CAS: 1078-71-3; Heptylbenzene

相似化合物

123-01-3 2189-60-8 4445-07-2

上下游产品

CAS号629-04-9 1-溴庚烷 | CAS号98-80-6 苯硼酸 | CAS号2996-92-1 苯基三甲氧基硅烷 | CAS号100-59-4 苯基氯化镁 | CAS号108-90-7 氯苯 | CAS号19969-03-0 1-butyl-3-pheny... | CAS号637-59-2 1-溴-3-苯基丙烷 | CAS号92273-73-9 丁基溴化锌 | CAS号4282-40-0 1-碘庚烷 | CAS号37593-03-6 4'-庚基苯乙酮 | CAS号38350-87-7 对正庚基苯甲酸 | CAS号37529-27-4 4-庚基苯胺 | CAS号50606-96-7 4-庚基苯甲酰氯 | CAS号79887-12-0 4-庚基苯乙炔 | CAS号76287-49-5 1-溴-4-庚苯 | CAS号5617-41-4 庚基环己烷 | CAS号2189-60-8 正辛基苯 | CAS号16577-10-9 4-heptylbenzene... | CAS号49763-67-9 4-正庚基苯甲醛

📜正庚醇置于吡啶,Cubr*me2S-Libr,苯硫酚锂,Magnesium体系中,化学反应 27.0H,反应生成庚基苯
参考文献:新型可溶性铜催化剂 [cubr-Lisph-Libr-Thf] 的范围和实用性:与其他铜催化剂在将一种等价的格氏试剂与烷基磺酸盐偶联的能力方面的比较
标题:新型可溶性铜催化剂 [cubr-Lisph-Libr-Thf] 的范围和实用性:与其他铜催化剂在将一种等价的格氏试剂与烷基磺酸盐偶联的能力方面的比较
摘要:等量的 Cubr−sme2,Libr 和 Lisph置于0oc 的 Thf 中的混合物提供了一种新的可溶性铜催化剂,该催化剂在将伯,仲,叔,芳基,乙烯基和烯丙基格氏试剂与伯甲苯磺酸盐和主要格氏试剂到二级甲苯磺酸盐和甲磺酸盐,所有这些都只使用 1 当量的格氏试剂.新催化剂被证明比铜催化剂 Cubr 和 Li2Cucl4 更具反应性,并且在转移仲和叔烷基方面比低级铜酸盐(吉尔曼试剂)更有效,并且表现出比低级铜酸盐更高的反应性及其偶联能力初级格氏试剂到次级磺酸盐.格氏试剂/催化剂系统与酯官能化甲苯磺酸酯相容,因此证明比没有催化剂的格氏试剂更具化学选择性.该催化剂在室温以下表现出非常好的反应活性,并且在催化剂溶液中加入6% V/v的hmpa...
Doi:10.1021/ja963944Q

专利信息

专利号:US-2003162992-A1
优先权日:2001-12-14
标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
发明人：WATANABE KYOICHI A; DU JINFA
摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

专利号:US-11306041-B2
优先权日:2017-03-30
标 题:Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts
发明人：SCHINSKI WILLIAM; GOLDMAN ALAN; GUNNOE THOMAS B; WEBSTER-GARDINER MICHAEL S; SCHWARTZ NICHOLE
权利人:UNIV VIRGINIA PATENT FOUNDATION
摘要:Catalytic methods for synthesis of super linear alkenyl arenes and alkyl arenes are provided. The methods are capable of synthesizing super linear alkyl and alkenyl arenes from simple arene and olefin starting materials and with high selectivity for linear coupling. Methods are also provided for making a 2,6-dimethylnapthalene (DMN) or 2,6-methylethylnapthalene (MEN).

专利号:US-7250510-B2
优先权日:2005-08-24
标 题:Transition metal complexes of N-heterocyclic carbenes, method of preparation and use in transition metal catalyzed organic transformations
发明人：ORGAN MICHAEL G; O'BRIEN CHRISTOPHER J; KANTCHEV ASSAM ERIC B
权利人:TOTAL SYNTHESIS LTD
摘要:The present invention relates to catalysts of transition metal complexes of N-heterocyclic carbenes, their methods of preparation and their use in chemical synthesis. The synthesis, ease-of-use, and activity of the compounds of the present invention are substantial improvements over in situ catalyst generation. Further, the transition metal complexes of N-heterocyclic carbenes of the present invention may be used as precatalysts in metal-catalyzed cross-coupling reactions.

专利号:US-5304647-A
优先权日:1988-02-09
标题:Method of preparation of halogenated diazines
发明人：STREKOWSKI LUCJAN; MOKROSZ MARIA; HARDEN DONALD B
权利人:UNIV GEORGIA STATE
摘要:A method of preparation of substituted halogenodiazines which are useful as intermediates in the synthesis of novel unfused heterobicyclic compounds, and the products thereof. The reaction consists of the addition of an organolithium reagent with subsequent dehydrogenation of the addition product. The reaction takes place in one reaction vessel, without isolation of the substituted halogenodihydrodiazine intermediate. The reactions proceed at moderate temperature and in a short amount of time, which decreases the probability of side reactions and increases yield. Furthermore, the workup step is conducted under two-phase conditions to prevent hydrolysis of the substituted halogenodiazine to a substituted hydroxydiazine. The method is easy, efficient and results in a high yield of product. The substituted halogenodiazines are used as intermediates in the synthesis of unfused heterobicyclic compounds containing an aromatic moiety, diazine, and another aromatic moiety, such as thiophene, benzene, or naphthalene, which have biological activity.

专利号:US-10940467-B2
优先权日:2014-01-27
标 题 :Synthesis of molecular sieves having MWW framework structure
发明人：JOHNSON IVY D; HRYCENKO NADYA A
权利人:EXXONMOBIL CHEMICAL PATENTS INC
摘要:The present invention provides an improved method for making molecular sieves having MWW framework structure using precipitated aluminosilicates (PAS), and the use of molecular sieves so made in processes for catalytic conversion of hydrocarbon compounds.

专利号:US-2002058286-A1
优先权日:1999-02-24
标 题 :Synthesis of epothilones, intermediates thereto and analogues thereof
发明人：DANISHEFSKY SAMUEL J; STACHEL SHAWN J; LEE CHUL BOM; CHAPPELL MARK D; CHOU TING-CHAO; WU ZHICAI
摘要:The present invention provides convergent processes for preparing epothilones, desoxyepothilones, and analogues thereof. The present invention further provides novel compositions and methods for the treatment of cancer and additionally provides methods for the treatment of cancer which has developed a multi-drug phenotype.