CAS: 931-40-8; 4-(Hydroxymethyl)-1,3-Dioxolan-2-One
该化合物是碳酸盐环状衍生物,具有氢氧化甲基功能组,在有机合成和聚合物应用中具有多功能性,其活性氢化和碳酸酯组使其能用作聚碳酸酯和聚氨酯的单体,有助于具有增强热稳定性和机械性的材料.该化合物作为制药中间体和锂离子电池电解添加剂的前体也具有价值,其极地结构可提高离子导电性.其双功能再活动允许有选择地进行修改,使其在交叉反应和精细化学合成中有用.由于对湿度和热度的敏感性,该产品通常在受控制的条件下处理.
- 英文名称4-(Hydroxymethyl)-1,3-Dioxolan-2-One
- 中文名称4-(羟甲基)-1,3-二氧戊环-2-酮
- IUPAC名称4-(hydroxymethyl)-1,3-dioxolan-2-one
- 其它别名丙三醇1,2-碳酸酯; 4羟甲基13二氧杂戊环2酮; 4-Hydroxymethyl-2-Oxo-1,3-Dioxolane
- CAS编号931-40-8
- MFCD编号:MFCD00085561
- EINECS号:213-235-0
- FDA UNII编号:C15K4UUJ1E
- 分子式:C4H6O4
- 分子量:118.09
- 产品CID: 1970068
- 产品分类有机原料→分子砌块→脂肪杂环类化合物→二氧杂环戊烷类化合物
- 相似结构搜索
- 产品信息参考
;;;; - InChIKey: JFMGYULNQJPJCY-UHFFFAOYNA-N
- InChI=1/C4H6O4/c5-1-3-2-7-4(6)8-3/h3,5H,1-2H2…
- 计算化学: 氢键受体数4.0氢键供体数1.0可旋转键数1.0
相似化合物
826-29-9 16606-55-6 51260-39-0物理性质
MSDS等安全信息
欧盟法规
REACH注册ECHA物质C&L通报REACH预注册上下游产品
CAS号124-38-9 二氧化碳 | CAS号56-81-5 甘油 | CAS号616-38-6 碳酸二甲酯 | CAS号556-52-5 缩水甘油 | CAS号57-13-6 尿素 | CAS号201230-82-2 carbon monoxide | CAS号105-58-8 碳酸二乙酯 | CAS号826-29-9 4-((烯丙氧基)甲基)-1,... | CAS号96-24-2 3-氯-1,2-丙二醇 | CAS号557-25-5 丁酸甘油酯 | CAS号538-43-2 3-苯氧基-1,2-丙二醇 | CAS号622-04-8 1,3-二苯氧基-2-丙醇 | CAS号141734-28-3 4-(1,2-dichloro... | CAS号56-81-5 甘油 | CAS号556-52-5 缩水甘油 | CAS号1400916-65-5 2,3-dihydroxypr...合成工艺路线路线简述
- 合成目标产物 4-Hydroxymethyl-1,3-Dioxolan-2-One 主要起始原料 Glycerol And Dimethyl Carbonate
- 56-81-5 = 931-40-8
反应条件:1.1 Catalysts: Carbon; 3 H,80 °C
标题:Carbon-So3Na Catalysed Synthesis Of Glycerol Carbonate Via Transesterification Of Glycerol And Dimethyl Carbonate
作者:Sandhya Rani,Gundabathini; Jyotsna,Adigopula; Prabhavathi Devi,Bethala L. A.
参考文献:Chemistryselect 日期:2022 卷标:7(47)]
556-52-5 = 931-40-8
反应条件:1.1 4 H,20 Bar,90 °C
标题:Halide Aided Synergistic Ring Opening Mechanism Of Epoxides And Their Cycloaddition To Co2 Using Mcm-41-Imidazolium Bromide Catalyst
作者:Adam,Farook; Appaturi,Jimmy Nelson; Ng,Eng-Poh
参考文献:Journal Of Molecular Catalysis A: Chemical 日期:2014 卷标:386 页码:42-48]
556-52-5 = 931-40-8
反应条件:1.1 Catalysts: Pentaerythritol,Tetrabutylammonium Iodide; 1 Min,4 Bar,Rt; Rt -> 70 °C; 16 H,70 °C
标题:Cycloaddition Of Carbon Dioxide And Epoxides Using Pentaerythritol And Halides As Dual Catalyst System
作者:Wilhelm,Michael E.; Anthofer,Michael H.; Cokoja,Mirza; Markovits,Iulius I. E.; Herrmann,Wolfgang A.; Et Al
参考文献:Chemsuschem 日期:2014 卷标:7(5) 页码:1357-1360]
556-52-5 = 931-40-8
反应条件:1.1 Catalysts: Aluminum(1+),Ethyl[n,N,N-Tributyl-3-[[[2-[[[5-(1,1-Dimethylethyl)-2-(Hydroxy-Ko...; 5 H,1 Mpa,120 °C
标题:Method For Preparing Highly Active Bifunctional Catalyst For Reaction Of Carbon Dioxide And Epoxy Alkane To Prepare Cyclic Carbonate And Its Application
参考文献:China]
56-81-5 = 931-40-8
反应条件:1.1 4 H,70 - 100 °C
标题:Method For Preparing Glycerol Carbonate From Biodiesel Based Glycerol And Dimethyl Carbonate
参考文献:China]
56-81-5 = 931-40-8
反应条件:1.1 Reagents: Potassium Carbonate,Oxygen Catalysts: Selenium Solvents: Dimethylformamide; 24 H,0.1 Mpa,20 °C
标题:Facile Synthesis Of Glycerol Carbonate From Glycerol Using Selenium-Catalyzed Carbonylation With Carbon Monoxide
作者:Mizuno,Takumi; Nakai,Takeo; Mihara,Masatoshi
参考文献:Heteroatom Chemistry 日期:2010 卷标:21(7) 页码:541-545]
530-62-1 + 56-81-5 = 931-40-8
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; Rt -> 0 °C1.2 Rt -> 40 °C; 10 Min,40 °C; 40 °C -> Rt1.3 Reagents: Hydrogen Ion Solvents: Water; Ph 7.0,Rt
标题:Process For Manufacturing Of Glycerin Carbonate
参考文献:Brazil]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: 1H-Imidazolium,3-Butyl-2-Carboxy-1-Methyl-,Inner Salt Solvents: Water; 80 Min,74 °C
标题:Imidazolium-2-Carboxylate As An Efficient,Expeditious And Eco-Friendly Organocatalyst For Glycerol Carbonate Synthesis
作者:Naik,Prashant U.; Petitjean,Laetitia; Refes,Karima; Picquet,Michel; Plasseraud,Laurent
参考文献:Advanced Synthesis & Catalysis 日期:2009 卷标:351 页码:1753-1756]
556-52-5 = 931-40-8
反应条件:1.1 Catalysts: Zinc,Dibromobis(1,3,5,7-Tetraazatricyclo[3.3.1.13,7]Decane-N1)-,(T-4)-; 12 H,1.5 Mpa,60 °C
标题:Hexamethylenetetramine Complexes As Easy-To-Handle And Efficient Lewis Acid-Base Heterogeneous Catalysts For Coupling Of Co2 Under Mild Conditions
作者:Lan,Dong-Hui; Chen,Kun; Zhu,Heng-Jun; Shen,Jing; Wu,Shui-Sheng; Et Al
参考文献:Industrial & Engineering Chemistry Research 日期:2022 卷标:61(31) 页码:11390-11396]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: 1-Butyl-3-Methylimidazolium Hydrogen Carbonate; Rt -> 65 °C; 1.5 H,65 °C
标题:Application Of Dialkylimidazolium Bicarbonate As Catalyst In Catalytic Synthesis Of Glycerol Carbonate
参考文献:China]
556-52-5 = 931-40-8
反应条件:1.1 Catalysts: Tetrabutylammonium Iodide,2279076-92-3; 10 Bar,25 °C -> 120 °C; 18 H,120 °C
标题:New Zinc/tetradentate N4 Ligand Complexes: Efficient Catalysts For Solvent-Free Preparation Of Cyclic Carbonates By Co2/epoxide Coupling
作者:Karame,Iyad; Zaher,Samira; Eid,Nadim; Christ,Lorraine
参考文献:Molecular Catalysis 日期:2018 卷标:456 页码:87-95]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: Trisodium Phosphate; 60 Min,70 °C
标题:Glycerol Carbonate Synthesis From Glycerol And Dimethyl Carbonate Using Trisodium Phosphate
作者:Okoye,P. U.; Abdullah,A. Z.; Hameed,B. H.
参考文献:Journal Of The Taiwan Institute Of Chemical Engineers 日期:2016 卷标:68 页码:51-58]
556-52-5 = 931-40-8
反应条件:1.1 Catalysts: 1H-Imidazolium,3-(2-Chloroethyl)-1-[3-(Trihydroxysilyl)Propyl]-,Chloride (1:1) (Mcm-41 Supported); 4 H,20 Bar,90 °C
标题:Solid Imidazolium Halide Catalysts For The Solvent-Free Synthesis Of Glycerol Carbonate
作者:Appaturi,Jimmy Nelson; Ng,Eng-Poh; Adam,Farook
参考文献:Journal Of Co2 Utilization 日期:2014 卷标:6 页码:69-74]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: Calcium Magnesium Oxide (Ca0.8Mg1.2O2); 90 Min,70 °C
标题:Mg1+xca1-Xo2 As Reusable And Efficient Heterogeneous Catalyst For The Synthesis Of Glycerol Carbonate Via The Transesterification Of Glycerol With Dimethyl Carbonate
作者:Khayoon,M. S.; Hameed,B. H.
参考文献:Applied Catalysis 日期:2013 卷标:466 页码:272-281]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: Mg Al Hydrotalcite (Anion-Exchanged); 6 H,403 K
标题:Tunable Basic And Textural Properties Of Hydrotalcite Derived Materials For Transesterification Of Glycerol
作者:Alvarez,M. G.; Chimentao,R. J.; Figueras,F.; Medina,F.
参考文献:Applied Clay Science 日期:2012 卷标:58 页码:16-24]
556-52-5 = 931-40-8
反应条件:1.1 Reagents: Tetrabutylammonium Bromide Catalysts: Stereoisomer Of Bis[[4,4′-[(1R,2R)-1,2-Cyclohexanediyldi(Nitrilo-Kn)]Bis[2-Penta...; 24 H,1 Atm,26 °C
标题:Bimetallic Aluminium(Acen) Complexes As Catalysts For The Synthesis Of Cyclic Carbonates From Carbon Dioxide And Epoxides
作者:North,Michael; Young,Carl
参考文献:Catalysis Science & Technology 日期:2011 卷标:1(1) 页码:93-99]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: Aluminate (Al(Oh)63-),(Oc-6-11)-,Magnesium Carbonate Hydroxide (2:5:1:2) Solvents: Dimethylformamide; 2 H,100 °C
标题:Method For Preparation Of Glycerin Carbonate
参考文献:Japan]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: Potassium Carbonate; 5 H,71 - 76 °C
标题:Synthesis Of Glycerol Carbonate From Glycerol,A By-Product Of Biodiesel Production
作者:Herseczki,Zsanett; Varga,Tamas; Marton,Gyula
参考文献:International Journal Of Chemical Reactor Engineering 日期:2009 卷标:7]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: Stereoisomer Of Octabutyldi-μ-Chlorodichlorodi-μ3-Oxotetratin; 2 H,100 °C; 100 °C -> Rt
标题:Effect Of Lipophilicity Of Catalyst In Cyclic Carbonate Formation By Transesterification Of Polyhydric Alcohols
作者:Patel,Yogesh; George,Jimil; Pillai,S. Muthukumaru; Munshi,Pradip
参考文献:Green Chemistry 日期:2009 卷标:11(7) 页码:1056-1060]
56-81-5 = 931-40-8
反应条件:1.1 Catalysts: Dabco; 16 H,75 °C
标题:Carbonate Couplers And Functional Cyclic Carbonates From Amino Acids And Glucosamine
作者:Fricke,Nicole; Keul,Helmut; Moeller,Martin
参考文献:Macromolecular Chemistry And Physics 日期:2009 卷标:210(3-4) 页码:242-255
4-(((Trimethylsilyl)Oxy)Methyl)-1,3-Dioxolan-2-One置于盐酸体系中,用 甲醇,水 作为反应溶剂,化学反应 2.0H,以99.5%的收率获得产物羟甲基二氧杂戊环酮
参考文献:一种碳酸甘油酯合成方法
标题:一种碳酸甘油酯合成方法
摘要:本发明涉及碳酸甘油酯领域,具体为一种高纯度的碳酸甘油酯合成方法,通过利用缩水甘油制备高纯度的碳酸甘油酯.首先将缩水甘油,三乙胺和二氯甲烷入到反应釜中,降温至零度,滴加硅基保护基团,滴加完毕,恢复室温反应过夜,水洗,干燥,蒸馏得到硅基保护的缩水甘油,然后利用催化剂与二氧化碳加成得到硅基保护的碳酸甘油酯,再利用酸脱保护,蒸馏掉溶剂得到高纯度的碳酸甘油酯.本发明工艺操作简单,原料可回收套用,产品纯度高,危险性小,适合工业化生产.
海关参考信息
- 2905122000-异丙醇
2905310000-1,2-乙二醇
2905320000-1,2-丙二醇
2905399001-1,3-丙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-9950988-B2
优先权日:2012-12-26
标题:Method for the synthesis of alpha/alpha-prime-alcoxylated glycerol linear carbonic esters
发明人：LEISING FRéDéRIC; MOULOUNGUI ZéPHIRIN
权利人:CHRYSO; INST NAT POLYTECHNIQUE TOULOUSE; INST NAT DE LA RECH AGRONOMIQUE INRA
摘要:A method for the synthesis of α/α′-alcoxylated glycerol linear carbonic esters, wherein the following are brought into contact at a reaction temperature lower than 220° C.: a quantity of at least one precursor selected from the group consisting of α/α′-alcoxylated glycerol cyclo-carbonates; a quantity of at least one catalyst selected from the group consisting of metal oxides, Lewis acids, organometallic catalysts and mineral bases; and a quantity of at least one organic primer. A composition containing at least one novel α/α′-alkoxylated glycerol linear carbonic ester.
专利号:US-11897860-B2
优先权日:2022-03-14
标题 :Direct synthesis of cyclic carbonates using choline chloride as catalyst under mild conditions
发明人：CARRASCO ANALETTE; WEERS JERRY J; BLACKWELL CATHERINE C; MURUGESAN SANKARAN; WANG XIAOFENG; NUGENT DOUGLAS; ROBERTS CORBY A
权利人:BAKER HUGHES OILFIELD OPERATIONS LLC
摘要:A method for direct synthesis of cyclic carbonates is achieved by reacting at least one epoxide with carbon dioxide in the presence of a choline catalyst, such as choline chloride, under mild conditions such as a temperature between about 25° C. to 150° C. and a pressure of from about atmospheric to 75 psi (0.52 MPa), in a cyclic carbonate solvent. The choline catalyst may be the only catalyst used, and a co-catalyst or hydrogen bond donor is not necessary. The concentration of choline catalyst in the solvent ranges from about 0.5 mol % to about 10 mol %, based on the epoxide.
专利号:US-5326885-A
优先权日:1992-05-01
标 题 :Process of preparing enriched enantiomers of glycerol carbonate and derivatives thereof for synthesis of β-blockers
发明人：OLIVERO ALAN G; CASSEL JONATHAN M; POULSEN JAMES R
权利人:COGNIS INC
摘要:Enriched enantiomers of glycerol Carbonate are produced under the influence of a hydrolytic enzyme, either by selective esterification of racemic glycerol carbonate or by selective hydrolysis of an ester of the racemate. The enriched enantiomeric product is readily converted to starting materials and intermediates useful in the synthesis of enantiomerically pure therapeutic agents, such as beta -adrenergic blockers.
专利号:EP-1992632-A1
优先权日:2007-05-12
标题 :Method for the synthesis of cyclouridine
发明人：MOCIARDINI SIMONE; COLOMBO PAOLO
权利人:EXPLORA LAB SA
摘要:Method for the synthesis of possibly substituted cyclic derivatives of uridine, of formula (II)n nwherein R is chosen in the group that comprises: hydrogen, halogen and C 1-4 alkyl, the method comprising the step of reacting a possibly substituted uridine of formula (III)n nwherein R has the same meanings as in formula (II), and glycerol carbonate in the presence of an alkaline carbonate at a temperature of 70°C-130°C.
专利号:WO-2014059961-A1
优先权日:2012-10-15
标 题 :Method for the synchronous absorption of carbon dioxide from flue gas and synthesis of dialkyl carbonates and alkylene carbonates
发明人：BÃœTTNER HERMANN; Müller Jürgen; JONKER RAPHAEL; DOEDT SEBASTIAN; BOSSE TOBIAS; MAKRAN SEBASTIAN
权利人:BÃœTTNER HERMANN
摘要:The invention relates to a synchronous CCU method (carbon dioxide capture and utilisation) for the absorption of carbon dioxide from flue gas and other CO 2 -containing substance sources and simultaneous synthesis of dialkyl carbonates and alkylene carbonates. The general subject matter of the invention is, in terms of a 'carbon dioxide capture' on the one hand, the absorption of CO 2 from flue gas and other CO 2 -containing substance sources with ammonia and/or amines to form ammonium carbamates or ammonium hydrogen carbonates or ureas or urea intermediates and, in terms of a 'carbon dioxide utilisation' on the other hand, the reaction of ammonium carbamates or ammonium hydrogen carbonates or ureas or urea intermediates with aliphatic, alicyclic or unsaturated alcohols, and including unsaturated aromatic alcohols to give dialkyl carbonates or alkylene carbonates in such a form that the CO 2 n absorption agent is re-released and fed back into the repetitive process again. A repetitive process control is extremely energy and CO 2 n efficient.
专利号:US-2024425446-A1
优先权日:2023-06-23
标题:Dichloromethane-free synthesis of cyclopropenimines
发明人：HEDRICK JAMES L; CAMPOS LUIS M; PARK NATHANIEL H; WU DINO
权利人:IBM; THE TRUSTEE OF COLUMBIA UNIV IN THE CITY OF NEW YORK
摘要:A process of forming a cyclopropenimine (CPI) is disclosed. The process includes obtaining a solution of pentachlorocyclopropane (PCC) dissolved in a first solvent and adding a secondary amine to the solution. The process further includes obtaining precipitated products, including a CPI chloride (CPI−Cl) salt and a secondary amine salt, of a reaction between the secondary amine and the PCC and mixing the precipitated products in a second solvent. The CPI−Cl salt is substantially soluble in the second solvent and the secondary amine salt is substantially insoluble in the second solvent. A CPI composition, an apparatus containing the CPI composition, a process of capturing carbon dioxide (CO2) with the CPI composition, and a process of generating carbonate with the CPI composition are also disclosed.
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📌 第三方产品分析报告
主要参考文献
参考标题:Synthesis Of Cyclic Carbonates With Carbon Dioxide And Cesium Carbonate作者:Michael R. Reithofer,Yin Ngai Sum,Yugen Zhang
摘要:Cyclic Carbonates Are Important Compounds For The Synthesis Of Biocompatible Polymers And Linear Dialkyl Carbonates, As Well As Solvents And Electrolytes. We Report Here The Synthesis Of Such Compounds From Easily Accessible Starting Materials With Carbon Dioxide As A C1 Source And Caesium Carbonate As The Base. This New Methodology Is Able To Yield 5- And 6-Membered Cyclic Carbonates Very Efficiently
合成参考文献
摘要:Li, H.; Wang, Y.; Liu, Q., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 558.
📝 需求与反馈
尽可能描述清楚需求与问题信息
