CAS: 515-24-2; Turicin

该化合物其该化合物其内盐形成有助于其稳定性和离子特性,从而增强它的传导性.该化合物的手性性质使它得以参与不对称合成,使其在有机化学和制药领域具有价值.此外,它还可能展现出低挥发性和热稳定性等有趣的特性,这些特性有利于各种应用,包括催化和提取过程.

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物理性质

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    上下游产品

    4-hydroxyproline methyl iodide

    合成工艺路线路线简述

      📜顺式-4-羟基-D-脯氨酸置于水,Silver(L) Oxide体系中,化学反应生成 水苏碱
      参考文献:Studies On Hydroxyproline
      标题:Studies On Hydroxyproline
      摘要:
      DOI:10.1021/ja01558A050

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      专利信息


      专利号:WO-2007107319-A1
      优先权日:2006-03-17
      标题:Isolation, structure determination, synthesis and bioactivity of damipipecolin and damituricin
      发明人：AIELLO ANNA; GIORDANO ANTONELLA; FATTORUSSO ERNESTO; MENNA MARIALUISA; SCHROEDER HEINZ C; MUELLER WERNER E G
      权利人:BIOTECMARIN GMBH; AIELLO ANNA; GIORDANO ANTONELLA; FATTORUSSO ERNESTO; MENNA MARIALUISA; SCHROEDER HEINZ C; MUELLER WERNER E G
      摘要:Two new bromopyrrole alkaloids, compounds (1) and (2), have been isolated from the Mediterranean sponge Axinella damicÏ…rnis, and their structure established through spectroscopic methods. Compounds (1) and (2 )display a modulating effect of the serotonin receptor activity and neuroprotective activity in vitro.

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      合成参考文献


      参考文献:10.1128/mbio.00933-13
      摘要:Kumar R, Zhao S, Vetting MW, Wood BM, Sakai A, Cho K, Solbiati J, Almo SC, Sweedler JV, Jacobson MP, Gerlt JA, Cronan JE. Prediction and biochemical demonstration of a catabolic pathway for the osmoprotectant proline betaine. mBio. 2014 Feb 11;5(1):e00933–13.
      参考文献:10.1038/nature12576
      摘要:Zhao S, Kumar R, Sakai A, Vetting MW, Wood BM, Brown S, Bonanno JB, Hillerich BS, Seidel RD, Babbitt PC, Almo SC, Sweedler JV, Gerlt JA, Cronan JE, Jacobson MP. Discovery of new enzymes and metabolic pathways by using structure and genome context. Nature. 2013 Oct 31;502(7473):698–702.
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