CAS: 2478-35-5; Cellohexaose

该化合物是一种聚沙律,主要由乙醇-(14)甘蓝结壳相连的葡萄糖单位组成,这一结构表明这是一种乙醇/甘蓝,是一种可溶性纤维.乙酸甘蓝因其健康利益而闻名,包括潜在的胆固醇低效效应和免疫系统支持.重复的乙醇 -- D-甘蓝酸盐单位有助于其溶解性和水溶性.这种化合物通常存在于各种天然来源,包括燕麦和大麦,并因其功能特性而用于食品和药物应用.其分子重量和具体物理特性可因聚合程度和来源而异.总体而言,乙-D-甘露色酸基-(1- >-4)-D甘蓝糖因其营养和治疗潜力而得到承认.

结构式图片

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CAS号528-50-7 D(+)-纤维二糖

合成工艺路线路线简述

    📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于甲醇,Sodium Methylate体系中,化学反应生成纤维六糖
    参考文献:The Polymer-Homologous Series Of Oligosaccharides From Cellulose1
    标题:The Polymer-Homologous Series Of Oligosaccharides From Cellulose1
    摘要:
    Doi:10.1021/ja01141A032

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    主要参考文献

    参考标题:Enzymatic Synthesis Of Cellulose Ii-Like Substance Via Cellulolytic Enzyme-Mediated Transglycosylation In An Aqueous Medium
    作者:Takeshi Hattori,Makoto Ogata,Yumiko Kameshima,Kazuhide Totani,Mitsuru Nikaido,Takashi Nakamura,Hiroyuki Koshino,Taichi Usui |发布日期:2012.5
    摘要:The Enzymatic Synthesis Of Cellulose-Like Substance Via A Non-Biosynthetic Pathway Has Been Achieved By Transglycosylation In An Aqueous System Of The Corresponding Substrate, Cellotriose For Cellulolytic Enzyme Endo-Acting Endoglucanase I (Eg I) From Hypocrea Jecorina. A Significant Amount Of Water-Insoluble Product Precipitated Out From The Reaction System. Maldi-Tof Mass Analysis Showed That The Resulting Precipitate Had A Degree Of Polymerization (Dp) Of Up To 16 From Cellotriose. Solid-State C-13 Nmr Spectrum Of The Resulting Water-Insoluble Product Revealed That All Carbon Resonance Lines Were Assigned To Two Kinds Of Anhydroglucose Residues In The Corresponding Structure Of Cellulose Ii. X-Ray Diffraction (Xrd) Measurement As Well As C-13 Nmr Analysis Showed That The Crystal Structure Corresponds To Cellulose Ii With A High Degree Of Crystallinity. We Propose The Multiple Oligomers Form Highly Crystalline Cellulose Ii As A Result Of Self-Assembly Via Oligomer-Oligomer Interaction When They Precipitate. Crown Copyright (C) 2012 Published By Elsevier Ltd. All Rights Reserved.

    合成参考文献


    参考文献:10.1016/j.bmc.2011.04.048
    摘要:Noguchi S, Takemoto S, Kidokoro S, Yamamoto K, Hashimoto M. Syntheses of cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases. Bioorg Med Chem. 2011 Jun 15;19(12):3812–30. doi: 10.1016/j.bmc.2011.04.048.
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