CAS: 791-31-1; Triphenylsilanol

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CAS号18858-69-0 benzyloxytriphe... | CAS号789-25-3 三苯基硅烷 | CAS号16527-35-8 Silanol,1,1,1-t... | CAS号1450-23-3 六苯基二硅烷 | CAS号76-86-8 三苯基氯硅烷 | CAS号6990-64-3 bromo(triphenyl... | CAS号591-51-5 苯基锂 | CAS号15487-82-8 potassium,triph... | CAS号4131-46-8 triphenyl(2-phe... | CAS号1450-18-6 1,1,1-三甲基-2,2,2... | CAS号4215-80-9 三苯甲硅烷基 | CAS号379-50-0 三苯甲基氟硅烷 | CAS号1829-41-0 甲氧基三苯基硅烷 | CAS号17964-41-9 butyl-hydroxy-d... | CAS号18754-87-5 triethyl(triphe... | CAS号1896-62-4 反式苯亚甲基丙酮 | CAS号1829-40-9 六苯基二硅氧烷 | CAS号813-19-4 六丁基锡 | CAS号778-25-6 羟基甲基二苯基硅烷 | CAS号1066-40-6 三甲基硅醇

三苯基硅烷置于[fe(C6H5N2O)(Co)(Mecn)3][pf6],水体系中,用 四氢呋喃 作为反应溶剂,化学反应 0.67H,以46%的收率获得产物三苯基硅醇
参考文献:A Novel Iron Complex For Highly Efficient Catalytic Hydrogen Generation From The Hydrolysis Of Organosilanes
标题:A Novel Iron Complex For Highly Efficient Catalytic Hydrogen Generation From The Hydrolysis Of Organosilanes
摘要:硅烷的水解氧化反应,在铁基催化剂的作用下反应生成氢气和硅醇.
DOI:10.1039/c4Cc02852J

专利信息

专利号:US-8492390-B2
优先权日:2002-05-08
标题 :Synthesis of locked nucleic acid derivatives
发明人：DETLEF SORENSEN MADS; WENGEL JESPER; KOCH TROELS; CHRISTENSEN SIGNE M; ROSENBOHM CHRISTOPH; PEDERSEN DANIEL SEJER
权利人:DETLEF SORENSEN MADS; WENGEL JESPER; KOCH TROELS; CHRISTENSEN SIGNE M; ROSENBOHM CHRISTOPH; PEDERSEN DANIEL SEJER; SANTARIS PHARMA AS
摘要:The invention relates to a novel strategy for the synthesis of Locked Nucleic Acid derivatives, such as α- L -oxy-LNA, amino-LNA, α- L -amino-LNA, thio-LNA, α- L -thio-LNA, seleno-LNA and methylene LNA, which provides scalable high yielding reactions utilising intermediates that also can produce other LNA analogues such as oxy-LNA. Also, the compounds of the formula X are important intermediates that may be reacted with varieties of nucleophiles leading to a wide variety of LNA analogues.

专利号:US-4514569-A
优先权日:1982-01-28
标 题 :Synthesis of 1-substituted isoquinolines
发明人：HENDRICKSON JAMES B; RODRIGUEZ CESAR
权利人:HENDRICKSON JAMES B; RODRIGUEZ CESAR
摘要:A method for the synthesis of particular isoquinoline compounds which are useful intermediates in the preparation of members of the family of opium alkaloids, such as morphine and codeine. Steps in the process include the acylation of the isoquinoline nitrogen; reaction of the acylated isoquinoline with a phosphorous compound; and condensation with a benzaldehyde derivative to yield a 1-benzyl isoquinoline.

专利号:EP-1501848-B1
优先权日:2002-05-08
标 题 :Synthesis of locked nucleic acid derivatives
发明人：SORENSEN MADS DETLEF; WENGEL JESPER; KOCH TROELS; CHRISTENSEN SIGNE M; ROSENBOHM CHRISTOPH; PEDERSEN DANIEL SEJER
权利人:SANTARIS PHARMA AS
摘要:The invention relates to a novel strategy for the synthesis of Locked Nucleic Acid derivatives, such as alpha-L-oxy-LNA, amino-LNA, alpha-L-amino-LNA, thio-LNA, alpha-L-thio-LNA, seleno-LNA and methylene LNA, which provides scalable high yielding reactions utilising intermediates that also can produce other LNA analogues such as oxy-LNA. Also, the compounds of the formula X are important intermediates that may be reacted with varieties of nucleophiles leading to a wide variety of LNA analogues. (Formula I)

专利号:US-5502126-A
优先权日:1993-06-17
标 题 :Process for the synthesis of isoprene butadiene rubber
发明人：BELL ANTHONY J; MATRANA BARRY A; HALASA ADEL F
权利人:GOODYEAR TIRE & RUBBER
摘要:The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component; (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component; and (3) adding a compound which contains at least one labile halogen atom to the Group III-B metal containing catalyst component.

专利号:US-4616097-A
优先权日:1984-10-22
标 题:Process for low pressure synthesis of ethylene glycol from synthesis gas plus formaldehyde
发明人：KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon-containing promoter at a temperature of at least 50 DEG C. and a pressure of at least 500 psi.

专利号:US-4565896-A
优先权日:1984-10-22
标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
发明人：KNIFTON JOHN F; DURANLEAU ROGER G
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.