CAS: 16971-33-8; Carbonylchlorohydridotris(Triphenylphosphine)Ruthenium(Ii)

上下游产品

2-methoxy-ethanol formaldehyd ruthenium trichloride hydrate triphenylphosphine2(PPh3)2RuHCl(CO)NHEt2(PPh3)2

专利信息

专利号:US-2023212216-A1
优先权日:2019-12-20
标 题:Synthesis of lactone derivatives and their use in the modification of proteins
发明人：MORRIS ALEXANDER REDFERN; SUTOV GRIGORIJ; BRUNE KARL DIETRICH
权利人:GENIE BIOTECH UK LTD
摘要:Site-specific modifications of proteins are desirable in biotechnological applications such as biopharmaceuticals, immunotherapy, vaccines, and are useful in chemical biology. Gluconoylation is a non-enzymatic, covalent, post-translational modification commonly observed on N-terminal His-Tags bearing proteins. We synthesized glucono-1,5-lactone derivatives, including azido variants for selective acylation. High yield acylation is achieved by simply mixing derivatives with target protein amidst diverse conditions of temperatures, aqueous buffers, excipients, or complex cell lysate.

专利号:US-9045381-B2
优先权日:2010-10-19
标 题:Ruthenium complexes and their uses in processes for formation and/or hydrogenation of esters, amides and derivatives thereof
发明人：MILSTEIN DAVID; BALARAMAN EKAMBARAM; GUNANATHAN CHIDAMBARAM; GNANAPRAKASAM BOOPATHY; ZHANG JING
权利人:MILSTEIN DAVID; BALARAMAN EKAMBARAM; GUNANATHAN CHIDAMBARAM; GNANAPRAKASAM BOOPATHY; ZHANG JING; YEDA RES & DEV
摘要:The present invention relates to novel Ruthenium catalysts and related borohydride complexes, and the use of such catalysts, inter alia, for (1) hydrogenation of amides (including polyamides) to alcohols and amines; (2) preparing amides from alcohols with amines (including the preparation of polyamides (e.g., polypeptides) by reacting dialcohols and diamines and/or by polymerization of amino alcohols); (3) hydrogenation of esters to alcohols (including hydrogenation of cyclic esters (lactones) or cyclic di-esters (di-lactones) or polyesters); (4) hydrogenation of organic carbonates (including polycarbonates) to alcohols and hydrogenation of carbamates (including polycarbamates) or urea derivatives to alcohols and amines; (5) dehydrogenative coupling of alcohols to esters; (6) hydrogenation of secondary alcohols to ketones; (7) amidation of esters (i.e., synthesis of amides from esters and amines); (8) acylation of alcohols using esters; (9) coupling of alcohols with water to form carboxylic acids; and (10) dehydrogenation of beta-amino alcohols to form pyrazines. The present invention further relates to the novel uses of certain pyridine Ruthenium catalysts.

专利号:US-8372986-B2
优先权日:2005-09-30
标 题 :Ruthenium-catalyzed cycloaddition of alkynes and organic azides
发明人：FOKIN VALERY; JIA GUOCHENG; SHARPLESS K BARRY
权利人:SCRIPPS RESEARCH INST; UNIV HONG KONG SCIENCE & TECHN; FOKIN VALERY; JIA GUOCHENG; SHARPLESS K BARRY
摘要:A convenient process for the regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles and 1,4,5-trisubstituted 1,2,3-triazoles from organic azides and alkynes employs catalytic ruthenium.

专利号:US-9944579-B2
优先权日:2015-01-15
标题 :Catalytic hydrogenation process for the synthesis of terminal diols from terminal dialkyl aliphatic esters
发明人：BALARAMAN EKAMBARAM; SAHOO MANOJ KUMAR
权利人:COUNCIL SCIENT IND RES
摘要:A phosphorus ligand-free, mild, efficient and complete catalytic hydrogenation process is for the sustainable production of terminal diols from renewable terminal dialkyl esters with improved yield. Soluble, phosphorus ligand free Ru (II)-pincer type complexes can be used as catalysts in the hydrogenation process.

专利号:WO-2023248205-A1
优先权日:2022-06-23
标 题 :Novel ruthenium complexes, method of their synthesis, intermediate compounds used in this method, method of their synthesis and the use of novel ruthenium complexes in olefin metathesis reactions
发明人：GRELA KAROL; KAJETANOWICZ ANNA; SYTNICZUK ADRIAN; MILEWSKI MARIUSZ; PUROHIT VISHAL; STRUZIK FILIP
权利人:UNIV WARSZAWSKI
摘要:The subject of the invention is a novel ruthenium complex with the general formula Ru-1, in which all the variables have the meaning defined in the disclosure. The subject of the invention is also a synthesis method of the ruthenium complex, an intermediate which is a precursor of the ligand used in the synthesis reactions of the ruthenium complex CAAC-1 and application of this ruthenium complex as a (pre)catalyst in olefin metathesis reactions.

专利号:US-11964260-B2
优先权日:2016-08-08
标题:Method for manufacturing ammonia synthesis catalyst, and method for manufacturing ammonia
发明人：HOSONO HIDEO; KITANO MASAAKI; YOKOYAMA TOSHIHARU; LI JIANG; KAWAMURA SHIGEKI; KISHIDA Kazuhisa
权利人:TOKYO INST TECH; TSUBAME BHB CO LTD
摘要:Provided is a method for manufacturing a catalyst with which it is possible to obtain a supported metal ammonia synthesis catalyst, in which there are restrictions in terms of producing method and producing facility, and particularly large restrictions for industrial-scale producing, in a more simple manner and so that the obtained catalyst has a high activity. This method for manufacturing an ammonia synthesis catalyst includes: a first step for preparing 12CaO·7Al 2 O 3 having a specific surface area of 5 m 2 /g or above; a second step for supporting a ruthenium compound on the 12CaO·7Al 2 O 3 ; and a third step for performing a reduction process on the 12CaO·7Al 2 O 3 supporting the ruthenium compound, obtained in the second step. This invention is characterized in that the reduction process is performed until the average particle diameter of the ruthenium after the reduction process has increased by at least 15% in relation to the average particle diameter of the ruthenium before the reduction process.