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专利号:US-12421186-B2 优先权日:2022-11-29 标 题 :Organic ammonium salts with traceability and detergent dispersant properties to liquid fuels and processes for their synthesis 发明人:CAMACHO RICARDO CERÓN; ROA RAÚL OVIEDO; RAMÃ?REZ PÉREZ JORGE FRANCISCO; CASTRUITA ENRIQUE SOTO; DÉVORA RODOLFO CISNEROS; NIETO Ã?LVAREZ DAVID AARON; MARTINEZ MAGADAN JOSÉ MANUEL; SERVÃ?N NÃ?JERA Ana Graciela; ZAMUDIO RIVERA LUIS SILVESTRE 权利人:MEXICANO INST PETROL 摘要:The present invention is related to a process for obtaining organic ammonium salts (OAS) and their derivatives, supramolecular surfactants (SS), which simultaneously present the properties of traceability and detergents dispersant of organic scales. Organic ammonium salts (OAS) and their derivatives supramolecular surfactants (SS) have applications as differentiators, markers, or tracers in fuels derived from hydrocarbons; and also to disperse organic scales or inhibit the gums precipitation both in injectors and intake valves of automotive vehicle engines. Organic ammonium salts (OAS) are obtained through an acid-base reaction between a molecule from the azo family and an amine. Once the OAS is obtained, it reacts with an organic compound (OC) so that through non-covalent interactions, a self-assembly process occurs that gives rise to the SS. Said process is based on green chemistry, that is, in the absence of solvents. These OAS and SS are quantified through the analytical techniques of ultraviolet-visible (UV-VIS) and high-performance liquid chromatography (HPLC) through a calibration curve. Additionally, its performance as a gum-dispersing agent in a single-cylinder engine is evaluated.
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合成参考文献
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