CAS: 125306-83-4; Cafenstrole

该化合物是一种化学化合物,被归类为选择性除草剂,主要用于农业用途,以控制各种大叶杂草和草,属于被称为苯丙胺的化合物类别;食氯素通过抑制某些植物荷尔蒙生物合成中涉及的特定酶而运作,从而干扰目标植物的生长和发展;该化合物的特点是它对非目标生物的毒性相对较低,使其在综合虫害管理战略中成为首选选择;其行动方式主要是抑制植物中的光合作用和其他代谢过程;食氯素通常用于前期和发芽后配方,允许在杂草管理做法中具有灵活性;此外,它具有中度的环境持久性,需要认真考虑施用时间和方法,以尽量减少对周围生态系统的潜在影响;与任何除草剂一样,遵守安全准则和条例对于确保有效和负责任地使用至关重要.

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合成工艺路线路线简述

    N,N-Diethyl-3-(2,4,6-Trimethylphenyl)Sulfanyl-1,2,4-Triazole-1-Carboxamide 反应生成N,N-二乙基-3-均三甲基苯磺酰基-1H-1,2,4-三唑-1-甲酰胺
    参考文献:Pharmaceutical Use Of N-Carbamoylazole Derivatives
    标题:Pharmaceutical Use Of N-Carbamoylazole Derivatives

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:BR-102013018473-B1
    优先权日:2012-07-24
    标题 :HERBICIDAL COMPOSITIONS COMPENDIENT 4-AMINO-3-CHLORO-5-FLUORO-6- (4-CHLORO-2-FLUORO-3-ETOXYPHENYL) PYRIDINE-2-CARBOXYLIC ACID OR A DERIVATIVE OF THE SAME AND HERBICIDES INHIBITING THE SYNTHESIS OF VLCFA AND SYNTHESIS OF GRAIN ACID / LIPID, AND METHOD FOR UNDESIRABLE VEGETATION CONTROL
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    主要参考文献


    1: Kang G, Kim J, Park H, Kim TH. Crystal structure of cafenstrole. Acta Crystallogr E Crystallogr Commun. 2015 Jul 29;71(Pt 8):o614. doi: 10.1107/S2056989015013869.
    2: Abd El-Aty AM, Lee GW, Mamun MI, Choi JH, Cho SK, Shin HC, Shim JH. Development and validation of a method for the analysis of cafenstrole and its metabolite in brown rice grains and rice straw using high-performance liquid chromatography. Biomed Chromatogr. 2008 Mar;22(3):306-15. doi: 10.1002/bmc.934. 82(10):1770-1779. doi: 10.1080/09168451.2018.1484278. Epub 2018 Jun 18. 56(9-10):781-6. doi: 10.1515/znc-2001-9-1016. 72(Pt 11):1610-1613. doi: 10.1107/S2056989016016662.
    6: Jung SC, Kim HG, Kuk YI, Ahn HG, Senseman SA, Lee DJ. Bioavailability of the Nano-Unit 14C-Agrochemicals Under Various Water Potential. J Nanosci Nanotechnol. 2015 Aug;15(8):6206-9. doi: 10.1166/jnn.2015.10447. 66(7):794-800. doi: 10.1002/ps.1944. 54(20):7724-8. doi: 10.1021/jf0609328. 15(1):676-9. doi: 10.1166/jnn.2015.8370. 82(6):716-21. doi: 10.1007/s00128-009-9681-0. Epub 2009 Mar 10. 64(6):1045-54. doi: 10.1016/s0031-9422(03)00516-8. 11(4):e1001531. doi: 10.1371/journal.pbio.1001531. Epub 2013 Apr 9.

    合成参考文献


    摘要:S120 | DUSTCT2024 | Substances from Second NORMAN Collaborative Dust Trial | DOI:10.5281/zenodo.13835254
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