CAS: 89343-06-6; Ethynyltriisopropylsilane

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CAS号13154-24-0 三异丙基氯硅烷 | CAS号74-86-2 乙炔 | CAS号74-96-4 溴乙烷 | CAS号111409-79-1 (溴乙炔基)三异丙基硅烷 | CAS号373596-08-8 6,13-双(三异丙硅基乙炔基)并五苯 | CAS号142761-84-0 1,5-bis[tri(pro... | CAS号183852-53-1 (2R)-4-tri(prop... | CAS号199275-03-1 1,6-bis[tri(pro... | CAS号189619-30-5 1,2-bis[4-[2-tr... | CAS号248276-94-0 N,N-dibutyl-4-i... | CAS号261713-83-1 2-(2-bromopheny... | CAS号82192-57-2 1-(三异丙基硅基)-1-丙炔

Propargyl Alcohol置于[rh(Oh)(Cod)]2,Sodium Methylate,R-(+)-1,1'-联萘-2,2'-双二苯膦体系中,用 甲苯 作为反应溶剂,化学反应 1.0H,以30%的收率获得产物三异丙基硅基乙炔
参考文献:铑(i)催化的顺序c(sp)c(sp3)和c(sp3)通过迁移碳插入形成c(sp3)键
标题:铑(i)催化的顺序c(sp)c(sp3)和c(sp3)通过迁移碳插入形成c(sp3)键
摘要:已开发出一种rh I催化的叔炔丙醇,重氮酸酯和烷基卤的三组分反应.该反应可视为涉及卡宾的顺序烷基和炔基偶合,其中c(sp)c(sp 3)和c(sp 3)c(sp 3)键是在羧基碳原子上连续建立的.提出了rh I-卡宾迁移插入炔基部分和随后进行烷基化的方法,以解释两个独立的cc键形成.该反应为全碳四元中心的构建提供了一种有效且可调节的方法.
DOI:10.1002/anie.201503140

专利信息

专利号:US-8268936-B2
优先权日:2005-01-04
标题:Synthesis of hybrid block copolymers and uses thereof
发明人：BREITENKAMP KURT; SILL KEVIN N
权利人:BREITENKAMP KURT; SILL KEVIN N; INTEZYNE TECHNOLOGIES INC
摘要:The present invention relates to the field of polymer chemistry and more particularly to multiblock copolymers and methods of preparing the same.

专利号:US-2012196989-A1
优先权日:2005-02-11
标题:Synthesis of homopolymers and block copolymers
发明人：BREITENKAMP KURT; SILL KEVIN N
权利人:BREITENKAMP KURT; SILL KEVIN N; INTEZYNE TECHNOLOGIES INC
摘要:The present invention relates to the field of polymer chemistry and more particularly to homopolymers and block copolymers and methods of preparing the same.

专利号:US-11465997-B2
优先权日:2017-06-22
标 题 :Synthesis of disorazoles and analogs thereof as potent anticancer agents
发明人：NICOLAOU KYRIACOS C; BELLAVANCE GABRIEL; BUCHMAN MAREK; PULUKURI KIRAN KUMAR; RIGOL STEPHAN
权利人:UNIV RICE WILLIAM M
摘要:In one aspect, the present disclosure provides disorazole analogs of the formula: Formula (I) wherein the variables are as defined herein. In another aspect, the present disclosure also provides methods of preparing the compounds disclosed herein. In another aspect, the present disclosure also provides pharmaceutical compositions and methods of use of the compounds disclosed herein. Additionally, drug conjugates with cell targeting moieties of the compounds are also provided.

专利号:US-8207329-B2
优先权日:2005-11-30
标题:Synthesis of chlorins and phorbines with enhanced red spectral features
发明人：LINDSEY JONATHAN S; LAHA JOYDEV K; CHINNASAMY MUTHIAH; BORBAS K ESZTER
权利人:LINDSEY JONATHAN S; LAHA JOYDEV K; CHINNASAMY MUTHIAH; BORBAS K ESZTER; UNIV NORTH CAROLINA STATE
摘要:The present invention provides compounds of the general Formula DI: along with methods of making such compounds, formulations containing the same, and methods of using the same (e.g., in photodynamic therapy, for the production of solar cells, etc.).

专利号:US-10236457-B2
优先权日:2016-06-29
标题 :Synthesis of porphyrin materials for highly efficient organic photovoltaics
发明人：ZHU XUNJIN; CHEN SONG; WONG WAI YEUNG; WONG WAI KWOK
权利人:UNIV HONG KONG BAPTIST UNIV
摘要:The present disclosure relates to porphyrin small molecules that can be represented by, e.g., a compound of Formula IV designed and synthesized for bulk heterojunction (BHJ) organic solar cells (OSCs). Provided are synthesized materials with strong and ordered self-assembly property, leading to form bi-continuous, interpenetrating networks which are required for efficient charge separation and transport in organic solar cells. The power conversion efficiency (PCE) of the solar cells devices based on the embodiments of the present disclosure have the highest PCE among the solution-processed BHJ solar cell based on porphyrin small molecules to date.

专利号:US-12378246-B2
优先权日:2019-04-11
标 题:Synthetic options towards the manufacture of (6R,10S)-10-{4-[5-chloro-2-(4-chloro-1H-1,2,3-triazol-1-yl)phenyl]-6-oxo-1(6H)-pyrimidinyl} - 1-(difluoromethyl)-6-methyl-1,4,7,8,9,10-hexahydro-11,15-(metheno)pyrazolo[4,3-b][1,7]diazacyclotetradecin-5(6H)-one
发明人：CUNIERE NICOLAS; FAN YU; KOLOTUCHIN SERGEI; MUKHERJEE SUBHA; SIMMONS ERIC M; SINGH AMARJIT; WEI CAROLYN S; XIAO YI; YUAN CHANGXIA; ZHENG BIN; WAGSCHAL SIMON ALBERT; BROGGINI DIEGO FERNANDO DOMENICO; CAO DUY CHI TRUNG; CHERNICHENKO KOSTIANTYN; LEMAIRE SEBASTIEN FRANCOIS EMMANUEL; BEN HAÃ M CYRIL
权利人:BRISTOL MYERS SQUIBB CO; JANSSEN PHARMACEUTICA NV
摘要:Highly efficient methods are provided for preparing key intermediates in the synthesis of Compound (I), which are broadly applicable and can provide selected components having a variety of substituents groups.