CAS: 358-63-4; Tris(2,2,2-Trifluoroethyl)Phosphate

相似化合物

370-69-4 1623-19-4 78-40-0

上下游产品

CAS号75-89-8 三氟乙醇 | CAS号370-69-4 三(2,2,2-三氟乙烷基)亚磷酸盐 | CAS号61358-25-6 双(4-叔丁基苯)碘六氟磷酸盐 | CAS号1825-33-8 phenylazo-i-but... | CAS号71181-76-5 pentakis(2,2,2-... | CAS号353-83-3 2,2,2-三氟碘乙烷

2,2,2-三氟乙醇置于五氯化磷体系中,化学反应 12.0H,以73%的收率获得产物磷酸三(2,2,2-三氟乙基)酯
参考文献:氟化磷化合物:第3部分.对称和不对称氟烷基磷酸酯的合成
标题:氟化磷化合物:第3部分.对称和不对称氟烷基磷酸酯的合成
摘要:五氯化磷与氟代醇的4个摩尔当量的处理,得到对称的磷酸盐(r ˚f O)3 Po中分离产率10-92%之间[r ˚f cf 3 Ch 2,C 2 ˚f 5 Ch 2,Hcf 2 Cf 2 Ch 2,C 3 F 7 Ch 2,(fch 2)2 Ch,(cf 3)2 Ch,C 2 F 5(ch 3)ch].对于具有许多氟原子的氟代醇,反应进行得最好.2,2-二氟乙醇hcf 2 CH2Oh和1,3-二氟异丙醇(fch 2)2 Choh不能干净地反应,得到产物混合物.六氟异丙醇制得对称磷酸盐[(cf 3)2 Cho] 3 P = O和氯磷烷[(cf 3)2 Cho] 4 Pcl的3:7混合物.后者容易与水和醇反应.加热氯化物cf 3 CH2Op(o)cl 2,(cf 3 CH2O)2在氯化钙催化剂存在下,P(o)cl和(c 2 F 5 CH2O)2 P(o)cl与各种氟代醇的不对
DOI:10.1016/s0022-1139(00)00327-4

专利信息

专利号:US-11862794-B2
优先权日:2020-05-06
标题:Cost effective synthesis of oxide materials for lithium ion batteries

专利号:US-2024351913-A1
优先权日:2020-05-06
标 题 :Cost effective synthesis of oxide materials for lithium ion batteries

专利号:US-12211999-B2
优先权日:2020-05-06
标题:Cost effective synthesis of oxide materials for lithium ion batteries
发明人：XIAO JIE; BI YUJING
权利人:BATTELLE MEMORIAL INSTITUTE
摘要:Methods for synthesizing single crystalline Ni-rich cathode materials are disclosed. The Ni-rich cathode material may have a formula LiNi X Mn y M z Col 1-x-y-z O 2 , where M represents one or more dopant metals, x≥0.6, 0.01≤y<0.2, 0≤z≤0.05, and x+y+z≤1.0. The methods are cost-effective, and include methods for solid-state, molten-salt, and flash-sintering syntheses.

专利号:US-2024088382-A1
优先权日:2020-05-06
标题 :Cost effective synthesis of oxide materials for lithium ion batteries

专利号:US-9879037-B2
优先权日:2012-03-30
标 题 :Fluorine-containing phosphate ester-amide, and flame retardant resin, flame retardant liquid and flame retardant solvent for organic synthesis containing same
发明人：MIMURA HIDEYUKI; FUJITA HIROAKI; EGUCHI HISAO
权利人:TOSOH F-TECH INC
摘要:[Problem] To provide a fluorine-containing phosphate ester-amide which has high flame retardancy such as exhibiting flame retardant effects at a small quantity of addition, and sufficient hydrolysis resistance. n [Solution] A fluorine-containing phosphate ester-amide represented by general formula (1). (In the formula, R1 and R2 are the same or different and represent a branched or linear alkyl group having 1 to 20 carbon atoms in which at least one carbon bonded to a nitrogen atom is a secondary or tertiary carbon, wherein R1 and R2 may have a substituent group selected from the group consisting of an alkoxy group, a hydroxy group, an amino group, a methyl amino group, an ethyl amino group, a dimethyl amino group, diethyl amino group and a fluorine atom. In addition, R1 and R2 may be bonded together to form a five- to eight-membered cyclic structure. X and Y are the same or different and represent a hydrogen atom or a fluorine atom, and n and m represent an integer of 1 to 6.)

专利号:WO-2022026014-A2
优先权日:2020-05-06
标 题:Cost effective synthesis of oxide materials for lithium ion batteries