CAS: 138-55-6; (R)-2,6,6-Trimethyl-4-(((2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Cyclohex-1-Ene-1-Carbaldehyde
该化合物是天然的化合物,主要见于红花,Crocus sativius的干污,是一种甘蓝的化合物,具体地说,是单极甘蓝的甘蓝,是香红花苦味的原因.Picrocrocrocin是一种无色的晶体物质,溶于水和酒精,可溶于各种烹饪菜的口味.其化学结构包括一种与对生物活动至关重要的树脂相连的葡萄糖.Picrocrocrocyn也是麻黄花的前体,是负责番红花特征的芳香色的化合物.除了其烹饪用途外,还研究过它潜在的健康利益,包括抗氧化剂和抗氟化物特性.然而,它在番花中的浓度可能有很大差异,受到种植条件和加工方法等因素的影响.
- 英文名称(R)-2,6,6-Trimethyl-4-(((2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Cyclohex-1-Ene-1-Carbaldehyde
- 中文名称苦番紅花素
- IUPAC名称(R)-2,6,6-trimethyl-4-(((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)cyclohex-1-ene-1-carbaldehyde
- 其它别名Picrocrocin; (R)-4-(β-D-Glucopyranosiloxy)-2,6,6-Trimethyl-1-Cyclohexene-1-Carbaldehyde; (R)-4-(β-D-Glucopyranosyloxy)-2,6,6-Trimethyl-1-Cyclohexene-1-Carbaldehyde; Saffron-Bitter; Picrocrocine; 1-Cyclohexene-1-Carboxaldehyde,4-(B-D-Glucopyranosyloxy)-2,6,6-Trimethyl-,(4R)-; Safranbitter; (4S)-2,6,6-Trimethyl-4-[(2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Oxan-2-Yl]Oxy-Cyclohexene-1-Carbaldehyde
- CAS编号138-55-6
- MFCD编号:MFCD09752814
- EINECS号:112-623-6
- FDA UNII编号:ON5B022511
- 分子式:C16H26O7分子量:330.38
- 产品CID: 598230
- 产品分类生物化工 → 中草药成分
物理性质
- 熔点196 °C (ethyl acetate )
- 沸点520.4 °C at 760mmHg
- 闪点187.1 °C
- 密度1.31g/cm3
- pKa:12.91±0.70(预测)
- PSA:116.45
- LogP:-0.240 (est)
- 折射率1.561
- 蒸汽压5.27E-13mmHg at 25°C
- 外观形态白色晶体或粉末
- 储存条件2-8°C，密封保存，避光，干燥环境
- 产品应用该化合物是松鼠的单体甘蓝原前体. 皮克鲁氯素在香料红花中找到, 香料花是来自花的; 皮科克罗青素是焦质素的降解产物. 青素显示对SKMEL-2人类恶性黑素细胞的生长抑制效应, 其目标针对JAK/STAT5信号路径, 细胞循环阻塞和米托氏体介质的流行性.
MSDS等安全信息
欧盟法规
C&L通报上下游产品
CAS号76686-29-8 (4R)-4-(β-D-Glu... | CAS号76686-28-7 (4R)-4-(β-D-Glu... | CAS号76686-26-5 (R)-(4-((2-meth...合成工艺路线路线简述
📜(3R)-3-Hydroxy-β-Cyclogeranylacetat置于calcium Sulfate,Sodium Acetate,Sodium,Pyridinium Chlorochromate,Silver(L) Oxide体系中,用 甲醇,二甲基亚砜,苯 用作溶剂,化学反应 52.0H,反应生成苦番紅花素
参考文献:合成胡萝卜素,天然胡萝卜素和天然维生素.六.合成吡柔比星†
标题:合成胡萝卜素,天然胡萝卜素和天然维生素.六.合成吡柔比星†
摘要:光学活性天然类胡萝卜素和结构相关化合物的合成.六.青霉素的合成
Doi:10.1002/hlca.19800630616
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905310000-1,2-乙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:WO-2024015528-A1
优先权日:2022-07-15
标题 :Efficient procedure for the synthesis of hydrazone-linked tetrahedral nanocages
发明人：SCHNEEBELI SEVERIN; VESTRHEIM OLAV
权利人:UNIV VERMONT
摘要:The present application is directed to a nanocage of Formula (I): wherein A and R are as described herein. The present application is also directed to an efficient process for preparation of a nanocage of Formula (I), which allows for efficient scale-up of the nanocage synthesis. Furthermore, this new process allows for rapid nanocage diversification, due a newly introduced late-stage functionalization method.
专利号:CN-102618484-A
优先权日:2012-03-28
标题 :A method for improving the synthesis of saffron pigment by saffron cells
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Mir JA, Yadav AK, Singh D, Ashraf N. A novel mutation in non-constitutive lycopene beta cyclase (CstLcyB2a) from Crocus sativus modulates carotenoid/apocarotenoid content, biomass and stress tolerance in plants. Planta. 2024 Aug 27;260(4):80. doi: 10.1007/s00425-024-04515-x. 29(13):3080. doi: 10.3390/molecules29133080.
3: Mir RA, Tyagi A, Hussain SJ, Almalki MA, Zeyad MT, Deshmukh R, Ali S. Saffron, a Potential Bridge between Nutrition and Disease Therapeutics: Global Health Challenges and Therapeutic Opportunities. Plants (Basel). 2024 May 25;13(11):1467. doi: 10.3390/plants13111467.
4: Hasheminasab FS, Azimi M, Raeiszadeh M. Therapeutic effects of saffron (Crocus sativus L) on female reproductive system disorders: A systematic review. Phytother Res. 2024 Jun;38(6):2832-2846. doi: 10.1002/ptr.8186. Epub 2024 Apr 1. 38(5):2482-2495. doi: 10.1002/ptr.8169. Epub 2024 Mar 6. 27(3):123. doi: 10.3892/etm.2024.12411.
合成参考文献
参考文献:10.1016/j.foodchem.2020.127786
摘要:Moratalla-López N, Parizad S, Habibi MK, Winter S, Kalantari S, Bera S, Lorenzo C, García-Rodríguez MV, Dizadji A, Alonso GL. Impact of two different dehydration methods on saffron quality, concerning the prevalence of Saffron latent virus (SaLV) in Iran. Food Chem. 2021 Feb 01;337():127786. doi: 10.1016/j.foodchem.2020.127786.
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