CAS: 1027-62-9; Bis(Dimethylamino)Diphenylsilane

该化合物是一种专门的有机硅化合物,其特点是将中央硅原子粘合到两个苯基组和四甲基替代二胺混合物中,这种结构具有独特的反应性和稳定性,在地表改变,粘合促进和硅酮化学前体等应用中具有价值.四甲基替代提高了其在有机溶剂中的溶解性,而二苯组则有助于热和氧化稳定性.其双功能性质允许与金属交叉或协调,使其在高级材料合成和催化方面有用.由于对湿度的敏感性,该化合物通常在不热条件下处理.

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CAS号124-40-3 二甲胺 | CAS号80-10-4 二苯基二氯硅烷

合成工艺路线路线简述

    📜二甲胺,二苯二氯硅烷 以 乙醚 用作溶剂,化学反应生成二(二甲氨基)二苯基硅
    参考文献:氯氨基硅烷ii.烷基-(二甲基氨基)氯硅烷的制备和光谱研究
    标题:氯氨基硅烷ii.烷基-(二甲基氨基)氯硅烷的制备和光谱研究
    摘要:已经制备了同时与硅连接的同时含有氯和二甲基氨基的几种新化合物.一般的方法包括使合适的聚氯硅烷在乙醚中的溶液在约200oc下反应.-用二甲胺的乙醚溶液冷却50°.以这种方式制备的是ch 3 Si(nme 2)cl 2,Ch 3 Si(nme 2)2-Cl,Phsi(nme 2)cl 2,Phsi(nme 2)2 Cl,Ch 3(h)si(nme 2)氯,(ch 3)2的si(nme 2)氯,Ch 2 ch(ch3)si(nme 2)cl和ph 2 Si(nme 2)cl.这些化合物的光谱与全卤和全胺系列光谱的比较表明,用nme 2代替cl导致与硅连接的其他基团的共振发生高场移位,该移位与在取代ch 3时观测到的平行对于cl.红外光谱中的ν(sih)和NMR光谱中的δ(sih)呈线性关系.
    Doi:10.1016/s0022-328X(00)90592-8

    专利信息


    专利号:US-7402648-B2
    优先权日:2004-11-05
    标 题 :Method for producing cyclic organic silicon compound and organic silicon resin having alcoholic hydroxyl group
    发明人:KOMURO KATSUHIKO; SUZUKI HIROSHI
    权利人:TOAGOSEI CO LTD
    摘要:The object of the present invention is to provide a production method wherein synthesis of a cyclic organic silicon compound similar to oxa-silacyclopentanes is completed in a single-step reaction. It is also to provide an organic silicon resin having an alcoholic hydroxyl group, which is capable of easily controlling its construction and is longitudinally stable. n The means for solving is to produce the cyclic organic silicon compound represented by the formula (3) below by reacting an olefin represented by the formula (1) below and an alkoxysilane represented by the formula (2) below in the presence of a catalyst comprising a transition metal. n n(In the formula, Z is alkenyl group having carbon atoms from 2 to 5 where the terminal carbon atom forms a Câ•?C bond, R is methyl group or hydrogen atom, and Me is methyl group.)n n n(In the formula, R 1 is alkyl group or alkoxyl group, having carbon atoms from 1 to 3, and R 2 is alkyl group having carbon atoms from 1 to 3.)n n n(In the formula, Z′ is alkylene group having carbon atoms from 2 to 5.)n n And it is an organic silicon resin having an alcoholic hydroxyl group obtained by performing hydrolysis and condensation of a cyclic organic silicon compound represented by the formula (3) above, or of a mixture of this and a polyfunctional alkoxyilane.

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    合成参考文献

    合成方法参考DOI号:10.1016/S0022-328X(00)90592-8
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