltransferase
发明人：THORSON JON; HUBER TYLER; ZHANG JIANJUN; Singh Shanteri
权利人:UNIV KENTUCKY RES FOUND
摘要:The present disclosure relates to the synthesis of non-natural analogs of S-adenosyl-L-methionine (SAM) and/or of Se-adenosyl-L-methionine (SeAM) by reacting a methionine analog and adenosine triphosphate (ATP) in the presence of at least one methionine adenosyltransferase (MAT), and to use thereof with downstream SAM and/or SeAM utilizing enzymes. The non-natural analogs of SAM and/or SeAM have the general formula: n nwhere X is S or Se, and R 1 is an alkyl group.