CAS: 3468-11-9; 1-Imino-1H-Isoindol-3-Amine

📜1,2-二氰基苯置于sulfur 氨体系中,化学反应 6.0H,以100%的收率获得1,3-二亚胺基异吲哚啉
参考文献:Elemental Sulfur-Catalyzed Synthesis Ofn,N'-Disubstituted 1,3-Diiminoisoindolines From Phthalonitrile With Ammonia And Amines
标题:Elemental Sulfur-Catalyzed Synthesis Ofn,N'-Disubstituted 1,3-Diiminoisoindolines From Phthalonitrile With Ammonia And Amines
摘要:通过元素硫催化邻苯二腈与氨和一些伯胺的反应,合成了各种 N,N'-二取代的 1,3-二亚氨基异吲哚啉,产量极高.此外,还以高产率获得了几种官能化的异吲哚胺.
Doi:10.1246/cl.1984.1423

专利信息

专利号:US-2018208775-A1
优先权日:2014-06-23
标 题:New aromatic macrocyclic metal complex dyes and the synthesis thereof with active nano metal powders
发明人：OLGUN UGURSOY; YILDIZ SALIH ZEKI
权利人:OLGUN UGURSOY; YILDIZ SALIH ZEKI
摘要:The present invention relates to a new type of inorganic coordination compound dyes having advanced technology optical, electronic and medical characteristics and relates to production of these dyes by means of new synthesis methods. The present invention relates to dyes which are metal (M: Li, Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, Sb, Bi, Se, Te) complexes of aromatic macrocyclic compounds of the type Phtalocyanine (Pc), Naphtalocyanine (Nc), Porphyrazine (Pz), Porphyrin (Pr), sub-Phtalocyanine (subPc), sub-Naphtalocyanine (subNc), sub-Porphyrazine (subPz), sub-Porphyrine (subPr), and relates to the synthesis of these complexes and derivatives. The subject matter dyes can be used in solar cell photovoltaic (PV) panels, in OLEDS which are organic structured light emitting diodes, in polymers, in textile and in photodynamic therapy PDT applications. Moreover, industrial applications are possible which depend on strong fluorescence characteristics.

专利号:US-6491796-B1
优先权日:2001-06-26
标 题:Synthesis of phthalocyanines by microwave irradiation
发明人：HU ANDREW TEH; TSENG TSAI-WIE; HWU HERNG-DAR; LIU LUNG-CHANG; LEE CHUNG-CHUN; LEE MING-CHIA; CHEN JUN-RONG
权利人:AGI CORP; UNIV TSINGHUA
摘要:This invention provides a novel process for preparing soluble phthalocyanines by microwave irradiation in the absence of any organic solvent. Three different starting materials, i.e. t-butylphthalic anhydride, t-butyl phthalonitrile and metal-free H 2 Pc (tetra-t-butylphthalocyanine) have been adopted, respectively. The starting material with proper metal compound, such as chloride or acetate were irradiated in a commercial microwave oven for a period of 1 to 30 minutes at a power of 200Ëœ900 W. This process is noted to reduce drastically reaction time of MPc formation from 8Ëœ24 hours to 10Ëœ30 minutes due to its unique heating by microwave irradiation. Sandwiched type MPc 2 (such as Lu Pc 2 ) can be produced only through metal replacement from metal-free phthalocyanine by microwave irradiation.

专利号:US-2003010621-A1
优先权日:2001-06-26
标题:Novel synthesis of phthalocyanines by microwave irradiation

专利号:US-8206502-B2
优先权日:2008-12-15
标 题 :Titanyl phthalocyanine with improved milling properties
发明人：GRUENBAUM WILLIAM T
权利人:GRUENBAUM WILLIAM T; EASTMAN KODAK CO
摘要:The invention is directed to mixtures of PcTiO and a minor amount of another, substituted titanyl phthalocyanine and the synthesis of mixtures of PcTiO and a minor amount of another, substituted titanyl phthalocyanine. The invention is further directed towards milled pigment compositions of such mixtures, and to use of such milled pigment compositions in an electrophotographic element.

专利号:US-10249833-B2
优先权日:2016-03-02
标 题:Phthalocyanine compound and synthesis method and use thereof
发明人：GAO XUE; LIU FEI; ZHANG CAN
权利人:BOE TECHNOLOGY GROUP CO LTD
摘要:The invention relates to a phthalocyanine compound, which has a structure as represented by Formula I, wherein A represents a transition metal or a rare earth metal; R1 represents a phenyl group, a naphthyl group, or a C 4 -C 16 n-alkyl group. The aromatic phthalocyanine compound having the structure of Formula I provided in the invention contains a transition metal or a rare earth metal, and introduces a peripheral substituent into a linearly extended Ï€-conjugated system. It is relatively stabler at 400° C. or less and will be easily evaporated in vacuum to form a uniform thin film, and has good thermal stability, high chemical stability, and high mobility. The organic semiconductor device has the features of relatively fast on-off speed, relatively high on-off ratio, and strong reliability.

专利号:US-7947844-B2
优先权日:2007-08-01
标题:One-pot synthesis of benzisoindolenines used in the preparation of naphthalocyanines