CAS: 2688-96-2; [1,1'-Biphenyl]-2-Thiol

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CAS号90-41-5 2-氨基联苯 | CAS号132-27-4 邻苯基苯酚钠 | CAS号90-43-7 2-苯基苯酚 | CAS号139-66-2 苯硫醚 | CAS号1623-99-0 phenyl-sodium | CAS号945-51-7 二苯基亚砜 | CAS号129922-51-6 2-三氟甲硫基-1,1’-联苯 | CAS号129922-37-8 S-(TRIFLUOROMET... | CAS号160656-62-2 S-(三氟甲基)二苯并噻吩-3-磺酸盐 | CAS号129946-88-9 S-(三氟甲基)二苯并噻吩三氟甲基磺酸盐 | CAS号129922-49-2 2-联苯基三氟甲基亚砜 | CAS号19813-97-9 2-Biphenylyl di...

📜二苯并噻吩置于sodium Hydroxide,联苯,Lithium体系中,用 四氢呋喃,乙醚,水,甲苯 用作溶剂,化学反应 4.0H,反应生成2-苯基苯硫酚
参考文献:开环二苯并噻吩及其相关的二巯基联二芳基配体的钛茂复合物
标题:开环二苯并噻吩及其相关的二巯基联二芳基配体的钛茂复合物
摘要:本文介绍了由二茂钛二氯化物与二烯并噻吩(dbt)衍生物反应制得的有机钛衍生物.Dbt的锂裂解产生2,2'-Li(lis)c 12 H 8,其与(c 5 H 5)2 Ticl 2反应,得到金属环配合物(c 5 H 5)2 Tisc 12 H 8(1).分离了少量的两种副产物,硫醇盐(c 5 H 5)2 Ti(sc 6 H 4-2-Ph)2(2)和(c 5H 5)2 Ti(sc 6 H 4-2-Ph)cl.DNMR研究表明1和它的mec 5 H 4类似物3由于有机硫螯合物的折叠而在立体化学上是非刚性的.通过单晶x射线衍射确认了(mec 5 H 4)2 Tisc 12 H 8的结构.该络合物由与环裂解的dbt的碳和硫配位的预期(mec 5 H 4)2 Ti部分组成.尝试生成2,2'-Li(lis)c 12 H 8通过在tmeda存在下,将2-苯基苯硫醇与两个当量的buli进行双金属化,然后用(c
Doi:10.1016/s0022-328X(96)06581-3

专利信息

专利号:US-9000198-B2
优先权日:2013-05-21
标 题:Mixed-valent transition metal-phosphoranimide catalysts
发明人：BROWN HOUSTON J S; STRYKER JEFFREY MARK; HEBERT DOMINQUE M
权利人:UNIV ALBERTA
摘要:Phosphoranimide-metal catalysts are disclosed. The catalysts comprise first row transition metals such as nickel, cobalt or iron. The hydrocarbon-soluble catalysts have a metal to anionic phosphoranimide ratio of 1:1, and have no inactive bulk phase and no dative ancillary ligands. The electronic state of the clusters can be adjusted to optimize catalytic activity for a range of commercially important reductive transformations, including hydrodesulfurization. A method of synthesis of these catalysts by anionic metathesis of a halide substituted precursor followed by oxidation is also disclosed.

专利号:US-6121495-A
优先权日:1995-09-12
标题:Ethynyl substituted aromatic compounds, synthesis, polymers and uses thereof
发明人：BABB DAVID A; SMITH JR DENNIS W; MARTIN STEVEN J; GODSCHALX JAMES P
权利人:DOW CHEMICAL CO
摘要:Compounds of ethynyl aromatic compounds form polymers which have high thermal stability. The monomers are useful for coating a wide variety of substances such as dielectric coatings where high thermal resistance is desirable including electronic components such as computer chips.

专利号:US-8901334-B2
优先权日:2012-12-21
标 题 :Transition metal-phosphoranimide catalysts
发明人：BUNQUIN JEFFREY CAMACHO; STRYKER JEFFREY MARK
权利人:UNIV ALBERTA
摘要:Phosphoranimide-metal catalysts are disclosed. The catalysts comprise first row transition metals such as nickel, cobalt or iron. The hydrocarbon-soluble catalysts have a metal to anionic phosphoranimide ratio of 1:1, have no inactive bulk phase and no dative ancillary ligands, and are active for a range of commercially important reductive transformations. A method of synthesis of these catalysts by reduction of a precursor of these catalysts is also disclosed.

专利号:CN-117551673-A
优先权日:2023-11-10
标 题:Application of glycosyltransferase RrUGT3 gene in the synthesis of N-glycosides and S-glycosides

专利号:US-8664277-B2
优先权日:2008-09-19
标 题:Compounds and methods for PKCθ inhibition
发明人：AJIOKA JANET; HUMMEL HEIDI S; MEYER RICH B; SWINDLE JOHN
权利人:COMPLEGEN PARTNERS LLC
摘要:The present invention provides a method of selectively inhibiting PKCθ in the presence of PKCδ, by administering to a subject in need thereof, a therapeutically effective amount of a compound of Formula I. The present invention also provides a method of inhibiting cytokine synthesis in a T cell, a method of inhibiting T cell proliferation, and a method of inhibiting the replication of and cytokine production by T lymphocytes, while not stimulating or inhibiting the replication of B lymphocytes.

专利号:CN-117624121-A
优先权日:2023-11-28
标 题:A kind of synthesis method of dibenzothiophene