CAS: 17887-41-1; Tert-Butyldichloro(Phenyl)Silane
该化合物是一种有机硅化合物,主要用作有机合成和表面变异的多功能中间体,其二氯硅烷功能可产生高效的混合反应,使其对将三丁基苯基硅烷组引入目标分子具有价值.三丁基替代成分会增加消毒障碍,改善反应环境中的稳定性.该化合物在生产硅联动剂,防护涂层和功能化材料方面特别有用.它与氢氧基体组的再活动可以使硅基子体有效地表功能化.需要谨慎处理,因为其湿度敏感,需要在惰性条件下储存.该化合物的平衡反应性和稳定性使得它适合于材料科学和精细化学合成的专门应用.
- 英文名称Tert-Butyldichloro(Phenyl)Silane
- 中文名称t-丁基苯基二氯硅烷
- IUPAC名称tert-butyl-dichloro-phenylsilane
- 其它别名Silane,dichloro(1,1-dimethylethyl)phenyl- (9CI); Silane, tert-butyldichlorophenyl-(8CI); tert-Butyldichlorophenylsilane; tert-Butylphenyldichlorosilane
- CAS编号17887-41-1
- MFCD编号:MFCD00051441
- EINECS号:241-835-2
- 分子式:C10H14Cl2Si分子量:233.21
- 产品CID: 920002
- 产品分类化学试剂 → 硅烷试剂
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
tert.-butyl lithium Phenyltrichlorosilane(t-bu)phSi(OH)2 2)2(t-bu)phSi(NH2)2 1,2,3,4-tetra-t-butyl-1,2,3,4-tetraphenylcyclotetrasilane 1-((4aR,6R,7aS)-2-tert-Butyl-2-phenyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-5-methyl-1H-pyrimidine-2,4-dione合成工艺路线路线简述
📜苯基三氯硅烷置于t-C4H9Li体系中,用 Not Given 用作溶剂,以80%的收率获得t-丁基苯基二氯硅烷
参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Si: Mvol.C,58,Page 165-167
标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Si: Mvol.C,58,Page 165-167
海关参考信息
- 2902200000-苯
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-5589586-A
优先权日:1990-11-26
标 题 :Nucleosides attached to a solid support through a 3'-silyl linkage and their use in oligonucleotide synthesis
发明人：HOLMBERG LARS
权利人:PHARMACIA LKB BIOTECH
摘要:Support system for the synthesis of oligonucleotides wherein the first nucleoside is bound to the support via a silylether linkage, especially of the formula ##STR1## wherein B is a nucleoside or deoxynucleoside base. n R 1 is a protecting group. n R 2 is --H, --OH, or --OR 5 , in which R 5 is a protecting group. n R 3 , R 4 and X each represent alkyl, aryl, cycloalkyl, alkenyl, aralkyl, cycloalkylalkyl, alkyloxy, aryloxy, cycloalkyloxy, alkenyloxy, aralkyloxy. n S is a solid support, whereby not more than one of R 3 , R 4 and X represent alkyloxy, aryloxy, cycloalkyloxy, alkenyloxy, aralkyloxy or cycloalkylalkyloxy.
专利号:US-9416147-B2
优先权日:2014-04-03
标题 :Preparation of silazane compound
发明人：TONOMURA YOICHI; KUBOTA TOHRU
权利人:SHINETSU CHEMICAL CO
摘要:A silazane compound useful as synthesis intermediates for paint additives, polymer modifiers, pharmaceuticals and agricultural chemicals is efficiently prepared by reaction of a halosilane compound with an amino-containing compound in a solvent which is the same silazane compound as the target product.
专利号:EP-0514513-A1
优先权日:1990-11-26
标题 :METHOD AND MEANS FOR SYNTHESIS OF OLIGONUCLEOTIDES.
专利号:DE-69116864-T2
优先权日:1990-11-26
标 题 :METHOD AND MEANS FOR THE SYNTHESIS OF OLIGONUCLEOTIDES
专利号:JP-H05503715-A
优先权日:1990-11-26
标题:Methods and means of oligonucleotide synthesis
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Palladium‐catalyzed Synthesis Of Benzophenanthrosilines By C−h/c−h Coupling Through 1,4‐palladium Migration/alkene Stereoisomerization作者:Tomohiro Tsuda,Yuka Kawakami,Seung‐min Choi,Ryo Shintani |发布日期:2020.5.18
摘要:Catalysis. The Reaction Mechanism Has Been Experimentally Investigated And A Catalytic Cycle Involving A C-H/c-H Coupling Through A New Mode Of 1,4-Palladium Migration With Concomitant Alkene Stereoisomerization Has Been Proposed.
📝 需求与反馈
尽可能描述清楚需求与问题信息
