CAS: 634-74-2; (2S,3S,4R,5R)-2,3,4,5-Tetrahydroxyhexanal

该化合物是一种天然的糖和单沙律,被归类为脱氧糖,特别是甲基刺青.它是一种阿尔多索脱氧糖,意谓它含有甲状腺,有六种碳原子.D-Rhamnose通常存在于各种植物中,特别是花草和其他二级代谢物的胶质上.它的特征是白色晶状表面,在水中可溶,表现出甜味.D-Rhamnose的分子式是C6H12O5, 其具体旋转值约为+20度.这种糖在植物代谢中起着重要作用,并且也用于食品和制药工业,以获得潜在的健康利益,包括其前生特性.此外,D-Rhamnose还参与某些聚沙酸盐和甘油的合成,有助于植物的细胞壁结构.它的独特结构和特性使它成为各种生物化学和工业应用的兴趣对象.

结构式图片

相似化合物

10030-85-0 3615-41-6 2438-80-4

上下游产品

CAS号3615-37-0 D-(+)岩藻糖 | CAS号2438-80-4 L-岩藻糖 | CAS号620-02-0 5-甲基-2-糠醛

合成工艺路线路线简述

    📜Methyl-(Tri-O-Benzoyl-6-Deoxy-α-D-Altropyranoside)置于甲醇,Sodium Methylate体系中,化学反应生成 6-脱氧阿卓糖
    参考文献:L-Fuco-4-Ketose,A New Sugar Produced By The Action Of Acetobacter Suboxydans On L-Fucitol1
    标题:L-Fuco-4-Ketose,A New Sugar Produced By The Action Of Acetobacter Suboxydans On L-Fucitol1
    摘要:
    DOI:10.1021/ja01167A025

    海关参考信息

    专利信息


    专利号:US-12188072-B2
    优先权日:2018-03-19
    标题 :Compositions and methods for rapid in vitro synthesis of bioconjugate vaccines in vitro via production and N-glycosylation of protein carriers in detoxified prokaryotic cell lysates
    发明人:JEWETT MICHAEL CHRISTOPHER; STARK JESSICA CAROL; DELISA MATTHEW P; JAROENTOMEECHAI THAPAKORN
    权利人:UNIV NORTHWESTERN; UNIV CORNELL
    摘要:Disclosed are methods, systems, components, and compositions for cell-free synthesis of glycosylated carrier proteins. The glycosylated carrier proteins may be utilized in vaccines, including anti-bacterial vaccines. The glycosylated carrier proteins may include a bacterial polysaccharide conjugated to a carrier, which may be utilized to generate an immune response in an immunized host against the polysaccharide conjugated to the carrier. The glycosylated carrier proteins may be synthesized in cell-free glycoprotein synthesis (CFGpS) systems using prokaryote cell lysates that are enriched in components for glycoprotein synthesis such as oligosaccharyltransferases (OSTs) and lipid-linked oligosaccharides (LLOs) including OSTs and LLOs associated with synthesis of bacterial O antigens.

    专利号:US-2022395800-A1
    优先权日:2019-11-04
    标题:Device for automated synthesis of oligo- and polysaccharides
    发明人:SEEBERGER PETER H; DANGLAD FLORES JOSE; LE MAI HOANG KIM; PARDO VARGAS ALONSO; SLETTEN ERIC; SALWICZEK MARIO
    权利人:MAX PLANCK GESELLSCHAT ZU RFERDERUNG DER WSS E V; GlycoUniverse GmbH & Co KG&A
    摘要:The present invention generally relates to automated synthesis technology, and more particularly, to a device and method for automated synthesis of oligo- and polysaccharides on a solid support. In particular the present invention relates to a device for automated synthesis of oligo- and polysaccharides on a solid support comprising a reaction vessel, a reagent storing component, a reagent delivery system, a cooling device for cooling reaction vessel, and a pre-cooling device for pre-cooling the reagents to be supplied.

    专利号:US-7435816-B2
    优先权日:2003-04-30
    标 题 :Synthesis of solanum glycosides
    发明人:SHAHID MOHAMMED
    权利人:SHAHID MOHAMMED
    摘要:The present invention relates to the chemical synthesis of solanum glycosides, in particular to the synthesis of solasonine as well as to novel β-monosaccharide intermediate compounds, of Formula (2), where R 1 is a benzylidene, 4-nitrobenzylidene or 4-methoxybenzylidine group, and each R 2 independently is a benzoyl, acetyl or pivaloyl group:

    专利号:EP-1421100-B1
    优先权日:2001-08-21
    标 题 :Chemical synthesis of solamargine
    发明人:SHAHID MOHAMMED
    权利人:GLYCOMED SCIENCES LTD
    摘要:The present invention relates to the chemical synthesis of solanum glycosides, in particular to the synthesis of solamargine as well as to novel beta-monosaccharide Intermediate compounds.

    专利号:WO-2018002957-A8
    优先权日:2016-06-29
    标 题 :A method for synthesis of 6-deoxy-l-hexoses from l-rhamnose
    发明人:KULKARNI SUVARN SUBHASH; SANAPALA SOMESWARA RAO
    权利人:INDIAN INST TECHNOLOGY BOMBAY
    摘要:The present invention relates to a process for synthesis of 6-Deoxy-L-Hexoses from L-Rhamnose comprising the steps of optional regioselective protection of C2-, C3- and/or C4-OH of the L- Rhamnose of formula (1) to obtain compounds of formulae (2) and subjecting said compounds of formulae 2 to triflation followed by nitrite anion or water mediated inversion to obtain 6-deoxy- L-Hexoses of formulae (3).

    专利号:US-5945529-A
    优先权日:1996-07-19
    标题:Synthesis of polyol fatty acid polyesters using column with inert gas stripping
    发明人:CORRIGAN PATRICK JOSEPH; KENNEALLY COREY JAMES; GRANBERG ERIC PAUL
    权利人:PROCTER & GAMBLE
    摘要:Processes for the synthesis of polyol fatty acid polyester by transesterification of a polyol comprise reacting polyol with a first portion of fatty acid lower alkyl ester to provide a first step reaction product in which substantially all of the polyol is reacted with at least one fatty acid lower alkyl ester. The processes then employ a multistage column providing substantial plug flow of liquid therein for further transesterification of the first step reaction product. Partially esterified polyol, a second portion of fatty acid lower alkyl ester and catalyst are fed to the column to form a mixture and cause further transesterification of the partially esterified polyol and fatty acid lower alkyl ester, with lower alkyl alcohol being formed as a by product. The resulting liquid mixture of reactants and product is passed in a first direction between adjacent stages through the column for further reaction of partially esterified polyol with fatty acid lower alkyl ester. An inert stripping or sparging gas is fed through the column in a second direction between adjacent stages, counter current to the flow of the liquid mixture between adjacent stages in the first direction, with radial shear agitation. The lower alkyl alcohol by-product of the polyol-fatty acid lower alkyl ester reaction is transferred from the liquid mixture to the inert gas.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s10482-011-9588-8
    摘要:Miao Q, Qin S, Bian GK, Yuan B, Xing K, Zhang YJ, Li Q, Tang SK, Li WJ, Jiang JH. Amycolatopsis endophytica sp. nov., a novel endophytic actinomycete isolated from oil-seed plant Jatropha curcas L. Antonie Van Leeuwenhoek. 2011 Oct;100(3):333–9. doi: 10.1007/s10482-011-9588-8.
    参考文献:10.1186/s12866-017-0943-4
    摘要:Hong TP, Carter MQ, Struffi P, Casonato S, Hao Y, Lam JS, Lory S, Jousson O. Conjugative type IVb pilus recognizes lipopolysaccharide of recipient cells to initiate PAPI-1 pathogenicity island transfer in Pseudomonas aeruginosa. BMC Microbiology. 2017 Feb 07;17(1):31. doi: 10.1186/s12866-017-0943-4.
    参考文献:10.1007/bf01240135
    摘要:Zhu H, Zollner TM, Klein-Franke A, Anderer FA. Enhancement of MHC-unrestricted cytotoxic activity of human CD56+ CD3− natural killer (NK) cells and CD3+ T cells by rhamnogalacturonan: Target cell specificity and activity against NK-insensitive targets. Journal of Cancer Research and Clinical Oncology. 1994 Jul;120(7):383–8. doi: 10.1007/bf01240135.
    参考文献:10.1007/bf02538423
    摘要:KREGER-VAN RIJ NJ. Taxonomy of Cryptococcus neoformans and its variety uniguttulatus. Antonie Van Leeuwenhoek. 1961;27():59–64. doi: 10.1007/bf02538423.
    参考文献:10.1023/b:glyc.0000038290.74944.65
    摘要:Novotny R, Pfoestl A, Messner P, Schäffer C. Genetic organization of chromosomal S-layer glycan biosynthesis loci of Bacillaceae. Glycoconj J. 2004;20(7-8):435–47. doi: 10.1023/b:glyc.0000038290.74944.65.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知