CAS: 224-41-9; Benzo[m]Tetraphene

该化合物是一种多环芳烃(PAH),其特点是结构复杂,由四个引信的苯环组成,在室内温度下是固体,一般是暗色的晶体物质,众所周知,该化合物在水中具有高度稳定性和低溶解性,使其在有机溶剂中更易溶解.Dibenz[a,j]anthracene由于其潜在的致癌特性及其在化石燃料和燃烧产品中的存在,对环境化学特别感兴趣.它经常被研究其在形成烟尘中的作用及其对空气质量和人类健康的影响.此外,Dibenz[a,j]anthracene因其独特的电子特性,被用于与有机电子学和材料科学有关的研究.在处理该化合物时,安全防范是必要的,因为它被归类为一种可能的人类致癌物质.总的来说,Dibenz[a,j]anthracene在环境和材料化学两方面都是一个重要的研究对象.

结构式图片

上下游产品

1-Methylnaphthalene anthracene5,6,8,9-Tetrahydrodibenzoanthracene H-dibenz[a,j]anthracen-7-one14H-dibenz[a,j]anthracen-7-one (E,E)-1,3-distyrylbenzeneanthrachinoneDibenzoanthrachinone anthracene-5,6-dionedibenzanthracene-5,6-dione dibenz[a,j]anthracene-5,6-oxide 3-(2-Formylphenyl)-2-phenanthrenecarboxaldehyde

合成工艺路线路线简述

    📜N,N-二乙基-1-萘羧酰胺置于四甲基乙二胺,氢碘酸,仲丁基锂,亚膦酸,三苯基氯甲烷体系中,用 溶剂黄146 用作溶剂,化学反应 245.0H,反应生成二苯并[a,J]蒽
    参考文献:Synthesis Of Polycyclic Aromatic Hydrocarbons Via A Novel Annelation Method
    标题:Synthesis Of Polycyclic Aromatic Hydrocarbons Via A Novel Annelation Method
    摘要:
    Doi:10.1021/jo00132A026

    海关参考信息

    专利信息


    专利号:US-2003162992-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
    发明人:WATANABE KYOICHI A; DU JINFA
    摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

    专利号:US-3965049-A
    优先权日:1972-10-24
    标 题 :One-step synthesis of aromatic organic diselenides
    发明人:GRUSHKIN BERNARD; SALZMAN MICHAEL N
    权利人:XEROX CORP
    摘要:Disclosed is a novel method for the preparation of aromatic organic diselenide compounds. The method involves reacting an alkali metal diselenide with certain halogenated aromatic compounds in dimethylformamide to form the corresponding aromatic diselenide. The use of dimethylformamide enables one to prepare certain aromatic diselenide compounds containing two replaceable halogen atoms in a one-step process.

    专利号:CA-2470202-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides

    专利号:US-9181504-B2
    优先权日:2009-09-25
    标题 :Method and device for removing tars from synthesis gas obtained during gasification of biomass
    发明人:ZWART ROBIN; BOS ALEXANDER; KUIPERS JOHANNES
    权利人:ZWART ROBIN; BOS ALEXANDER; KUIPERS JOHANNES; STICHTING ENERGIE
    摘要:Method and system for gasifying biomass. Tar loaded gas from the reactor for gasifying the biomass is subjected to a saturation and absorption treatment with a first and second fluid respectively. The first fluid comprises aromatic hydrocarbons whilst the second fluid comprises linear hydrocarbons. Tars received in the aromatic fluid is entered together with such fluid in a separation column. Separation is effected based on evaporation temperature and the lighter fraction is returned to the inflow of the saturation separator. The heavier fractions are either discharged or sent back to the biomass reactor. An intermediate buffer vessel can be provided between the discharge of the saturation cleaner and the separator.

    专利号:WO-03051298-A2
    优先权日:2001-12-14
    标 题:Preparation of intermediates useful in the synthesis of antiviral nucleosides

    专利号:EP-1461041-A4
    优先权日:2001-12-14
    标 题:PREPARATION OF INTERMEDIATES SUITABLE FOR THE SYNTHESIS OF ANTIVIRAL NUCLEOSIDES

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Cycloaromatization Of α-Oxoketene Dithioacetals And β-Oxodithioacetals With Benzyl-,1-(Naphthylmethyl) And 2-(Naphthylmethyl)Magnesium Halides: Synthesis Of Condensed Polynuclear Aromatic Hydrocarbons
    作者:Ch.Srinivasa Rao,Maliakel P Balu,Hiriyakkanavar Ila,Hiriyakkanavar Junjappa |发布日期:1991.1
    摘要:An Efficient Route For The Synthesis Of Substituted Naphthalenes, Phenanthrenes And Other Polynuclear Aromatic Hydrocarbons Has Been Developed. The Methodology Involves 1,2- (Or Sequential 1,4- And 1,2-) Addition Of Either Benzyl, 1-(Naphthylmethyl) Or 2-(Naphthylmethyl) Magnesium Halides To α-Oxoketene Dithioacetals Or β-Oxodithioacetals Followed By Borontrifluoride Etherate Catalyzed Cycloaromatization

    合成参考文献


    摘要:Stará, I. G.; Starý, I., Science of Synthesis, (2010) 45, 946.
    参考文献:10.1016/s1383-5718(01)00240-6
    摘要:Machala M, Vondráček J, Bláha L, Ciganek M, Neča J. Aryl hydrocarbon receptor-mediated activity of mutagenic polycyclic aromatic hydrocarbons determined using in vitro reporter gene assay. Mutation Research/Genetic Toxicology and Environmental Mutagenesis. 2001 Oct;497(1-2):49–62. doi: 10.1016/s1383-5718(01)00240-6.
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