CAS: 706-07-0; 1-Chloro-4-(2-Nitrovinyl)Benzene

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CAS号75-52-5 硝基甲烷 | CAS号104-88-1 对氯苯甲醛 | CAS号1615-02-7 4-氯肉桂酸 | CAS号1073-67-2 对氯苯乙烯 | CAS号1749-03-7 1-(4-chlorophen... | CAS号3395-81-1 4-氯苯甲醛二甲基缩醛 | CAS号22245-95-0 7-氯-3,4-二氢-2H-异... | CAS号29655-76-3 diethyl 2-[1-(4... | CAS号82626-74-2 6-氯-2-(4-氯苯基)咪唑... | CAS号69308-37-8 (R)-巴氯芬(mM/ml) | CAS号128869-29-4 1-chloro-4-(2-n... | CAS号360072-54-4 METHYL 3-(4-CHL... | CAS号1019-85-8 2-(4-氯苯基)苯并咪唑 | CAS号140-53-4 对氯苯乙腈 | CAS号156-41-2 对氯苯乙胺 | CAS号114012-12-3 3-氨基-2-(4-氯苯基)丙基膦酸

📜(4-Chlorostyryl)Boronic Acid置于硝酸体系中,用 1,2-二氯乙烷 作为反应溶剂,化学反应 16.0H,以38%的收率获得产物1-(4-氯苯基)-2-硝基乙烯
参考文献:用发烟硝酸对芳基硼酸进行 Ipso 硝化
标题:用发烟硝酸对芳基硼酸进行 Ipso 硝化
摘要:使用发烟硝酸作为硝化剂,已经开发了芳基硼酸衍生物的原位硝化.这种简便的程序提供了对各种芳族硝基化合物的有效和化学选择性访问.虽然文献中已经报道了几种活化剂和硝基源可用于这种综合有用的转化,但本报告表明这些过程可能会产生一种常见的活性试剂无水 Hno 3.动力学和机理研究表明,Hno 3中的反应级数大于2,表明• No 2自由基是活性物质.
DOI:10.1021/acs.Joc.1C00886

专利信息

专利号:US-7968734-B2
优先权日:2004-07-01
标 题 :Organocatalysts and methods of use in chemical synthesis
发明人：WANG WEI; WANG JIAN; LI HAO
权利人:STC UNM
摘要:The present invention pertains generally to compositions comprising organocatalysts that facilitate stereo-selective reactions and the method of their synthesis and use. Particularly, the invention relates to metal-free organocatalysts for facilitation of stereo-selective reactions, and the method of their synthesis and use.

专利号:CN-101343263-A
优先权日:2008-08-25
标题:Method for synthesis of 5-nitryl-4, 5-dihydrofuran derivant

专利号:US-2007244328-A1
优先权日:2004-07-01
标 题 :Organocatalysts and Methods of Use in Chemical Synthesis

专利号:CN-107188771-B
优先权日:2017-05-25
标题 :Chiral synthesis method of gamma-nitrophenol compound