9-(3-溴苯基)-9H-咔唑置于叔丁基锂,Copper(L) Cyanide体系中,用 四氢呋喃,正戊烷 用作溶剂,化学反应 4.0H,以85%的收率获得3,3'-二(N-咔唑基)-1,1'-联苯 参考文献:Synthesis Of Symmetrical Dicarbazole-Biphenyls,Components Of Phosphorescentorganic Light-Emitting Diodes (Pholeds) Using Organocuprates 标题:Synthesis Of Symmetrical Dicarbazole-Biphenyls,Components Of Phosphorescentorganic Light-Emitting Diodes (Pholeds) Using Organocuprates 摘要:An Effective One-Stage Method Is Proposed For Obtaining Symmetrical Dicarbazole-Biphenyls,Components Of Phosphorescent Organic Light-Emitting Diodes Through Organocuprates Of The Corresponding N-(Bromophenyl)Carbazoles. The Reaction Products Were Obtained In Moderate To High Yields. Doi:10.1007/s10593-011-0800-6
专利号:US-8987451-B2 优先权日:2012-01-03 标题 :Synthesis of cyclometallated platinum(II) complexes 发明人:TSAI JUI-YI; KOTTAS GREGG; YEAGER WALTER 权利人:UNIVERSAL DISPLAY CORP 摘要:A single-step method of making tetradentate platinum complexes is disclosed. The method advantageously allows the formation of a platinum complex in a single step, even with sterically hindered ligands, without the use of highly reactive intermediates. The compounds made by the disclosed method are useful in OLED applications.
专利号:US-2013172561-A1 优先权日:2012-01-03 标 题:Synthesis of cyclometallated platinum(ii) complexes
专利号:US-10577325-B2 优先权日:2017-03-28 标 题 :Method for preparing a series of carbazole derivatives and use thereof in organic light-emitting diodes 发明人:CAO JIANHUA; WANG SHIBO; HUA RUIMAO 权利人:SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD 摘要:Disclosed are a method for preparing a series of carbazole derivatives and use thereof in organic light-emitting diodes. The structure of the material is as shown in Formula I. An organic electroluminescent device prepared by the material can have a significantly improved power efficiency and an external quantum efficiency for the device and an extended life for an orange light or red light device; moreover, the material has characteristics, for example, methods for the synthesis and purification of the material are simple and suitable for large-scale production, and is an ideal choice as a luminescent material for organic electroluminescent devices. The use of the organic electroluminescent diode material as a carrier transport material or as a luminescent material alone or as a host material in a light-emitting layer also falls within the scope of protection.
专利号:US-11462694-B2 优先权日:2017-09-20 标题 :Imidazole derivative, material and organic light-emitting device comprising the same 发明人:CAO JIANHUA; DONG LIANG; WANG SHIBO; ZHANG JIANCHUAN; SUI YAN; HUA RUIMAO 权利人:SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD 摘要:There is provided an imidazole derivative, wherein the structural formula of the imidazole derivative is as represented by formula I:There is further provided a material containing the imidazole derivative and an organic light-emitting device containing the imidazole derivative. The imidazole derivative has an excellent carrier transport capacity, and the organic light-emitting device produced by using the material has obviously reduced starting voltage and improved luminous efficiency and luminance; and due to the features such as relatively good film-forming performance and simple material synthesis and purification methods which are applicable to mass production, the imidazole derivative is an ideal option for an electron transport material of organic light-emitting devices.
专利号:US-10873044-B2 优先权日:2007-05-23 标题 :Method and apparatus for light absorption and charged carrier transport 发明人:XUE JIANGENG 权利人:UNIV FLORIDA 摘要:Embodiments of the invention pertain to the use of alloyed semiconductor nanocrystals for use in solar cells. The use of alloyed semiconductor nanocrystals offers materials that have a flexible stoichiometry. The alloyed semiconductor may be a ternary semiconductor alloy, such as AxB1-xC or AB1-yCy, or a quaternary semiconductor alloy, such as AxByC1-x-yD, AxB1-xCyD1-y or ABxCyD1-x-y (where A, B, C, and D are different elements). In general, alloys with more than four elements can be used as well, although it can be much harder to control the synthesis and quality of such materials. Embodiments of the invention pertain to solar cells having a layer incorporating two or more organic materials such that percolated paths for one or both molecular species are created. Specific embodiments of the invention pertain to a method for fabricating nanostructured bulk heterojunction that facilitates both efficient exciton diffusion and charge transport. Embodiments of the subject invention pertain to a solar cell having an architecture that allows for efficient harvesting of solar energy. The organic solar cell architecture can incorporate a host/guest (or matrix/dopant) material system that utilizes the long diffusion lengths for triplet excitons without compromising light absorption efficiency.
专利号:RU-2550812-C2 优先权日:2011-01-05 标 题:Novel method of agomelatine synthesis
参考文献:10.1007/s40843-022-2342-x 摘要:Park J, Lim J, Lee JY. A silane-based host material with improved electron transport properties for phosphorescent OLEDs with high efficiency and low efficiency roll-off. Sci. China Mater. 2023 Feb 17;66(5):1997–2003. doi: 10.1007/s40843-022-2342-x. 参考文献:10.1038/s41566-024-01395-1 摘要:Stavrou K, Franca LG, Danos A, Monkman AP. Key requirements for ultraefficient sensitization in hyperfluorescence organic light-emitting diodes. Nat. Photon. 2024 Feb 13;18(6):554–61. doi: 10.1038/s41566-024-01395-1. 参考文献:10.1007/s40843-024-3008-8 摘要:Hu J, Liang J, Yan Z, Ni H, Liao X, Zheng Y. One-shot synthesis of heavy-atom-modified carbazole-fused multi-resonance thermally activated delayed fluorescence materials. Sci. China Mater. 2024 Jul 17;67(9):2789–95. doi: 10.1007/s40843-024-3008-8. 参考文献:10.1007/s11426-024-2264-7 摘要:Wang Y, Yang W, Zhang H, Li N, Gong S, Gao X, Yang C. Pyrazine-fused polycyclic aromatic hydrocarbons towards efficient multiple-resonance narrowband deep-blue emission. Sci. China Chem. 2024 Oct 31;68(3):1018–25. doi: 10.1007/s11426-024-2264-7. 参考文献:10.1007/s40843-025-3490-4 摘要:Liu J, Zhang Z, Liu Y, Liu J, Miao J, Liu H, Yang C. Fine tuning of spiro-locking multi-resonance thermally activated delayed fluorescent emitter for efficient green electroluminescence approaching BT.2020. Sci. China Mater. 2025 Sep 11;68(11):4059–67. doi: 10.1007/s40843-025-3490-4.