CAS: 6373-93-9; Disperse Red 58

上下游产品

6-methoxybenzothiazol-2-ylamine 2,2'-(phenylimino)bis[ethanol]

📜2-氨基-6-甲氧基苯并噻唑,N,N-二羟乙基苯胺置于硫酸,Sodium Nitrite,Sodium Hydroxide体系中,用 溶剂黄146,丙酸,乙腈 作为反应溶剂,化学反应 3.0H,以86%的收率获得产物分散红58
参考文献:Some Heterocyclic Azo Dyes Derived From Thiazolyl Derivatives; Synthesis; Substituent Effects And Solvatochromic Studies
标题:Some Heterocyclic Azo Dyes Derived From Thiazolyl Derivatives; Synthesis; Substituent Effects And Solvatochromic Studies
摘要:A Series Of Azo Disperse Dyes Were Synthesized By Coupling Reaction Of N,N-Diethylaniline,2-Anilinoethanol And N-Phenyl-2,2'-Iminodiethanol With Diazotized Aminothiazolyl Derivatives As Diazo Components. These Dyes Have Been Prepared In Good Yields,And Were Characterized By Uv-Vis,Ft-Ir And (1)H NMR Spectroscopic Techniques. The Effects Of Solvent Polarity And Various Ph On Dyes In The Visible Absorption Spectra Were Evaluated. All Dyes Exhibit An Excellent Correlation Coefficient (R > 0.92) For The Linear Salvation Energy Relationship With Pi* Values Calculated By Kamlet Et Al. The Influence Of The Ph On The Dyes With Electron-Donating Group Implied That These Dyes Exist In Acid-Base Equilibrium In Acidic Environment. The Effect Of Substituents Of Both Coupler And Diazo Component On The Color Of Dyes Was Investigated As Well. (C) 2010 Elsevier B.V. All Rights Reserved.
DOI:10.1016/j.Saa.2010.08.079